journal article·2020Open access

Research Progress on Nanostructured Metal Oxides as Anode Materials for Li-ion Battery

ZHENG Shiyou, DONG Fei, PANG Yuepeng, HAN Pan, YANG Junhe

Journal of Inorganic Materials· Volume 35· Issue 12

Abstract

Anode material is an important component for Li-ion battery. The current anode materials are mainly based on graphite, which possesses low theoretical specific capacity of 372 mAh/g, and thus hinder the further development of Li-ion battery. Among the newly developed anode materials, metal oxides have recently attracted intense attention due to their high theoretical specific capacity, low cost and environmental friendliness. However, metal oxides own poor electrical conductivity and large volume changes during cycling. Nanosizing can overcome these disadvantages while maintaining the advantages for metal oxide based anode materials, and thus becomes a research hot spot. Herein, we review the recent research advances of the nanostructured metal oxides as anode materials, mainly focusing on the microstructure design and performance optimization of representative metal oxides and their composites. In addition, some suggestions are presented for further explorations in relative fields.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

References (80)

Show source-provided references
1. CHEN H, LING M, HENCZ L, et al. Exploring chemical, mechanical, and electrical functionalities of binders for advanced energy- storage devices. Chemical Reviews, 2018,118(18):8936-8982.10.1021/acs.chemrev.8b00241 ↗
2. XIONG Q Q, JI Z G. Controllable growth of MoS2/C flower-like microspheres with enhanced electrochemical performance for lithium ion batteries. Journal of Alloys and Compounds, 2016,673:215-219.10.1016/j.jallcom.2016.02.253 ↗
3. ZHANG Y, XIA X, LIU B, et al. Multiscale graphene-based materials for applications in sodium ion batteries. Advanced Energy Materials, 2019,9(8):1803342.10.1002/aenm.201803342 ↗
4. LIN Y, GAO M X, ZHU D, et al. Effects of carbon coating and iron phosphides on the electrochemical properties of LiFePO4/C. Journal of Power Sources, 2008,184(2):444-448.10.1016/j.jpowsour.2008.03.026 ↗
5. ZHANG S, GU H, PAN H, et al. A novel strategy to suppress capacity and voltage fading of Li- and Mn-rich layered oxide cathode material for lithium-ion batteries. Advanced Energy Materials, 2017,7(6):1601066.10.1002/aenm.201601066 ↗
6. GENG K M, WU J J, GENG H B, et al. N-doped carbon- encapsulated cobalt nanoparticles on N-doped graphene nanosheets as a high-capacity anode material for lithium-ion storage. Chinese Journal of Inorganic Chemistry, 2016,32(9):1495-1502.
7. ZHANG X F, ZHAO Y, PATEL Y, et al. Potentiometric measurement of entropy change for lithium batteries. Physical Chemistry Chemical Physics, 2017,19(15):9833-9842.10.1039/C6CP08505A ↗
8. DONG H, KOENIG G M. A review on synthesis and engineering of crystal precursors produced via coprecipitation for multicomponent lithium-ion battery cathode materials. CrystEngComm, 2020,22(9):1514-1530.10.1039/C9CE00679F ↗
9. SHEN S, ZHANG S, DENG S, et al. Bioinspired large-scale production of multidimensional high-rate anodes for both liquid & solid-state lithium ion batteries. Journal of Materials Chemistry A, 2019,7(40):22958-22966.10.1039/C9TA08899G ↗
10. AN W, GAO B, MEI S, et al. Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes. Nature Communications, 2019,10(1):1447.10.1038/s41467-019-09510-5 ↗
11. WANG J, CHENG Z N, GUO Y Z, et al. Preparation and electrochemical performance of ordered mesoporous Si/C composite for anode material. Journal of Inorganic Materials, 2018,33(3):313-319.10.15541/jim20170145 ↗
12. GUO S L, KANG S, LU W Q. Ge nanoparticles in MXene sheets: one-step synthesis and highly improved electrochemical property in lithium-ion batteries. Journal of Inorganic Materials, 2020,35(1):105-111.
