Size Effect of Nanosheet on BN Fibers Derived from BNNS/Polyborazine Hybrid Precursor

1. NACLERIO A E E, KIDAMBI P R R. A review of scalable hexagonal boron nitride (h-BN) synthesis for present and future applications. Advanced Materials , 2023, 35(6): 2207374.10.1002/adma.202207374 ↗

2. WANG B, CAI D, ZHU Q, et al . Mechanical properties and thermal shock resistance of SrAl 2 Si 2 O 8 reinforced BN ceramic composites. Journal of Inorganic Materials , 2024, 39(10): 1182.10.15541/jim20240091 ↗

3. AN L, YU Y, CAI Q, et al . Hexagonal boron nitride nanosheets: preparation, heat transport property and application as thermally conductive fillers. Progress in Materials Science , 2023, 138: 101154.10.1016/j.pmatsci.2023.101154 ↗

4. LIN S, YE F, MA J, et al . Fabrication and properties of porous boron nitride/silicon oxynitride ceramic composites via gas pressure sintering. Materials & Design , 2015, 87: 272.10.1016/j.matdes.2015.08.032 ↗

5. LIAO P, HE H, GUO H, et al . Highly thermally conductive boron nitride fiber. ACS Nano , 2025, 19(16): 16043.10.1021/acsnano.5c02929 ↗

6. WANG Z, GE M, YU S, et al . Microstructures and properties of polymer-derived hexagonal boron nitride fibers with initial gradient oxygen contents. Materials Characterization , 2024, 207: 113503.10.1016/j.matchar.2023.113503 ↗

7. ZOU C, GUO S, ZHOU X. Mechanical property and fracture behavior of borazine-derived bulk boron nitride ceramics reinforced with chopped Si 3 N 4 fiber. Journal of Materials Engineering and Performance , 2025, 34(6): 4821.10.1007/s11665-024-09485-5 ↗

8. MIELE P, BERNARD S, CORNU D, et al . Recent developments in polymer-derived ceramic fibers (PDCFs): preparation, properties and applications-a review. Soft Materials , 2007, 4(2/3/4): 249.10.1080/15394450701310228 ↗

9. DENG C, SONG Y, WANG Y, et al . Synthesis of polymeric precursor for boron nitride through substitution reaction of methylamine/dimethylamine. Acta Chimica Sinica , 2010, 68(12): 1217.

10. HOSSAIN A, SOUVIGNET T, INNIS N R, et al . Two-step ALD process for non-oxide ceramic deposition: the example of boron nitride. Journal of Physics: Materials , 2024, 7(3): 035006.10.1088/2515-7639/ad561e ↗

11. TOURY B, MIELE P, CORNU D, et al . Boron nitride fibers prepared from symmetric and asymmetric alkylaminoborazines. Advanced Functional Materials , 2002, 12(3): 228.10.1002/1616-3028(200203)12:3<228::AID-ADFM228>3.0.CO;2-U ↗

12. LEI Y, WANG Y, SONG Y. Atmosphere influence in the pyrolysis of poly (alkylamino)borazine for the production of BN fibers. Ceramics International , 2013, 39(6): 6847.10.1016/j.ceramint.2013.02.017 ↗

13. LI W, WANG J, XIE Z, et al . Synthesis and characterization of silicon-containing polyborazine to boron nitride ceramic fiber. Acta Chimica Sinica , 2011, 69(16): 1936.

14. DU Y, WANG B, MENG F, et al . Nearly stoichiometric BN fiber with high crystallinity achieved by boron trichloride assisted curing process. Journal of the American Ceramic Society , 2022, 105(1): 82.10.1111/jace.18124 ↗

15. LIU Y, PAN Y, YIN D, et al . Investigations on microstructure and mechanical properties of boron nitride fiber using experimental and numerical methods. Materials Today Communications , 2022, 33: 104554.10.1016/j.mtcomm.2022.104554 ↗

16. BERNARD S, CHASSAGNEUX F, BERTHET M P, et al . Crystallinity, crystalline quality, and microstructural ordering in boron nitride fibers. Journal of the American Ceramic Society , 2005, 88(6): 1607.10.1111/j.1551-2916.2005.00318.x ↗

