journal article·2026Open access

Research Progress on Mott-Schottky Hydrogen Evolution Catalysts Based on Metal/Transition Metal Compounds

Xianpei REN, Chao LI, Qiwei HU, Hui XIANG, Yuehong PENG

Journal of Inorganic Materials· Volume 41· Issue 2

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OpenAlex topics: Electrocatalysts for Energy Conversion · Ammonia Synthesis and Nitrogen Reduction · Catalytic Processes in Materials Science

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References (69)

Show source-provided references
1. XU Y, WANG C, HUANG Y, et al . Recent advances in electrocatalysts for neutral and large-current-density water electrolysis. Nano Energy , 2021, 80: 105545.10.1016/j.nanoen.2020.105545 ↗
2. XU Z, WU Z S. Scalable production of high-performance electrocatalysts for electrochemical water splitting at large current densities. eScience , 2025, 5(4): 100334.10.1016/j.esci.2024.100334 ↗
3. 李宇明, 徐砚文, 刘红宇, 等. 镍基磷化物的合成及其在电解水制氢中的应用. 化工学报, 2024, 75(12): 4385.
4. 陈心悦, 陈彬剑, 毛煜东, 等. 碱性电解水析氢催化剂的研究进展及展望. 化工进展, 2025, 44(11): 6334.10.61189/158176zcolcy ↗
5. HU C, LV C, ZENG N, et al . Recent advances in Ni-based electrocatalysts for hydrogen evolution reaction. Energy Technology , 2023, 11(1): 2201048.10.1002/ente.202201048 ↗
6. HE H, MAI J H, HU K S, et al . Recent advances in electrocatalysts for efficient hydrogen evolution reaction. Rare Metals , 2025, 44: 2208.10.1007/s12598-024-02649-1 ↗
7. 王红霞, 徐婉怡, 张早校. 可再生电力电解制绿色氢能的发展现状与建议. 化工进展, 2022, 41(S1): 118.
8. 张正, 宋凌珺. 电解水制氢技术: 进展、挑战与未来展望. 工程科学学报, 2025, 47(2): 282.
9. DOU S, WANG X, WANG S Y, et al . Rational design of transition metal-based materials for highly efficient electrocatalysis. Small Methods , 2019, 3(1): 1800211.10.1002/smtd.201800211 ↗
10. 张博轩, 崔金星, 李智芳, 等. 非贵金属析氢电催化剂的结构调控研究进展. 化学通报, 2023, 86(7): 784.
11. DO H H, TRAN N T, VAN TRAN V. Recent advancements and perspectives in MoO 2 -based heterostructures for electrochemical hydrogen evolution reaction. International Journal of Hydrogen Energy , 2025, 105: 234.10.1016/j.ijhydene.2025.01.293 ↗
12. XIONG W, YIN H, WU T, et al . Challenges and opportunities of transition metal oxides as electrocatalysts. Chemistry-A European Journal , 2023, 29(5): e202202872.10.1002/chem.202202872 ↗
13. ZHU Y L, LIN Q, ZHONG Y J, et al . Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts. Energy & Environmental Science , 2020, 13: 3361.10.1039/D0EE02485F ↗
14. SHIRAZ H G, CRISPIN X, BERGGREN M. Transition metal sulfides for electrochemical hydrogen evolution. International Journal of Hydrogen Energy , 2021, 46(47): 24060.10.1016/j.ijhydene.2021.04.194 ↗
15. GUO Y, PARK T, YI J W, et al . Nanoarchitectonics for transition- metal-sulfide-based electrocatalysts for water splitting. Advanced Materials , 2019, 31(17): 1807134.10.1002/adma.201807134 ↗
16. 万凯, 向志朋, 刘文博, 等. 过渡金属硫化物电解水析氢/析氧反应电催化剂研究进展. 科学通报, 2022, 67(19): 2126.
17. WANG Z Y, LIU S L, DUAN W, et al . Transition metal selenides as catalysts for electrochemical water splitting. International Journal of Hydrogen Energy , 2024, 60: 1414.10.1016/j.ijhydene.2024.02.201 ↗
18. LI Y, WANG C, ABDUKAYUM A, et al . Advances in green hydrogen generation based on MoSe 2 hybrid catalysts. Electrochimica Acta , 2024, 503: 144891.10.1016/j.electacta.2024.144891 ↗
19. 白苗苗, 刘江英, 韩婕, 等. 硒化镍基电催化水裂解催化剂的研究进展. 功能材料, 2023, 54(11): 11050.