13. YE X, LIN Z, LIANG S, et al. Upcycling of electroplating sludge into ultrafine Sn@C nanorods with highly stable lithium storage performance. Nano Letters, 2019,19(3):1860-1866.10.1021/acs.nanolett.8b04944 ↗
14. SCHULZE M C, BELSON R M, KRAYNAK L A, et al. Electrodeposition of Sb/CNT composite films as anodes for Li- and Na-ion batteries. Energy Storage Materials, 2020,25:572-584.10.1016/j.ensm.2019.09.025 ↗
15. MCNULTY D, GEANEY H, BUCKLEY D, et al. High capacity binder-free nanocrystalline GeO2 inverse opal anodes for Li-ion batteries with long cycle life and stable cell voltage. Nano Energy, 2018,43:11-21.10.1016/j.nanoen.2017.11.007 ↗
16. LI W, WANG K, CHENG S, et al. A two-dimensional hybrid of SbOx nanoplates encapsulated by carbon flakes as a high performance sodium storage anode. Journal of Materials Chemistry A, 2017,5(3):1160-1167.10.1039/C6TA09265A ↗
17. WANG D, GAO M, PAN H, et al. High performance amorphous- Si@SiOx/C composite anode materials for Li-ion batteries derived from ball-milling and in situ carbonization. Journal of Power Sources, 2014,256:190-199.10.1016/j.jpowsour.2013.12.128 ↗
18. XIA X, ZHANG Y, CHAO D, et al. Solution synthesis of metal oxides for electrochemical energy storage applications. Nanoscale, 2014,6(10):5008-5048.10.1039/C4NR00024B ↗
19. LIANG C, GAO M, PAN H, et al. Lithium alloys and metal oxides as high-capacity anode materials for lithium-ion batteries. Journal of Alloys and Compounds, 2013,575:246-256.10.1016/j.jallcom.2013.04.001 ↗
20. IDOTA Y, KUBOTA T, MATSUFUJI A, et al. Tin-based amorphous oxide: a high-capacity lithium-ion-storage material. Science, 1997,276(5317):1395.10.1126/science.276.5317.1395 ↗
21. WANG R, XU C, SUN J, et al. Solvothermal-induced 3D macroscopic SnO2/nitrogen-doped graphene aerogels for high capacity and long-life lithium storage. ACS Applied Materials & Interfaces, 2014,6(5):3427-3436.10.1021/am405557c ↗
22. WANG L P, LECONTE Y, FENG Z, et al. Novel preparation of N-doped SnO2 nanoparticles via laser-assisted pyrolysis: demonstration of exceptional lithium storage properties. Advanced Materials, 2017,29(6):1603286.10.1002/adma.201603286 ↗
23. ZHOU X, YU L, LOU X W. Nanowire-templated formation of SnO2/carbon nanotubes with enhanced lithium storage properties. Nanoscale, 2016,8(15):8384-8389.10.1039/C6NR01272H ↗
24. ZHANG X, JIANG B, GUO J, et al. Large and stable reversible lithium-ion storages from mesoporous SnO2 nanosheets with ultralong lifespan over 1000 cycles. Journal of Power Sources, 2014,268:365-371.10.1016/j.jpowsour.2014.06.077 ↗
25. LIU S, WANG R, LIU M, et al. Fe2O3@SnO2 nanoparticle decorated graphene flexible films as high-performance anode materials for lithium-ion batteries. Journal of Materials Chemistry A, 2014,2(13):4598-4604.10.1039/C3TA14897A ↗
26. BHASKAR A, DEEPA M, RAO T N. Size-controlled SnO2 hollow spheres via a template free approach as anodes for lithium ion batteries. Nanoscale, 2014,6(18):10762-10771.10.1039/C4NR02505A ↗
27. PANG Y, WANG J, YANG J, et al. Fully reversible lithium storage of tin oxide enabled by self-doping and partial amorphization. Nanoscale, 2019,11(27):12915-12923.10.1039/C9NR03445E ↗
28. ZHOU D, SONG W L, FAN L Z. Hollow core-shell SnO2/C fibers as highly stable anodes for lithium-ion batteries. ACS Applied Materials & Interfaces, 2015,7(38):21472-21478.10.1021/acsami.5b06512 ↗
29. MA C, ZHANG W, HE Y S, et al. Carbon coated SnO2 nanoparticles anchored on CNT as a superior anode material for lithium-ion batteries. Nanoscale, 2016,8(7):4121-4126.10.1039/C5NR07996A ↗
30. WANG J, FANG F, YUAN T, et al. Three-dimensional graphene/ single-walled carbon nanotube aerogel anchored with SnO2 nanoparticles for high performance lithium storage. ACS Applied Materials & Interfaces, 2017,9(4):3544-3553.10.1021/acsami.6b10807 ↗
