journal article·2024Open access

Research Progress on Ultra-high Temperature Ceramic Composites

Xinghong ZHANG, Yiming WANG, Yuan CHENG, Shun DONG, Ping HU

Journal of Inorganic Materials· Volume 39· Issue 6

Abstract

In response to the evolving landscape of high-speed aircraft, characterized by an expansive airspace, prolonged flight durations, and increased velocities, the thermal protection requirements for key structures such as the nose cone, leading edge, and engine combustion chamber have become more exacting.This necessitates a concerted focus on the development of high-performance thermal protection materials capable of withstanding extreme conditions.Ultra-high temperature ceramic composites have emerged as noteworthy candidates, showcasing exceptional oxidation and ablation resistance.Despite their commendable properties, the inherent brittleness of these composites poses a significant obstacle to widespread engineering applications.To address this limitation, there is a growing emphasis on toughening through structural modulation.Simultaneously, the imperative to enhance aircraft payload capacity underscores the demand for lightweight ultra-high temperature ceramic (UHTC) composites.This paper provides a systematic overview of the major research advances made in recent years on ultrahigh-temperature ceramic composites, including preparation methods such as pressure sintering, mud impregnation, pre-cursor impregnation cracking, reactive fusion infiltration, chemical vapor-phase infiltration, and solid-liquid combination processes, toughening methods such as particles, whiskers, soft-phase materials, short-cut fibers, and continuous fibers, as well as oxidation ablation-resistant mechanisms and lightweighting design.The relationship between the components, microstructures and properties of UHTC composites is discussed in depth, and the current challenges as well as the future development trends of UHTC composites are presented.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Recycling and utilization of industrial and municipal waste in materials production · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. STOLLERY J L. Hypersonic viscous interaction on curved surfaces. Journal of Fluid Mechanics, 1970, 43(3):497.10.1017/S0022112070002549 ↗
2. OPEKA M M, TALMY I G, ZAYKOSKI J. Oxidation-based materials selection for 2000 ℃+hypersonic aerosurfaces: theoretical considerations and historical experience. Journal of Materials Science, 2004, 39: 5887.10.1023/B:JMSC.0000041686.21788.77 ↗
3. SUTTON G P, BIBLARZ O. Rocket propulsion elements. Hoboken: John Wiley & Sons, Inc., 2016: 540.
4. SCHMIDT D L. Ablative polymers in aerospace technology. Journal of Macromolecular Science—Chemistry, 1969, 3(3):327.10.1080/10601326908053818 ↗
5. SCITI D, ZOLI L, SILVESTRONI L, et al. Design, fabrication and high velocity oxy-fuel torch tests of a Cf-ZrB2-fiber nozzle to evaluate its potential in rocket motors. Materials & Design, 2016, 109: 709.10.1016/j.matdes.2016.07.090 ↗
6. LIFANOV I, YURISHCHEVA A, ASTAPOV A. High-temperature protective coatings on carbon composites. Russian Engineering Research, 2019, 39: 804.10.3103/S1068798X19090132 ↗
7. YOO H I, KIM H S, HONG B G, et al. Hafnium carbide protective layer coatings on carbon/carbon composites deposited with a vacuum plasma spray coating method. Journal of the European Ceramic Society, 2016, 36(7):1581.10.1016/j.jeurceramsoc.2016.01.032 ↗
8. ABDOLLAHI A, EHSANI N, VALEFI Z. High temperature ablation-oxidation performance of SiC nanowhisker toughened- SiC/ZrB2-SiC ultra-high temperature multilayer coatings under supersonic flame. Journal of Alloys and Compounds, 2018, 745: 798.10.1016/j.jallcom.2018.02.234 ↗
9. JIN X, FAN X, LU C, et al. Advances in oxidation and ablation resistance of high and ultra-high temperature ceramics modified or coated carbon/carbon composites. Journal of the European Ceramic Society, 2018, 38(1):1.10.1016/j.jeurceramsoc.2017.08.013 ↗
