Inkjet Printing Preparation of AgCuTe Thermoelectric Thin Films
Source abstract
Abstract
Flexible thermoelectric devices, capable of generating electricity from the slight temperature difference between the human body and the environment, demonstrate significant potential for continuous power supply in wearable devices.However, the poor thermoelectric performance still limits their widespread application.This study reports a method for fabricating high-performance flexible thermoelectric thin films using inkjet printing.AgCuTe nanowires prepared by a chemical transfer method were dispersed in ethanol to form the ink with no significant sedimentation, which could be stably and continuously sprayed to print p-type thermoelectric films on polyimide substrates.Dense thermoelectric films were then obtained through thermal treatment by a spark plasma sintering furnace, and the effect of sintering temperature on thermoelectric properties was studied.The results showed that the film sintered at a pressure of 10 MPa and a temperature of 400 for 15 min possessed a room temperature power factor of 432 Wm -1 K -2 , which is 182% higher than that of inkjet-printed p-type Bi 2 Te 3 films (a
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Thermoelectric Materials and Devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. PEI J, CAI B, ZHUANG H L, et al. Bi2Te3-based applied thermoelectric materials: research advances and new challenges. National Science Review, 2020, 7(12): 1856.10.1093/nsr/nwaa259 ↗
2. JIA B, HUANG Y, WANG Y, et al. Realizing high thermoelectric performance in non-nanostructured n-type PbTe. Energy & Environmental Science, 2022, 15(5): 1920.10.1039/D1EE03883D ↗
3. HU Z, FU Y, JIANG M, et al. Thermal stability of Nb/Mg3SbBi interface. Journal of Inorganic Materials, 2023, 38(8):931.10.15541/jim20230006 ↗
4. HONG M, ZOU J, CHEN Z, et al. Thermoelectric GeTe with diverse degrees of freedom having secured superhigh performance. Advanced Materials, 2019, 31(14):1807071.10.1002/adma.201807071 ↗
5. XU S, SHI X L, DARGUSCH M, et al. Conducting polymer-based flexible thermoelectric materials and devices: from mechanisms to applications. Progress in Materials Science, 2021, 121: 100840.10.1016/j.pmatsci.2021.100840 ↗
6. JIN H, LI J, IOCOZZIA J, et al. Hybride organisch- anorganische thermoelektrische materialien und baueinheiten. Angewandte Chemie International Edition, 2019, 131(43):15348.10.1002/ange.201901106 ↗
7. ZHANG L, SHI X L, YANG Y L, et al. Flexible thermoelectric materials and devices: from materials to applications. Materials Today, 2021, 46: 62.10.1016/j.mattod.2021.02.016 ↗
8. BURTON M, HOWELLS G, ATOYO J, et al. Printed thermoelectrics. Advanced Materials, 2022, 34(18):2108183.10.1002/adma.202108183 ↗
9. LIN Z, HOLLAR C, KANG J S, et al. A solution processable high- performance thermoelectric copper selenide thin film. Advanced Materials, 2017, 29(21):1606662.10.1002/adma.201606662 ↗
10. XU Y, WU B, HOU C, et al. High thermoelectric performance in Ti3C2Tx MXene/Sb2Te3 composite film for highly flexible thermoelectric devices. Global Challenges, 2024, 8(2):2300032.10.1002/gch2.202300032 ↗
11. NEWBROOK D W, RICHARDS S P, GREENACRE V K, et al. Selective chemical vapor deposition approach for Sb2Te3 thin film micro-thermoelectric generators. ACS Applied Energy Materials, 2020, 3(6):5840.10.1021/acsaem.0c00766 ↗
12. ZHENG Z H, SHI X L, AO D W, et al. Harvesting waste heat with flexible Bi2Te3 thermoelectric thin film. Nature Sustainability, 2022, 6(2):180.10.1038/s41893-022-01003-6 ↗
13. SHI J, WU X, GENG X, et al. Anisotropy engineering in solution- derived nanostructured Bi2Te3 thin films for high-performance flexible thermoelectric devices. Chemical Engineering Journal, 2023, 458: 141450.10.1016/j.cej.2023.141450 ↗
14. LIU Y, ZHU H, XING L, et al. Recent advances in inkjet-printing technologies for flexible/wearable electronics. Nanoscale, 2023, 15(13):6025.10.1039/D2NR05649F ↗
15. ZENG M, DU Y, JIANG Q, et al. High-throughput printing of combinatorial materials from aerosols. Nature, 2023, 617(7960):292.10.1038/s41586-023-05898-9 ↗
16. ZHANG D, LIM X J G, LI X, et al. 3D-Printed porous thermoelectrics for in situ energy harvesting. ACS Energy Letters, 2023, 8(1):332.10.1021/acsenergylett.2c02425 ↗
17. BERETTA D, BARKER A J, MAQUEIRA-ALBO I, et al. Thermoelectric properties of highly conductive poly(3,4- ethylenedioxythiophene) polystyrene sulfonate printed thin films. ACS Applied Materials & Interfaces, 2017, 9(21):18151.10.1021/acsami.7b04533 ↗
18. JING J, CHOPPLET L, BATTAGLINI N, et al. The role of substrates and electrodes in inkjet-printed PEDOT: PSS thermoelectric generators. Journal of Materials Chemistry C, 2024, 12(17):6185.10.1039/D4TC00505H ↗
