journal article·2012-09-14

Influence of Surface States on Gas Response Properties of Pt/TiO2

Mao-Lin ZHANG, Zhan-Heng YUAN, Jian-Ping SONG, Cheng ZHENG

Journal of Inorganic Materials· Volume 27· Issue 9
Publisher page

Abstract

通过浸渍法用H 2 PtCl 6 溶液修饰TiO 2 厚膜, 经过不同的处理工艺, 获得表面负载Pt粒子的Pt/TiO 2 厚膜. 采用XRD和SEM分析了Pt/TiO 2 的物相结构和表面形貌, 并通过电阻-氧分压关系计算Pt/TiO 2 厚膜活化能. 然后分别通过静态和动态测试法, 表征了Pt/TiO 2 厚膜在H 2 /O 2 中的稳态阻值和动态响应时间. 结果表明: 受“spill-over”机制影响, Pt/TiO 2 厚膜在H 2 /O 2 气氛下的稳态电阻与Pt的散布状态有关. 而样品响应时间不仅与Pt粒子的分布有关, 还受表面活化能的影响, 在Pt散布基本相同情况下, 活化能越低, 样品响应速度越快.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Advanced Memory and Neural Computing

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References (16)

Show source-provided references
1. TAI Hui-Ling
7. ZHOU Zhi-Gang
9. ZHANG Qing-Hong
13. Xu Yu-Long