31. HAN F, LI W C, LI M R, et al. Fabrication of superior performance SnO2@C composites for lithium-ion anodes using tubular mesoporous carbon with thin carbon walls and high pore volume. Journal of Materials Chemistry, 2012,22(19):9645-9651.10.1039/c2jm31359f ↗
32. JAHEL A, GHIMBEU C M, MONCONDUIT L, et al. Confined ultrasmall SnO2 particles in micro/mesoporous carbon as an extremely long cycle-life anode material for Li-ion batteries. Advanced Energy Materials, 2014,4(11):1400025.10.1002/aenm.201400025 ↗
33. NAGPURE S C, BHUSHAN B, BABU S S. Multi-scale characterization studies of aged Li-ion large format cells for improved performance: an overview. Journal of The Electrochemical Society, 2013,160(11):A2111-A2154.10.1149/2.001311jes ↗
34. HE S, LI J, WANG J, et al. Facile synthesis and lithium storage performance of hollow CuO microspheres. Materials Letters, 2014,129:5-7.10.1016/j.matlet.2014.05.034 ↗
35. XIANG J Y, TU J P, ZHANG L, et al. Self-assembled synthesis of hierarchical nanostructured CuO with various morphologies and their application as anodes for lithium ion batteries. Journal of Power Sources, 2010,195(1):313-319.10.1016/j.jpowsour.2009.07.022 ↗
36. WAN M, JIN D, FENG R, et al. Pillow-shaped porous CuO as anode material for lithium-ion batteries. Inorganic Chemistry Communications, 2011,14(1):38-41.10.1016/j.inoche.2010.09.025 ↗
37. HU Y, HUANG X, WANG K, et al. Kirkendall-effect-based growth of dendrite-shaped CuO hollow micro/nanostructures for lithium-ion battery anodes. Journal of Solid State Chemistry, 2010,183(3):662-667.10.1016/j.jssc.2010.01.013 ↗
38. CHEN K, XUE D. Room-temperature chemical transformation route to CuO nanowires toward high-performance electrode materials. The Journal of Physical Chemistry C, 2013,117(44):22576-22583.10.1021/jp4081756 ↗
39. JUNG H R, CHO S J, KIM K N, et al. Electrochemical properties of electrospun CuxO (x=1, 2)-embedded carbon nanofiber with EXAFS analysis. Electrochimica Acta, 2011,56(19):6722-6731.10.1016/j.electacta.2011.05.068 ↗
40. MA Z, RUI K, ZHANG Q, et al. Self-templated formation of uniform F-CuO hollow octahedra for lithium ion batteries. Small, 2017,13(10):1603500.10.1002/smll.201603500 ↗
41. JIA S, WANG Y, LIU X, et al. Hierarchically porous CuO nano- labyrinths as binder-free anodes for long-life and high-rate lithium ion batteries. Nano Energy, 2019,59:229-236.10.1016/j.nanoen.2019.01.081 ↗
42. YIN D, HUANG G, NA Z, et al. CuO nanorod arrays formed directly on Cu foil from MOFs as superior binder-free anode material for lithium-ion batteries. ACS Energy Letters, 2017,2(7):1564-1570.10.1021/acsenergylett.7b00215 ↗
43. XU Y, JIAN G, ZACHARIAH M R, et al. Nano-structured carbon- coated CuO hollow spheres as stable and high rate anodes for lithium- ion batteries. Journal of Materials Chemistry A, 2013,1(48):15486-15490.10.1039/c3ta13698a ↗
44. KO S, LEE J I, YANG H S, et al. Mesoporous CuO particles threaded with CNTs for high-performance lithium-ion battery anodes. Advanced Materials, 2012,24(32):4451-4456.10.1002/adma.201201821 ↗
45. WU S, FU G, LYU W, et al. A single-step hydrothermal route to 3D hierarchical Cu2O/CuO/rGo nanosheets as high-performance anode of lithium-ion batteries. Small, 2018,14(5):1702667.10.1002/smll.201702667 ↗
46. TAN Y, JIA Z, SUN J, et al. Controllable synthesis of hollow copper oxide encapsulated into N-doped carbon nanosheets as high-stability anodes for lithium-ion batteries. Journal of Materials Chemistry A, 2017,5(46):24139-24144.10.1039/C7TA08236C ↗
