journal article·2020Open access

Novel Inorganic Two-dimensional Materials for Gas Separation Membranes

YANG Liuxin, LUO Wenhua, WANG Changan, XU Chen

Journal of Inorganic Materials· Volume 35· Issue 9

Abstract

Membrane-based gas separation is one of the critical technologies in filtration and separation industry, since it is more efficient, energy-saving and environmentally friendly compared with traditional separation technologies. Novel inorganic two-dimensional materials (2DMs) for gas separation are expected to achieve both high selectivity and high permeability, breaking through the trade-off between selectivity and permeability of commercial polymer membranes. This review begins with a brief explanation of gas separation mechanisms for membranes. Afterwards, special attention will be given to the recent advances in novel inorganic 2DMs including graphene and their derivatives, TMDs and MXene, about their design, fabrication and application in gas separation. The gas separation characteristics of different materials, their challenges and directions for future research are summarized. Moreover, the application of other novel inorganic 2DMs, such as LDH, h-BN and mica nanosheets in gas separation technology is also discussed.
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Research context

OpenAlex topics: Membrane Separation and Gas Transport · Membrane Separation Technologies · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

1. School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;2. Institute of Materials, China Academy of Engineering Physics, Jiangyou 621700, China;

2. Institute of Materials, China Academy of Engineering Physics, Jiangyou 621700, China;

1. School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;

References (91)