10. PAUL A, RUBIO V, BINNER J, et al. Evaluation of the high temperature performance of HfB2 UHTC particulate filled Cf/C composites. International Journal of Applied Ceramic Technology, 2017, 14(3):344.10.1111/ijac.12659 ↗
11. FAHRENHOLTZ W G, WUCHINA E J, LEE W E, et al. Ultra- high temperature ceramics:materials for extreme environment applications. Hoboken: John Wiley & Sons, Inc., 2014.10.1002/9781118700853 ↗
12. FAHRENHOLTZ W, HILMAS G. Oxidation of ultra-high temperature transition metal diboride ceramics. International Materials Reviews, 2012, 57(1):61.10.1179/1743280411Y.0000000012 ↗
13. EAKINS E, JAYASEELAN D D, LEE W E. Toward oxidation- resistant ZrB2-SiC ultra high temperature ceramics. Metallurgical and Materials Transactions A, 2011, 42: 878.10.1007/s11661-010-0540-8 ↗
14. OPEKA M M, TALMY I G, WUCHINA E J, et al. Mechanical, thermal, and oxidation properties of refractory hafnium and zirconium compounds. Journal of the European Ceramic Society, 1999, 19(13/14):2405.10.1016/S0955-2219(99)00129-6 ↗
15. FAHRENHOLTZ W G, HILMAS G E, TALMY I G, et al. Refractory diborides of zirconium and hafnium. Journal of the American Ceramic Society, 2007, 90(5):1347.10.1111/j.1551-2916.2007.01583.x ↗
16. LIN J, ZHANG X, HAN W. Comparison of ZrB2-ZrO2f ceramics prepared by hot pressing and pressureless sintering. International Journal of Refractory Metals & Hard Materials, 2012, 35: 102.10.1016/j.ijrmhm.2012.04.007 ↗
17. LIN J, ZHANG X, WANG Z, et al. Microstructure and mechanical properties of hot-pressed ZrB2-SiC-ZrO2f ceramics with different sintering temperatures. Materials & Design, 2012, 34: 853.10.1016/j.matdes.2011.07.023 ↗
18. HU P, GUI K, HONG W, et al. High-performance ZrB2-SiC-Cf composite prepared by low-temperature hot pressing using nanosized ZrB2 powder. Journal of the European Ceramic Society, 2017, 37(6):2317.10.1016/j.jeurceramsoc.2017.02.008 ↗
19. BELLOSI A, MONTEVERDE F, SCITI D. Fast densification of ultra-high-temperature ceramics by spark plasma sintering. International Journal of Applied Ceramic Technology, 2006, 3(1):32.10.1111/j.1744-7402.2006.02060.x ↗
20. HU P, CHENG Y, WANG P, et al. Rolling compacted fabrication of carbon fiber reinforced ultra-high temperature ceramics with highly oriented architectures and exceptional mechanical feedback. Ceramics International, 2018, 44(12):14907.10.1016/j.ceramint.2018.04.249 ↗
21. ZHANG G J, DENG Z Y, KONDO N, et al. Reactive hot pressing of ZrB2-SiC composites. Journal of the American Ceramic Society, 2000, 83(9):2330.10.1111/j.1151-2916.2000.tb01558.x ↗
22. QU Q, HAN J, HAN W, et al. In situ synthesis mechanism and characterization of ZrB2-ZrC-SiC ultra high-temperature ceramics. Materials Chemistry and Physics, 2008, 110(2/3):216.10.1016/j.matchemphys.2008.01.041 ↗
23. WU H Y, ZOU J, ERIKSSON M, et al. Reactive sintering of 2.5D Cf/ZrC-SiC ceramic matrix composite. Journal of the European Ceramic Society, 2021, 41(13):6189.10.1016/j.jeurceramsoc.2021.06.015 ↗
24. EINARSRUD M A, HAGEN E, PETTERSEN G, et al. Pressureless sintering of titanium diboride with nickel, nickel boride and iron additives. Journal of the American Ceramic Society, 1997, 80(12):3013.10.1111/j.1151-2916.1997.tb03227.x ↗
25. RODRíGUEZ-SÁNCHEZ J, SÁNCHEZ-GONZÁLEZ E, GUIBERTEAU F, et al. Contact-mechanical properties at intermediate temperatures of ZrB2 ultra-high-temperature ceramics pressureless sintered with Mo, Ta, or Zr disilicides. Journal of the European Ceramic Society, 2015, 35(11):3179.10.1016/j.jeurceramsoc.2015.04.023 ↗
26. ZHANG S C, HILMAS G, FAHRENHOLTZ W. Pressureless densification of zirconium diboride with boron carbide additions. Journal of the American Ceramic Society, 2006, 89(5):1544.10.1111/j.1551-2916.2006.00949.x ↗