20. DU M, LI D, LIU S F, et al . Transition metal phosphides: a wonder catalyst for electrocatalytic hydrogen production. Chinese Chemical Letters , 2023, 34(9): 108156.10.1016/j.cclet.2023.108156 ↗
21. DENG R, GUO M, WANG C, et al . Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting: from catalytic mechanism and synthesis method to optimization design. Nano Materials Science , 2024, 6(2): 139.10.1016/j.nanoms.2022.04.003 ↗
22. ZHANG W Y, GUO R H, YUE Q X, et al . High-entropy phosphide bifunctional catalyst: preparation and performance of efficient water splitting. Journal of Inorganic Materials , 2024, 39(11): 1265.10.15541/jim20240074 ↗
23. PENG X, PI C, ZHANG X, et al . Recent progress of transition metal nitrides for efficient electrocatalytic water splitting. S ustainable Energy & Fuels , 2019, 3(2): 366.10.1039/C8SE00525G ↗
24. 蒋博龙, 崔艳艳, 史顺杰, 等. 双金属氮化物NiMoN析氢催化剂制备及其电解海水析氢性能的研究. 化学学报, 2022, 80(10): 1394.
25. JIANG J, QIU Y, DONG H, et al . Enhancing hydrogen evolution by heterointerface engineering of Ni/MoN catalysts. Journal of Colloid and Interface Science , 2025, 686: 681.10.1016/j.jcis.2025.01.201 ↗
26. XU C, HONG Y, LI Z, et al . Transition metal-based heterojunctions for alkaline electrocatalytic water splitting. Coordination Chemistry Reviews , 2025, 523: 216287.10.1016/j.ccr.2024.216287 ↗
27. LONG X, MENG J, GU J, et al . Interfacial engineering of NiFeP/ NiFe-LDH heterojunction for efficient overall water splitting. Chinese Journal of Structural Chemistry , 2022, 41(4): 2204046.
28. ZHAO G, JIANG Y, DOU S X, et al . Interface engineering of heterostructured electrocatalysts towards efficient alkaline hydrogen electrocatalysis. Science Bulletin , 2021, 66(1): 85.10.1016/j.scib.2020.09.014 ↗
29. REN X P, LI Q, LING F, et al . Construction of MoO 2 /MoS 2 heterojunction on carbon nanotubes as high-efficiency electrocatalysts for H 2 production. CrystEngComm , 2023, 25: 5238.10.1039/D3CE00674C ↗
30. XU D, ZHANG S N, LI X H, et al . Design of the synergistic rectifying interfaces in Mott-Schottky catalysts. Chemical Reviews , 2023, 123(1): 1.10.1021/acs.chemrev.2c00426 ↗
31. ZHANG H M, LI R, MUHAMMAD H, et al . Recent progress in Mott-Schottky junction electrocatalysts for the pH-universal hydrogen evolution reaction. Materials Chemistry Frontiers , 2024, 8(12): 2811.10.1039/D4QM00312H ↗
32. TONG Y X, LIU W, LI C M, et al . A metal/semiconductor contact induced Mott-Schottky junction for enhancing the electrocatalytic activity of water-splitting catalysts. Sustainable Energy Fuels , 2023, 7(1): 12.10.1039/D2SE01355J ↗
33. QIAO D, YUN S, SUN M, et al . 1D/3D trepang-like N-modified carbon confined bimetal carbides and metal cobalt: boosting electron transfer via dual Mott-Schottky heterojunctions triggered built-in electric fields for efficient hydrogen evolution and tri-iodide reduction. Applied Catalysis B: Environmental , 2023, 334: 122830.10.1016/j.apcatb.2023.122830 ↗
34. 刘恩科, 朱秉升, 罗晋生. 半导体物理学. 北京: 电子工业出版社, 2017.
35. 张伶, 陈红梅, 魏子栋. 过渡金属氧化物催化析氧反应研究进展. 化工学报, 2020, 71(9): 3876.