Show source-provided references
1. LIU G, JIN W, XU N. Graphene-based membranes. Chemical Society Reviews, 2015,44(15):5016-5030.10.1039/C4CS00423J ↗
2. SHOLL D S, LIVELY R P. Seven chemical separations to change the world. Nature, 2016,532(7600):435-437.10.1038/532435a ↗
3. LI P, WANG Z, QIAO Z, et al. Recent developments in membranes for efficient hydrogen purification. Journal of Membrane Science, 2015. 495:130-168.10.1016/j.memsci.2015.08.010 ↗
4. JEON Y W, LEE D H. Gas membranes for CO2/CH4 (biogas) separation: a review. Environmental Engineering Science, 2015,32(2):71-85.10.1089/ees.2014.0413 ↗
5. DALANE K, DAI Z, MOGSETH G, et al. Potential applications of membrane separation for subsea natural gas processing: a review. Journal of Natural Gas Science and Engineering, 2017,39:101-117.10.1016/j.jngse.2017.01.023 ↗
6. HIMMA N F, WARDANI A K, PRASETYA N, et al. Recent progress and challenges in membrane-based O2/N2 separation. Reviews in Chemical Engineering, 2019,35(5):591-625.10.1515/revce-2017-0094 ↗
7. ZHU J, HOU J, ULIANA A, et al. The rapid emergence of two-dimensional nanomaterials for high-performance separation membranes. Journal of Materials Chemistry A, 2018,6(9):3773-3792.10.1039/C7TA10814A ↗
8. GIN D L, NOBLE R D. Designing the next generation of chemical separation membranes. Science, 2011,332(6030):674.10.1126/science.1203771 ↗
9. QIU T, KUANG C, ZHENG X, et al. On the research and application trends of global gas membrane separation technology—— based on analysis of SCI articles and patents in recent 20 years. Chemical Industry & Engineering Progress, 2016,35(7):2299-2308.
10. YAMPOLSKII Y. Polymeric gas separation membranes. Macromolecules, 2012,45(8):3298-3311.10.1021/ma300213b ↗
11. PROZOROVSKA L, KIDAMBI P R. State-of-the-art and future prospects for atomically thin membranes from 2D materials. Advanced Materials, 2018,30(52):1801179.10.1002/adma.201801179 ↗
12. LIU M, GURR P A, FU Q, et al. Two-dimensional nanosheet-based gas separation membranes. Journal of Materials Chemistry A, 2018,6(46):23169-23196.10.1039/C8TA09070J ↗
13. LIU G, JIN W, XU N. Two-dimensional-material membranes: a new family of high-performance separation membranes. Angewandte Chemie International Edition, 2016,55(43):13384-13397.10.1002/anie.201600438 ↗
14. WANG L, BOUTILIER M S H, KIDAMBI P R, et al. Fundamental transport mechanisms, fabrication and potential applications of nanoporous atomically thin membranes. Nature Nanotechnology, 2017,12:509.10.1038/nnano.2017.72 ↗
15. WIJMANS J G, BAKER R W J. The solution-diffusion model: a review. Journal of Membrane Science, 1995,107:1-21.10.1016/0376-7388(95)00102-I ↗
16. LI C, MECKLER S M, SMITH Z P, et al. Engineered transport in microporous materials and membranes for clean energy technologies. Advanced Materials, 2018,30(8):1704953.10.1002/adma.201704953 ↗
17. SHEN J, LIU G, HUANG K, et al. Membranes with fast and selective gas-transport channels of laminar graphene oxide for efficient CO2 capture. Angewandte Chemie International Edition, 2015,127(2):588-592.10.1002/ange.201409563 ↗
18. DRAHUSHUK L W, WANG L, KOENIG S P, et al. Analysis of time-varying, stochastic gas transport through graphene membranes. ACS Nano, 2016,10(1):786-795.10.1021/acsnano.5b05870 ↗
19. KIM H W, YOON H W, YOON S M, et al. Selective gas transport through few-layered graphene and graphene oxide membranes. Science, 2013,342(6154):91-95.10.1126/science.1236098 ↗
20. LI H, SONG Z, ZHANG X, et al. Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation. Science, 2013,342(6154):95-98.10.1126/science.1236686 ↗
21. WANG Z, WANG D, ZHANG S, et al. Interfacial design of mixed matrix membranes for improved gas separation performance. Advanced Materials, 2016,28(17):3399-3405.10.1002/adma.201504982 ↗
22. ZHU X, TIAN C, DO-THANH C L, et al. Two‐dimensional materials as prospective scaffolds for mixed‐matrix membrane‐based CO2 separation. ChemSusChem, 2017,10(17):3304-3316.10.1002/cssc.201700801 ↗
23. GEIM A K, NOVOSELOV K S. The rise of graphene. Nature Materials, 2007,6:183.10.1038/nmat1849 ↗