17. RAJABIFAR N, GHANEMI S, ROSTAMI A, et al . Synergistic impact of hybrid carbon nanotube and graphene on crystallinity and thermo-mechanical behavior of polymer blends. Polymer Composites , 2025, 46(2): 1416.10.1002/pc.29047 ↗

18. SALEHI A, RAHMATI R, KHERADMANDKEYSOMI M, et al . Carbon nanotubes embedded in nanofibrillated EPDM rubber as thermally and electronically conducting polypropylene nanocomposites for flexible electrostatic discharging. ACS Applied Nano Materials , 2025, 8(8): 3847.10.1021/acsanm.4c06456 ↗

19. MANDAL S, ROY D, MUKHOPADHYAY K, et al . Mechanistic insight into the role of the aspect ratio of nanofillers in the gas barrier properties of polymer nanocomposite thin films. RSC Applied Interfaces , 2024, 1(5): 977.10.1039/D3LF00214D ↗

20. FENG L, GUO L, CHEN Q, et al . Tailoring the geometry of silicon nitride nanofillers to simultaneously strengthen and toughen carbon/carbon composites. Journal of Materials Science & Technology , 2024, 202: 183.10.1016/j.jmst.2024.01.100 ↗

21. ZHANG Y, WANG B, DU Y, et al . High crystallinity BN fiber derived from organic-inorganic hybrid BNNS/polyborazine precursor. Journal of the American Ceramic Society , 2025, 108(7): 20439.10.1111/jace.20439 ↗

22. DU Y, WANG B, LI W, et al . Design and synthesis of a novel spinnable polyborazine precursor with high ceramic yield via one-pot copolymerization. Journal of the American Ceramic Society , 2021, 104(11): 5509.10.1111/jace.17950 ↗

23. WANG G, SONG Y. Enhancing mechanical property of SiC fiber by decreasing fiber diameter through a modified melt-spinning process. Journal of Inorganic Materials , 2018, 33(7): 721.10.15541/jim20170512 ↗

24. ZHANG Y, CHEN J, ZHANG H, et al . Hexagonal boron nitride ceramic reinforced with a dispersed glass phase and microdomain-extruded glass fibers. Journal of the European Ceramic Society , 2025, 45(10): 117362.10.1016/j.jeurceramsoc.2025.117362 ↗

25. MIELE P, TOURY B, CORNU D, et al . Borylborazines as new precursors for boron nitride fibers. Journal of Organometallic Chemistry , 2005, 690(11): 2809.10.1016/j.jorganchem.2005.02.039 ↗

26. MIELE P, TOURY B, CHASSAGNEUX F, et al . Correlation between structural features and mechanical properties of boron nitride fibers derived from alkylaminoborazines. Journal of the European Ceramic Society , 2005, 25(2): 157.10.1016/j.jeurceramsoc.2004.07.023 ↗

27. WANG C, HONG C, YAN L, et al . Structural evaluation and mechanical property of boron nitride fibers during melt-drawn fabrication process. International Journal of Applied Ceramic Technology , 2018, 15(3): 660.10.1111/ijac.12857 ↗

28. VINCENT H, CHASSAGNEUX F, VINCENT C, et al . Microtexture and structure of boron nitride fibers by transmission electron microscopy, X-ray diffraction, photoelectron spectroscopy and Raman scattering. Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing , 2003, 340(1/2): 181.10.1016/S0921-5093(02)00185-5 ↗

29. WANG Z, GE M, YU S, et al . Microstructural evolution of polymer-derived hexagonal boron nitride fibers under high-temperature stretching. Journal of Advanced Ceramics , 2023, 12(10): 1973.10.26599/JAC.2023.9220801 ↗

30. GANESH R, OBAID A A, GILLESPIE J W. Experimental determination of bimodal strength distribution of S-glass fibers. Composites Part B: Engineering , 2023, 254: 110559.10.1016/j.compositesb.2023.110559 ↗