47. LU X, WANG R, BAI Y, et al. Facile preparation of a three- dimensional Fe3O4/macroporous graphene composite for high- performance Li storage. Journal of Materials Chemistry A, 2015,3(22):12031-12037.10.1039/C5TA01803J ↗
48. WANG R, XU C, SUN J, et al. Three-dimensional Fe2O3 nanocubes/nitrogen-doped graphene aerogels: nucleation mechanism and lithium storage properties. Scientific Reports, 2014,4(1):7171.10.1038/srep07171 ↗
49. CAI J X, LI Z P, LI W, et al. Synthesis and electrochemical performance of Fe2O3 nanofibers as anode materials for LIBs. Journal of Inorganic Materials, 2018,33(3):301-306.10.15541/jim20170095 ↗
50. WANG P, GAO M, PAN H, et al. A facile synthesis of Fe3O4/C composite with high cycle stability as anode material for lithium- ion batteries. Journal of Power Sources, 2013,239:466-474.10.1016/j.jpowsour.2013.03.073 ↗
51. QIN X, ZHANG H, WU J, et al. Fe3O4 nanoparticles encapsulated in electrospun porous carbon fibers with a compact shell as high-performance anode for lithium ion batteries. Carbon, 2015,87:347-356.10.1016/j.carbon.2015.02.044 ↗
52. ZHONG Y, FAN H, CHANG L, et al. Novel iron oxide nanotube arrays as high-performance anodes for lithium ion batteries. Journal of Power Sources, 2015,296:255-260.10.1016/j.jpowsour.2015.07.051 ↗
53. ZHAO B, ZHENG Y, YE F, et al. Multifunctional iron oxide nanoflake/ graphene composites derived from mechanochemical synthesis for enhanced lithium storage and electrocatalysis. ACS Applied Materials & Interfaces, 2015,7(26):14446-14455.10.1021/acsami.5b03477 ↗
54. PARK Y, OH M, PARK J S, et al. Electrochemically deposited Fe2O3 nanorods on carbon nanofibers for free-standing anodes of lithium-ion batteries. Carbon, 2015,94:9-17.10.1016/j.carbon.2015.06.031 ↗
55. QU J, YIN Y X, WANG Y Q, et al. Layer structured α-Fe2O3 nanodisk/reduced graphene oxide composites as high-performance anode materials for lithium-ion batteries. ACS Applied Materials & Interfaces, 2013,5(9):3932-3936.10.1021/am400670d ↗
56. ZOU Y, KAN J, WANG Y. Fe2O3-graphene rice-on-sheet nanocomposite for high and fast lithium ion storage. The Journal of Physical Chemistry C, 2011,115(42):20747-20753.10.1021/jp206876t ↗
57. KAN J, WANG Y. Large and fast reversible Li-ion storages in Fe2O3-graphene sheet-on-sheet sandwich-like nanocomposites. Scientific Reports, 2013,3(1):3502.10.1038/srep03502 ↗
58. LIU N, SHEN J, LIU D. A Fe2O3 nanoparticle/carbon aerogel composite for use as an anode material for lithium ion batteries. Electrochimica Acta, 2013,97:271-277.10.1016/j.electacta.2013.02.111 ↗
59. ZHU X, ZHU Y, MURALI S, et al. Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano, 2011,5(4):3333-3338.10.1021/nn200493r ↗
60. PANG Y, WANG J, ZHOU Z, et al. Core-shell Fe3O4@Fe ultrafine nanoparticles as advanced anodes for Li-ion batteries. Journal of Alloys and Compounds, 2018,735:833-839.10.1016/j.jallcom.2017.11.193 ↗
61. ZHAO J, ZHANG S, LIU W, et al. Fe3O4/ppy composite nanospheres as anode for lithium-ion batteries with superior cycling performance. Electrochimica Acta, 2014,121:428-433.10.1016/j.electacta.2013.12.105 ↗
62. GUO Q, GUO P, LI J, et al. Fe3O4-CNTs nanocomposites: inorganic dispersant assisted hydrothermal synthesis and application in lithium ion batteries. Journal of Solid State Chemistry, 2014,213:104-109.10.1016/j.jssc.2014.02.016 ↗
63. MAO J, NIU D, ZHENG N, et al. Fe3O4-embedded and N-doped hierarchically porous carbon nanospheres as high-performance lithium ion battery anodes. ACS Sustainable Chemistry & Engineering, 2019,7(3):3424-3433.10.1021/acssuschemeng.8b05651 ↗
64. MUSA N, WOO H J, TEO L P, et al. Optimization of Li2SnO3 synthesis for anode material application in Li-ion batteries. Materials Today: Proceedings, 2017,4(4, Part C):5169-5177.10.1016/j.matpr.2017.05.023 ↗