24. PARTOENS B, PEETERS F. From graphene to graphite: electronic structure around the K point. Phys. Rev. B, 2006,74(7):075404.
25. BUNCH J S, VERBRIDGE S S, ALDEN J S, et al. Impermeable atomic membranes from graphene sheets. Nano Letters, 2008,8(8):2458-2462.10.1021/nl801457b ↗
26. BERRY V. Impermeability of graphene and its applications. Carbon, 2013,62:1-10.10.1016/j.carbon.2013.05.052 ↗
27. LEE C, WEI X, KYSAR J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science, 2008,321(5887):385-388.10.1126/science.1157996 ↗
28. JIANG D E, COOPER V, DAI S. Porous graphene as the ultimate membrane for gas separation. Nano Letters, 2009,9:4019-4024.10.1021/nl9021946 ↗
29. WANG S, DAI S, JIANG D E. Continuously tunable pore size for gas separation via a bilayer nanoporous graphene membrane. ACS Applied Nano Materials, 2019,2(1):379-384.10.1021/acsanm.8b01967 ↗
30. KOENIG S P, WANG L, PELLEGRINO J, et al. Selective molecular sieving through porous graphene. Nature Nanotechnology, 2012,7(11):728-732.10.1038/nnano.2012.162 ↗
31. BELL D, LEMME M, STERN L, et al. Precision cutting and patterning of graphene with helium ions. Nanotechnology, 2009,20:455301.10.1088/0957-4484/20/45/455301 ↗
32. CELEBI K, BUCHHEIM J, WYSS R M, et al. Ultimate permeation across atomically thin porous graphene. Science, 2014,344(6181):289-292.10.1126/science.1249097 ↗
33. HUANG S, DAKHCHOUNE M, LUO W, et al. Single-layer graphene membranes by crack-free transfer for gas mixture separation. Nature Communications, 2018,9(1):2632-2632.10.1038/s41467-018-04904-3 ↗
34. FISCHBEIN M D, DRNDIĆ M. Electron beam nanosculpting of suspended graphene sheets. Applied Physics Letters, 2008,93(11):113107.10.1063/1.2980518 ↗
35. LU N, WANG J, FLORESCA H C, et al. In situ studies on the shrinkage and expansion of graphene nanopores under electron beam irradiation at temperatures in the range of 400-1200 ℃. Carbon, 2012,50(8):2961-2965.10.1016/j.carbon.2012.02.078 ↗
36. GARAJ S, HUBBARD W, REINA A, et al. Graphene as a subnanometre trans-electrode membrane. Nature, 2010,467:190.10.1038/nature09379 ↗
37. MERCHANT C. DNA translocation through graphene nanopores. Biophysical Journal, 2011,100(3):521a.10.1016/j.bpj.2010.12.3046 ↗
38. HUMMERS JR W S, OFFEMAN R E. Preparation of graphitic oxide. Journal of the American Chemical Society, 1958,80(6):1339.10.1021/ja01539a017 ↗
39. DIMIEV A, TOUR J. Mechanism of graphene oxide formation. ACS Nano, 2014,8(3):3060-3067.10.1021/nn500606a ↗
40. NAIR R R, WU H A, JAYARAM P N, et al. Unimpeded permeation of water through helium-leak-tight graphene-based membranes. Science, 2012,335(6067):442-444.10.1126/science.1211694 ↗
41. IBRAHIM A, LIN Y S. Gas permeation and separation properties of large-sheet stacked graphene oxide membranes. Journal of Membrane Science, 2018,550:238-245.10.1016/j.memsci.2017.12.081 ↗
42. YANG J, GONG D, LI G, et al. Self-assembly of thiourea-crosslinked graphene oxide framework membranes toward separation of small molecules. Advanced Materials, 2018,30(16):1705775.10.1002/adma.201705775 ↗
43. ABRAHAM J, VASU K S, WILLIAMS C D,et al. Tunable sieving of ions using graphene oxide membranes. Nature Nanotechnology, 2017,12(6):546-550.10.1038/nnano.2017.21 ↗
44. CHI C, WANG X, PENG Y, et al. Facile preparation of graphene oxide membranes for gas separation. Chemistry of Materials, 2016,28(9):2921-2927.10.1021/acs.chemmater.5b04475 ↗
45. YANG E, HAM M H, PARK H B, et al. Tunable semi-permeability of graphene-based membranes by adjusting reduction degree of laminar graphene oxide layer. Journal of Membrane Science, 2018,547:73-79.10.1016/j.memsci.2017.10.039 ↗
46. SU Y, KRAVETS V G, WONG S L, et al. Impermeable barrier films and protective coatings based on reduced graphene oxide. Nature Communications, 2014,5(1):4843.10.1038/ncomms5843 ↗
47. SUN P, WANG K, ZHU H. Recent developments in graphene-based membranes: structure, mass-transport mechanism and potential applications. Advanced Materials, 2016,28(12):2287-2310.10.1002/adma.201502595 ↗
48. ZHANG Y, ZHANG S, CHUNG T S. Nanometric graphene oxide framework membranes with enhanced heavy metal removal via nanofiltration. Environmental Science & Technology, 2015,49(16):10235-10242.10.1021/acs.est.5b02086 ↗
