Preparation of TiO2 Nanotube Arrays and Their Photoelectrochemical Properties
Source abstract
Abstract
采用声电化学阳极氧化法, 以H 3 PO 4 /NaF水溶液为电解液, 在20V直流电压下氧化钛箔制得TiO 2 纳米管阵列, 其管径约为100nm, 壁厚15~20nm, 管长随氧化时间的增长先增加后减小. 所制TiO 2 纳米管阵列电极在空气中经500℃煅烧后, 以高压汞灯为光源, 测得其光电压和平均光电流密度随制备样品的氧化时间的增长而减小, 且光电压降低程度要小于平均光电流密度降低的程度. 通过伏安曲线和Mott-Schottky图分析还可知, 所制样品的电荷转移能力和电荷载流子密度随阳极氧化时间的增长而减小. 这是由于以H 3 PO 4 /NaF水溶液为电解液, 超声场长时间加速传质过程的同时会引起管状结构的断裂和部分脱落, 从而使得电荷转移阻力增大而影响了光生电荷的传输.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Gas Sensing Nanomaterials and Sensors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (13)
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