65. HE T, FENG J, RU J, et al. Constructing heterointerface of metal atomic layer and amorphous anode material for high-capacity and fast lithium storage. ACS Nano, 2019,13(1):830-838.10.1021/acsnano.8b08344 ↗
66. TAN H, CHO H W, WU J J. Binder-free ZnO@ZnSnO3 quantum dots core-shell nanorod array anodes for lithium-ion batteries. Journal of Power Sources, 2018,388:11-18.10.1016/j.jpowsour.2018.03.066 ↗
67. GE X, LI Z, WANG C, et al. Metal-organic frameworks derived porous core/shell structured ZnO/ZnCo2O4/C hybrids as anodes for high-performance lithium-ion battery. ACS Applied Materials & Interfaces, 2015,7(48):26633-26642.10.1021/acsami.5b08195 ↗
68. LI G, LI W, XU K, et al. Sponge-like NiCo2O4/MnO2 ultrathin nanoflakes for supercapacitor with high-rate performance and ultra- long cycle life. Journal of Materials Chemistry A, 2014,2(21):7738-7741.10.1039/C4TA01337A ↗
69. RAI A K, GIM J, THI T V, et al. High rate capability and long cycle stability of Co3O4/CoFe2O4 nanocomposite as an anode material for high-performance secondary lithium ion batteries. The Journal of Physical Chemistry C, 2014,118(21):11234-11243.10.1021/jp502004c ↗
70. ISLAM M, ALI G, JEONG M G, et al. Study on the electrochemical reaction mechanism of NiFe2O4 as a high-performance anode for Li-ion batteries. ACS Applied Materials & Interfaces, 2017,9(17):14833-14843.10.1021/acsami.7b01892 ↗
71. LIAO L X, WANG M, FANG T, et al. Synthesis and characterization of ZnFe2O4 anode for lithium ion battery. Journal of Inorganic Materials, 2016,31(1):34-38.10.15541/jim20150272 ↗
72. WANG L, BOCK D C, LI J, et al. Synthesis and characterization of CuFe2O4 nano/submicron wire-carbon nanotube composites as binder-free anodes for Li-ion batteries. ACS Applied Materials & Interfaces, 2018,10(10):8770-8785.10.1021/acsami.8b00244 ↗
73. DENG S, ZHU H, WANG G, et al. Boosting fast energy storage by synergistic engineering of carbon and deficiency. Nature Communications, 2020,11(1):132.10.1038/s41467-019-13945-1 ↗
74. SHEN S, GUO W, XIE D, et al. A synergistic vertical graphene skeleton and S-C shell to construct high-performance TiNb2O7- based core/shell arrays. Journal of Materials Chemistry A, 2018,6(41):20195-20204.10.1039/C8TA06858E ↗
75. YAO Z, XIA X, ZHANG Y, et al. Superior high-rate lithium-ion storage on Ti2Nb10O29 arrays via synergistic TiC/C skeleton and N-doped carbon shell. Nano Energy, 2018,54:304-312.10.1016/j.nanoen.2018.10.024 ↗
76. WU J, PAN G, ZHONG W, et al. Rational synthesis of Cr0.5Nb24.5O62 microspheres as high-rate electrodes for lithium ion batteries. Journal of Colloid and Interface Science, 2020,562:511-517.10.1016/j.jcis.2019.11.085 ↗
77. ETTE P M, CHITHAMBARARAJ A, PRAKASH A S, et al. MoS2 nanoflower-derived interconnected CoMoO4 nanoarchitectures as a stable and high rate performing anode for lithium-ion battery applications. ACS Applied Materials & Interfaces, 2020,12(10):11511-11521.10.1021/acsami.9b20751 ↗
78. YU Z, BAI Y, ZHANG S, et al. Metal-organic framework-derived Zn0.975Co0.025S/CoS2 embedded in N, S-codoped carbon nanotube/ nanopolyhedra as an efficient electrocatalyst for overall water splitting. Journal of Materials Chemistry A, 2018,6(22):10441-10446.10.1039/C8TA01370E ↗
79. WU R, QIAN X, ZHOU K, et al. Porous spinel ZnxCo3-xO4 hollow polyhedra templated for high-rate lithium-ion batteries. ACS Nano, 2014,8(6):6297-6303.10.1021/nn501783n ↗
80. WU L L, WANG Z, LONG Y, et al. Multishelled NixCo3-xO4 hollow microspheres derived from bimetal-organic frameworks as anode materials for high-performance lithium-ion batteries. Small, 2017,13(17):1604270.10.1002/smll.201604270 ↗