49. BURRESS J W, GADIPELLI S, FORD J, et al. Graphene oxide framework materials: theoretical predictions and experimental results. Angewandte Chemie International Edition, 2010,49(47):8902-8904.10.1002/anie.201003328 ↗
50. KARUNAKARAN M, VILLALOBOS L F, KUMAR M, et al. Graphene oxide doped ionic liquid ultrathin composite membranes for efficient CO2 capture. Journal of Materials Chemistry A, 2017,5(2):649-656.10.1039/C6TA08858A ↗
51. WANG S, XIE Y, HE G, et al. Graphene oxide membranes with heterogeneous nanodomains for efficient CO2 separations. Angewandte Chemie, 2017,129(45):14434-14439.10.1002/ange.201708048 ↗
52. HUANG G, ISFAHANI A P, MUCHTAR A, et al. Pebax/ionic liquid modified graphene oxide mixed matrix membranes for enhanced CO2 capture. Journal of Membrane Science, 2018,565:370-379.10.1016/j.memsci.2018.08.026 ↗
53. XIN Q, MA F, ZHANG L, et al. Interface engineering of mixed matrix membrane via CO2-philic polymer brush functionalized graphene oxide nanosheets for efficient gas separation. Journal of Membrane Science, 2019,586:23-33.10.1016/j.memsci.2019.05.050 ↗
54. SHEN J, LIU G, HUANG K, et al. Subnanometer two-dimensional graphene oxide channels for ultrafast gas sieving. ACS Nano, 2016,10(3):3398-3409.10.1021/acsnano.5b07304 ↗
55. YING W, CAI J, ZHOU K, et al. Ionic liquid selectively facilitates CO2 transport through graphene oxide membrane. ACS Nano, 2018,12(6):5385-5393.10.1021/acsnano.8b00367 ↗
56. SCHMIDT H, WANG S, CHU L, et al. Transport properties of monolayer MoS2 grown by chemical vapor deposition. Nano Letters, 2014,14(4):1909-1913.10.1021/nl4046922 ↗
57. NICOLOSI V, CHHOWALLA M, G KANATZIDIS M et al. Liquid exfoliation of layered materials. Science, 2013,340:1226419.10.1126/science.1226419 ↗
58. ZHANG W, HUANG J K, CHEN C H, et al. High-gain phototransistors based on a CVD MoS2 monolayer. Advanced Materials, 2013,25(25):3456-3461.10.1002/adma.201301244 ↗
59. WANG H, FENG H, LI J. Graphene and graphene-like layered transition metal dichalcogenides in energy conversion and storage. Small, 2014,10(11):2165-2181.10.1002/smll.201303711 ↗
60. ZENG Z, SUN T, ZHU J, et al. An effective method for the fabrication of few-layer-thick inorganic nanosheets. Angewandte Chemie International Edition, 2012,124(36):9186-9190.10.1002/ange.201204208 ↗
61. GEE M A, FRINDT R F, JOENSEN P, et al. Inclusion compounds of MoS2. Materials Research Bulletin, 1986,21(5):543-549.10.1016/0025-5408(86)90108-X ↗
62. WANG D, WANG Z, WANG L, et al. Ultrathin membranes of single- layered MoS2 nanosheets for high-permeance hydrogen separation. Nanoscale, 2015,7(42):17649-17652.10.1039/C5NR06321C ↗
63. ACHARI A, SAHANA S, ESWARAMOORTHY M. High performance MoS2 membranes: effects of thermally driven phase transition on CO2 separation efficiency. Energy & Environmental Science, 2016,9(4):1224-1228.10.1039/C5EE03856A ↗
64. OSTWAL M, SHINDE D B, WANG X, et al. Graphene oxide- molybdenum disulfide hybrid membranes for hydrogen separation. Journal of Membrane Science, 2018,550:145-154.10.1016/j.memsci.2017.12.063 ↗
65. ZHAO S, XUE J, KANG W. Gas adsorption on MoS2 monolayer from first-principles calculations. Chemical Physics Letters, 2014, 595-596:35-42.10.1016/j.cplett.2014.01.043 ↗
66. HE Q, ZENG Z, YIN Z, et al. Fabrication of flexible MoS2 thin-film transistor arrays for practical gas-sensing applications. Small, 2012,8(19):2994-2999.10.1002/smll.201201224 ↗
67. BEREAN K J, OU J Z, DAENEKE T, et al. 2D MoS2 pdms nanocomposites for NO2 separation. Small, 2015,11(38):5035-5040.10.1002/smll.201501129 ↗
68. SHEN Y, WANG H, ZHANG X, et al. MoS2 nanosheets functionalized composite mixed matrix membrane for enhanced CO2 capture via surface drop-coating method. ACS Applied Materials & Interfaces, 2016,8(35):23371-23378.10.1021/acsami.6b07153 ↗
69. CHEN D K, YING W, GUO Y, et al. Enhanced gas separation through nanoconfined ionic liquid in laminated MoS2 membrane. ACS Applied Materials & Interfaces, 2017,9(50):44251-44257.10.1021/acsami.7b15762 ↗