36. SAHOO S, WICKRAMATHILAKA K Y, NJERI E, et al . A review on transition metal oxides in catalysis. Frontiers in Chemistry , 2024, 12: 1374878.10.3389/fchem.2024.1374878 ↗
37. CHEN L, WANG H, TIAN W W, et al . Enabling internal electric field in heterogeneous nanosheets to significantly accelerate alkaline hydrogen electrocatalysis. Small , 2024, 20(18): 2307252.10.1002/smll.202307252 ↗
38. LI R, PU Z, ZHOU R, et al . In situ controllable construction of Ni@NiO Schottky heterojunctions for electrocatalytic hydrogen evolution. Journal of Materials Chemistry C , 2024, 12(46): 18849.10.1039/D4TC03342F ↗
39. CHEN J, ZHENG J, HE W, et al . Self-standing hollow porous Co/a-WO x nanowire with maximum Mott-Schottky effect for boosting alkaline hydrogen evolution reaction. Nano Research , 2023, 16(4): 4603.10.1007/s12274-022-5072-1 ↗
40. LIU M, YANG H, ZHOU Z, et al . Homologous heterostructures of Ni/NiFeO Mott-Schottky for alkaline water electrolysis. Journal of Materials Chemistry A , 2024, 12: 22210.10.1039/D4TA04428B ↗
41. PENG L, SU L, YU X, et al . Electron redistribution of ruthenium- tungsten oxides Mott-Schottky heterojunction for enhanced hydrogen evolution. Applied Catalysis B: Environmental , 2022, 308: 121229.10.1016/j.apcatb.2022.121229 ↗
42. 何倩倩, 王哲, 孟令佳, 等. 基于过渡金属二硫族化物析氢催化的研究进展. 高等学校化学学报, 2021, 42(2): 523.
43. SUN J, MENG X. Modulating the electronic properties of MoS 2 nanosheets for electrochemical hydrogen production: a review. ACS Applied Nano Materials , 2021, 4(11): 11413.10.1021/acsanm.1c02832 ↗
44. JIANG L, XIA Y X, LI J J, et al . Engineering Mott-Schottky heterojunction Au δ + /1T-MoS 1.76 electrocatalyst for boosting hydrogen evolution reaction. ACS Applied Energy Materials , 2023, 6(6): 3255.10.1021/acsaem.3c00801 ↗
45. SUN Z, LIN L, YUAN M W, et al . Mott-Schottky heterostructure induce the interfacial electron redistribution of MoS 2 for boosting pH-universal hydrogen evolution with Pt-like activity. Nano Energy , 2022, 101: 107563.10.1016/j.nanoen.2022.107563 ↗
46. WAZIR M B, DAUD M, SAFEER S, et al . Review on 2D molybdenum diselenide (MoSe 2 ) and its hybrids for green hydrogen (H 2 ) generation applications. ACS Omega , 2022, 7(20): 16856.10.1021/acsomega.2c00330 ↗
47. YANG C M, LI X, LIANG Y C. Recent advances in molybdenum diselenide-based electrocatalysts: preparation and application in the hydrogen evolution reaction. Inorganic Chemistry Frontiers , 2023, 10(19): 5517.10.1039/D3QI00885A ↗
48. YANG C, ZHOU L, WANG C, et al . Large-scale synthetic Mo@(2H-1T)-MoSe 2 monolithic electrode for efficient hydrogen evolution in all pH scale ranges and seawater. Applied Catalysis B: Environmental , 2022, 304: 120993.10.1016/j.apcatb.2021.120993 ↗
49. SONG T, ZHANG Z, ZHAO B, et al . Boosting catalytic performance of hierarchical Co/Co 0.85 Se microspheres via Mott- Schottky effect toward triiodide reduction and alkaline hydrogen evolution. Journal of Alloys and Compounds , 2022, 918: 165608.10.1016/j.jallcom.2022.165608 ↗
50. REN X P, HU Q W, LING F, et al . Mott-Schottky heterojunction formation between Co and MoSe 2 on carbon nanotubes towards superior hydrogen evolution. New Carbon Materials , 2023, 38(6): 1059.10.1016/S1872-5805(23)60782-6 ↗
51. SHI Y M, ZHANG B. Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chemical Society Reviews , 2016, 45(6): 1529.10.1039/C5CS00434A ↗
52. 杨博, 吕功煊, 马建泰, 等. 过渡金属磷化物在催化反应中的稳定性. 化学进展, 2024, 36(7): 998.
