Amorphous Nd-Ni-B/NF Rare Earth Composites: Preparation and HER Electrocatalytic Performance
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Abstract
非晶 Nd-Ni-B/NF 稀土复合电极材料的制备及其析氢性能西宁 810000; 2. 中国科学技术大学 纳米科学技术学院, 苏州 215000) 摘 要: 本研究采用简单的一步化学沉积法制备非晶纳米 Nd-Ni-B/NF 稀土复合电极并研究其析氢(Hydrogen evolution reaction, HER)性能。通过各种测试方法对纳米电极材料进行物相分析和形貌表征,并探索其电催化析氢性 能和稳定性。 结果表明, 稀土 Nd 可提高电极的电催化析氢性能, 当硝酸钕浓度为 3 g•L -1 时, 恒温 35 ℃下施镀 1 h, 制备的 Nd-Ni-B/NF 电极析氢性能最佳。Nd-Ni-B/NF(Nickel foam)电极在 1.0 mol•L -1 KOH 溶液中, 20 mA•cm -2 电流 密度下的析氢过电位仅为 180 mV, Tafel 斜率为 117 mV•dec -1 , 析氢反应由 Volmer-Heyrovsky 步骤控制。此外,
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OpenAlex topics: Metallic Glasses and Amorphous Alloys · Phase-change materials and chalcogenides
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References (37)
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