70. CHEN D, WANG W, YING W, et al. CO2-philic WS2 laminated membranes with a nanoconfined ionic liquid. Journal of Materials Chemistry A, 2018,6(34):16566-16573.10.1039/C8TA04753G ↗
71. ALHABEB M, MALESKI K, ANASORI B, et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chemistry of Materials, 2017,29(18):7633-7644.10.1021/acs.chemmater.7b02847 ↗
72. WANG J T, CHEN P P, SHI B B, et al. A regularly channeled lamellar membrane for unparalleled water and organics permeation. Angewandte Chemie-International Edition, 2018,57(23):6814-6818.10.1002/anie.201801094 ↗
73. DING L, WEI Y, WANG Y, et al. A two-dimensional lamellar membrane: MXene nanosheet stacks. Angewandte Chemie International Edition, 2017,56(7):1825-1829.10.1002/anie.201609306 ↗
74. REN C E, HATZELL K B, ALHABEB M, et al. Charge- and size-selective ion sieving through Ti3C2Tx MXene membranes. The Journal of Physical Chemistry Letters, 2015,6(20):4026-4031.10.1021/acs.jpclett.5b01895 ↗
75. RASOOL K, MAHMOUD K A, JOHNSON D J, et al. Efficient antibacterial membrane based on two-dimensional Ti3C2Tx (MXene) nanosheets. Sci. Rep, 2017,7(1):1598.
76. RASOOL K, HELAL M, ALI A, et al. Antibacterial activity of Ti3C2Tx MXene. ACS Nano, 2016,10(3):3674-3684.10.1021/acsnano.6b00181 ↗
77. DING L, WEI Y, LI L, et al. MXene molecular sieving membranes for highly efficient gas separation. Nature Communications, 2018,9:155.10.1038/s41467-017-02529-6 ↗
78. SHEN J, LIU G Z, JI Y F, et al. 2D MXene nanofilms with tunable gas transport channels. Advanced Functional Materials, 2018,28(31):1801511.10.1002/adfm.201801511 ↗
79. LI L, ZHANG T, DUAN Y, et al. Selective gas diffusion in two-dimensional MXene lamellar membranes: insights from molecular dynamics simulations. Journal of Materials Chemistry A, 2018,6(25):11734-11742.10.1039/C8TA03701A ↗
80. WANG Q, O’HARE D. Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets. Chemical Reviews, 2012,112(7):4124-4155.10.1021/cr200434v ↗
81. LU P, LIU Y, ZHOU T, et al. Recent advances in layered double hydroxides (LDHs) as two-dimensional membrane materials for gas and liquid separations. Journal of Membrane Science, 2018,567:89-103.10.1016/j.memsci.2018.09.041 ↗
82. KIM T W, SAHIMI M, TSOTSIS T T. Preparation of hydrotalcite thin films using an electrophoretic technique. Industrial & Engineering Chemistry Research, 2008,47(23):9127-9132.10.1021/ie071446s ↗
83. KIM T W, SAHIMI M, TSOTSIS T T. The preparation and characterization of hydrotalcite thin films. Industrial & Engineering Chemistry Research, 2009,48(12):5794-5801.10.1021/ie900371r ↗
84. LIU Y, WANG N, CAO Z, et al. Molecular sieving through interlayer galleries. Journal of Materials Chemistry A, 2014,2(5):1235-1238.10.1039/C3TA13792A ↗
85. WANG Y, LOW Z X, KIM S, et al. Functionalized boron nitride nanosheets: a thermally rearranged polymer nanocomposite membrane for hydrogen separation. Angewandte Chemie International Edition, 2018,57(49):16056-16061.10.1002/anie.201809126 ↗
86. KIM S, HOU J, WANG Y, et al. Highly permeable thermally rearranged polymer composite membranes with a graphene oxide scaffold for gas separation. Journal of Materials Chemistry A, 2018,6(17):7668-7674.10.1039/C8TA02256A ↗
87. ZHANG X, HE Y, LI R, et al. 2D mica crystal as electret in organic field-effect transistors for multistate memory. Advanced Materials, 2016,28(19):3755-3760.10.1002/adma.201506356 ↗
88. WANG D, YUAN G, HAO G, et al. All-inorganic flexible piezoelectric energy harvester enabled by two-dimensional mica. Nano Energy, 2018,43:351-358.10.1016/j.nanoen.2017.11.037 ↗
89. YING W, HAN B, LIN H, et al. Laminated mica nanosheets supported ionic liquid membrane for CO2 separation. Nanotechnology, 2019,30(38):385705.10.1088/1361-6528/ab2b10 ↗
90. ZHANG H P, HU W, DU A, et al. Doped phosphorene for hydrogen capture: a DFT study. Applied Surface Science, 2018,433:249-255.10.1016/j.apsusc.2017.09.243 ↗
91. ZHANG H P, DU A, SHI Q B, et al. Adsorption behavior of CO2 on pristine and doped phosphorenes: a dispersion corrected DFT study. Journal of CO2 Utilization, 2018,24:463-470.10.1016/j.jcou.2018.02.005 ↗