Enhanced Lithium Storage Stability Mechanism of Ultra-high Nickel LiNi0.91Co0.06Al0.03O2@Ca3(PO4)2 Cathode Materials
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Abstract
超高镍 LiNi 0.91 Co 0.06 Al 0.03 O 2 @Ca 3 (PO 4 ) 2 正极材料的 储锂稳定性的提升机制 朱河圳 1 , 王选朋 2,3 , 韩 康 1 , 杨 晨 1 , 万睿哲 2 , 吴黎明 1 , 麦立强 1,3 (1.武汉理工大学 材料科学与工程学院, 武汉 430700; 2. 武汉理工大学 理学院, 武汉 430700; 3. 先进能源科学 与技术广东省实验室佛山分中心(佛山仙湖实验室), 佛山 528200) 摘 要: 超高镍正极材料具有高比能、高电压和低成本等特点, 在新一代锂离子电池中备受关注, 但在电池的长循 环过程中会出现微裂纹、机械粉化和不可逆相变, 导致差的循环性能。本研究采用简便的湿化学法制备了一系列 Ca 3 (PO 4 ) 2 包覆的超高镍 LiNi 0.91 Co 0.06 Al 0.03 O 2 材料(NCA@nCP)。其中, NCA@1CP 在 1C (1C=200 mA/g)、2.7~4.3V 下可获得 204.8 mAh/g 的放电比容量, 100 圈循环后容量保持率为 91.5%, 甚至在 2C 的倍率下循环 300 圈后仍保留 153.4 mAh
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OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Materials and Technologies
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References (39)
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