53. LIU Z Y, FENG C, YANG S T, et al . 1D/3D dual carbon-supported Mott-Schottky-type Co-Co 2 P heterojunctions for pH-universal hydrogen evolution. Journal of Colloid and Interface Science , 2024, 657: 559.10.1016/j.jcis.2023.11.149 ↗
54. WANG Z, WANG S. Constructing built-in electric field to accelerate the asymmetric local charge distribution for efficient alkaline overall water/seawater splitting. Applied Catalysis B: Environment and Energy , 2024, 352: 124002.10.1016/j.apcatb.2024.124002 ↗
55. XUE Z H, SU H, YU Q Y, et al . Janus Co/CoP nanoparticles as efficient Mott-Schottky electrocatalysts for overall water splitting in wide pH range. Advanced Energy Materials , 2017, 7(12): 1602355.10.1002/aenm.201602355 ↗
56. YAN L, CHEN Y H, XIE J C, et al . Optimizing heterointerface of NiCoP-Co/MXene with regulated charge distribution via built-in electric field for efficient overall water-splitting. Rare Metals , 2025, 44(2): 1067.10.1007/s12598-024-02950-z ↗
57. 秦睿, 王鹏彦, 林灿, 等. 过渡金属氮化物的活性起源、合成方法及电催化应用. 物理化学学报, 2021, 37(7): 41.
58. TANG S, ZHANG Z, XIANG J, et al . Recent advances in transition metal nitrides for hydrogen electrocatalysis in alkaline media: from catalyst design to application. Frontiers in Chemistry , 2022, 10: 1073175.10.3389/fchem.2022.1073175 ↗
59. ZHOU Y M, CHU B X, SUN Z J, et al . Surface reconstruction and charge distribution enabling Ni/W 5 N 4 Mott-Schottky heterojunction bifunctional electrocatalyst for efficient urea-assisted water electrolysis. Applied Catalysis B: Environmental , 2023, 323: 122168.10.1016/j.apcatb.2022.122168 ↗
60. HONG Z Z, XU Z L, WU Z T, et al . Construction of core-shell Co-NC@W 2 N Schottky heterojunctions for high-efficiency hydrogen evolution reaction. Applied Surface Science , 2023, 608: 155159.10.1016/j.apsusc.2022.155159 ↗
61. RUI D, LI J, DU X, et al . VFe@Ni/Ni 3 N Mott-Schottky heterojunction induced electronic modulation for efficient alkaline water splitting. Journal of Electroanalytical Chemistry , 2023, 947: 117763.10.1016/j.jelechem.2023.117763 ↗
62. SAKILA K, PAL S, ROY P, et al . Surface oxygen vacancy engineering of Cr-doped FeNi 3 /NiFe 2 O 4 Mott-Schottky heterojunction as efficient electrocatalyst for high current density water oxidation. Journal of Alloys and Compounds , 2024, 977: 173393.10.1016/j.jallcom.2023.173393 ↗
63. JIANG M M, XU J, CHEN Y J, et al . High-efficiency photo- assisted large current-density water splitting with Mott-Schottky heterojunctions. Angewandte Chemie International Edition , 2024, 64(3): e202415492.10.1002/anie.202415492 ↗
64. HUANG Z, CHEN L, ZHANG H, et al . Manipulating interfacial charge redistribution in Mott-Schottky electrocatalyst for high-performance water-seawater splitting. Chemical Engineering Journal , 2024, 501: 157628.10.1016/j.cej.2024.157628 ↗
65. REN Y, WANG C, DUAN W, et al . MoS 2 /Ni 3 S 2 Schottky heterojunction regulating local charge distribution for efficient urea oxidation and hydrogen evolution. Journal of Colloid and Interface Science , 2022, 628: 446.10.1016/j.jcis.2022.08.055 ↗
66. GU C, ZHOU G Y, YANG J, et al . NiS/MoS 2 Mott-Schottky heterojunction-induced local charge redistribution for high- efficiency urea-assisted energy-saving hydrogen production. Chemical Engineering Journal , 2022, 443: 136321.10.1016/j.cej.2022.136321 ↗
67. YUN S, GAO Z, YANG T, et al . Constructing NiSe 2 /MoSe 2 Mott- Schottky heterojunctions onto N-doped brain coral-carbon spheres by phase separation strategies for advanced energy conversion applications. Advanced Functional Materials , 2023, 34(17): 2314226.10.1002/adfm.202314226 ↗
68. SUN Y, CAO W, GE X, et al . Built-in electric field induced interfacial charge distributions of Ni 2 P/NiSe 2 heterojunction for urea-assisted hydrogen evolution reaction. Inorganic Chemistry Frontiers , 2023, 10: 6674.10.1039/D3QI01459B ↗
69. QIN M, CHEN L, ZHANG H, et al . Achieving highly efficient pH-universal hydrogen evolution by Mott-Schottky heterojunction of Co 2 P/Co 4 N. Chemical Engineering Journal , 2023, 454: 14023.10.1016/j.cej.2022.140230 ↗