19. JUNTUNEN T, JUSSILA H, RUOHO M, et al. Inkjet printed large-area flexible few-layer graphene thermoelectrics. Advanced Functional Materials, 2018, 28(22):1800480.10.1002/adfm.201800480 ↗
20. FERHAT S, DOMAIN C, VIDAL J, et al. Flexible thermoelectric device based on TiS2HAx n-type nanocomposite printed on paper. Organic Electronics, 2019, 68: 256.10.1016/j.orgel.2019.02.031 ↗
21. HORIKE S, FUKUSHIMA T, SAITO T, et al. Highly stable n-type thermoelectric materials fabricated via electron doping into inkjet-printed carbon nanotubes using oxygen-abundant simple polymers. Molecular Systems Design & Engineering, 2017, 2(5):616.10.1039/C7ME00063D ↗
22. DU J, ZHANG B, JIANG M, et al. Inkjet printing flexible thermoelectric devices using metal chalcogenide nanowires. Advanced Functional Materials, 2023, 33(26):2213564.10.1002/adfm.202213564 ↗
23. LU Z, LAYANI M, ZHAO X, et al. Fabrication of flexible thermoelectric thin film devices by inkjet printing. Small, 2014, 10(17):3551.10.1002/smll.201303126 ↗
24. CHEN B, DAS S R, ZHENG W, et al. Inkjet printing of single- crystalline Bi2Te3 thermoelectric nanowire networks. Advanced Electronic Materials, 2017, 3(4):1600524.10.1002/aelm.201600524 ↗
25. CHEN B, KRUSE M, XU B, et al. Flexible thermoelectric generators with inkjet-printed bismuth telluride nanowires and liquid metal contacts. Nanoscale, 2019, 11(12):5222.10.1039/C8NR09101C ↗
26. ZHANG K, ZHENG Q, WANG L, et al. Preparation and characterization of Ag2Se-based ink used for inkjet printing. Journal of Inorganic Materials, 2022, 37(10):1109.10.15541/jim20220030 ↗
27. LIU Y, ZHANG Q, HUANG A, et al. Fully inkjet-printed Ag2Se flexible thermoelectric devices for sustainable power generation. Nature Communications, 2024, 15(1): 2141.10.1038/s41467-024-46183-1 ↗
28. WANG S, JIANG M, WANG L, et al. n-Type Pb-free AgBiSe2 based thermoelectric materials with stable cubic phase structure. Journal of Inorganic Materials, 2023, 38(7):807.10.15541/jim20220751 ↗
29. LI L, ZHAI W, WANG C, et al. Maximizing phonon scattering efficiency by Cu2Se alloying in AgCuTe thermoelectric materials. Journal of Materials Chemistry A, 2022, 10(12):6701.10.1039/D1TA10692A ↗
30. WEI T, QIU P, ZHAO K, et al. Ag2Q-Based (Q = S, Se, Te) silver chalcogenide thermoelectric materials. Advanced Materials, 2023, 35(1):2110236.10.1002/adma.202110236 ↗
31. WU R, LI Z, LI Y, et al. Synergistic optimization of thermoelectric performance in p-type Ag2Te through Cu substitution. Journal of Materiomics, 2019, 5(3):489.10.1016/j.jmat.2019.01.008 ↗
32. LIU W, YANG L, CHEN Z, et al. Promising and eco-friendly Cu2X-based thermoelectric materials: progress and applications. Advanced Materials, 2020, 32(8):1905703.10.1002/adma.201905703 ↗
33. DENG S, JIANG X, CHEN L, et al. Ultralow thermal conductivity and high thermoelectric performance in AgCuTe1-xSex through isoelectronic substitution. ACS Applied Materials & Interfaces, 2021, 13(1):868.10.1021/acsami.0c17836 ↗
34. JIANG J, ZHU H, NIU Y, et al. Achieving high room-temperature thermoelectric performance in cubic AgCuTe. Journal of Materials Chemistry A, 2020, 8(9):4790.10.1039/C9TA12954E ↗
35. NIU Y, LI S, MAO J, et al. Suppressed phase transition and enhanced thermoelectric performance in iodine-doped AgCuTe. Nano Energy, 2020, 77: 105297.10.1016/j.nanoen.2020.105297 ↗
36. YANG Q, YANG S, QIU P, et al. Flexible thermoelectrics based on ductile semiconductors. Science, 2022, 377(6608):854.10.1126/science.abq0682 ↗
37. LI J, LYU J, YANG W, et al. The remarkable role of indium in synergistically optimizing carrier concentration and phase distribution of AgCuTe-based materials. Small, 2024, 20(28):2311340.10.1002/smll.202311340 ↗
38. LYU J, LI J, YANG W, et al. Enhancing thermoelectric performance in GeTe through Ge enrichment regulation and AgCuTe alloying. Chemical Engineering Journal, 2024, 485: 149695.10.1016/j.cej.2024.149695 ↗
39. MA Z, XU T, LI W, et al. High thermoelectric performance SnTe with a segregated and percolated structure. ACS Applied Materials & Interfaces, 2022, 14(7):9192.10.1021/acsami.1c24075 ↗
40. ROYCHOWDHURY S, JANA M K, PAN J, et al. Soft phonon modes leading to ultralow thermal conductivity and high thermoelectric performance in AgCuTe. Angewandte Chemie International Edition, 2018, 57(15):4043.10.1002/anie.201801491 ↗
41. LUAN X, LI J, WU S, et al. A nanoscale perspective of the coexistence of multidimensional defects in the AgCuTe system. Nano Energy, 2024, 124: 109505.10.1016/j.nanoen.2024.109505 ↗
42. ZENG M, ZAVANELLI D, CHEN J, et al. Printing thermoelectric inks toward next-generation energy and thermal devices. Chemical Society Reviews, 2022, 51(2):485.10.1039/D1CS00490E ↗
43. HU G, ALBROW-OWEN T, JIN X, et al. Black phosphorus ink formulation for inkjet printing of optoelectronics and photonics. Nature Communications, 2017, 8(1):278.10.1038/s41467-017-00358-1 ↗