27. HE R, ZHANG X, HU P, et al. Aqueous gelcasting of ZrB2-SiC ultra high temperature ceramics. Ceramics International, 2012, 38(7):5411.10.1016/j.ceramint.2012.03.051 ↗
28. CHEN X, CHENG G, ZHANG J, et al. Residual stress variation in SiCf/SiC composite during heat treatment and its effects on mechanical behavior. Journal of Advanced Ceramics, 2020, 9: 567.10.1007/s40145-020-0395-4 ↗
29. WANG C, PING W, BAI Q, et al. A general method to synthesize and sinter bulk ceramics in seconds. Science, 2020, 368: 521.10.1126/science.aaz7681 ↗
30. WANG R, DONG Q, WANG C, et al. High-temperature ultrafast sintering: exploiting a new kinetic region to fabricate porous solid- state electrolyte scaffolds. Advanced Materials, 2021, 33: 2008161.10.1002/adma.202100726 ↗
31. 程源.Cf/ZrC-SiC复合材料的强韧化与抗氧化性能研究. 哈尔滨: 哈尔滨工业大学博士论文, 2020.
32. BAKER B, RUBIO V, RAMANUJAM P, et al. Development of a slurry injection technique for continuous fibre ultra-high temperature ceramic matrix composites. Journal of the European Ceramic Society, 2019, 39(14):3927.10.1016/j.jeurceramsoc.2019.05.070 ↗
33. SERVADEI F, ZOLI L, GALIZIA P, et al. Development of UHTCMCs via water based ZrB2 powder slurry infiltration and polymer infiltration and pyrolysis. Journal of the European Ceramic Society, 2020, 40(15):5076.10.1016/j.jeurceramsoc.2020.05.054 ↗
34. LI L, WANG Y, CHENG L, et al. Preparation and properties of 2D C/SiC-ZrB2-TaC composites. Ceramics International, 2011, 37(3):891.10.1016/j.ceramint.2010.10.033 ↗
35. UHLMANN F, WILHELMI C, SCHMIDT-WIMMER S, et al. Preparation and characterization of ZrB2 and TaC containing Cf/SiC composites via polymer-infiltration-pyrolysis process. Journal of the European Ceramic Society, 2017, 37(5): 1955.10.1016/j.jeurceramsoc.2016.12.048 ↗
36. LESLIE C J, BOAKYE E E, KELLER K A, et al. Development of continuous SiC fiber reinforced HfB2-SiC composites for aerospace applications. Processing and Properties of Advanced Ceramics and Composites V: Ceramic Transactions, 2013, 240: 1.10.1002/9781118744109.ch1 ↗
37. TAMMANA S M, DUAN M, ZOU J, et al. Ablation behaviour of Cf-ZrC-SiC with and without rare earth metal oxide dopants. Open Ceramics, 2022, 10: 100270.10.1016/j.oceram.2022.100270 ↗
38. ZHOU H, NI D, HE P, et al. Ablation behavior of C/C-ZrC and C/SiC-ZrC composites fabricated by a joint process of slurry impregnation and chemical vapor infiltration. Ceramics International, 2018, 44(5):4777.10.1016/j.ceramint.2017.12.062 ↗
39. ZHU Y, HUANG Z, DONG S, et al. Manufacturing 2D carbon- fiber-reinforced SiC matrix composites by slurry infiltration and PIP process. Ceramics International, 2008, 34(5):1201.10.1016/j.ceramint.2007.02.014 ↗
40. ZHANG D, HU P, DONG S, et al. Microstructures and mechanical properties of Cf/ZrB2-SiC composite fabricated by nano slurry brushing combined with low-temperature hot pressing. Journal of Alloys and Compounds, 2019, 789: 755.10.1016/j.jallcom.2019.03.147 ↗
41. ZHAO X, WANG Y, DUAN L, et al. Improved ablation resistance of C/SiC-ZrB2 composites via polymer precursor impregnation and pyrolysis. Ceramics International, 2017, 43(15):12480.10.1016/j.ceramint.2017.06.118 ↗
42. YAN C, LIU R, ZHA B, et al. Fabrication and properties of 3-dimensional 4-directional Cf/HfC-SiC composites by precursor impregnation and pyrolysis process. Journal of Alloys and Compounds, 2018, 739: 955.10.1016/j.jallcom.2017.12.059 ↗
43. ZHANG J P, FU Q G, WANG L. Preparation, ablation behavior and thermal retardant ability of C/C-HfB2-SiC composites. Materials & Design, 2017, 132: 552.10.1016/j.matdes.2017.07.041 ↗
44. JIA Y, YAO X, SUN J, et al. Effect of ZrC particle size on the ablation resistance of C/C-ZrC-SiC composites. Materials & Design, 2017, 129: 15.10.1016/j.matdes.2017.05.019 ↗
45. WANG Z, DONG S, ZHANG X, et al. Fabrication and properties of Cf/SiC-ZrC composites. Journal of the American Ceramic Society, 2008, 91(10):3434.10.1111/j.1551-2916.2008.02632.x ↗
46. NASLAIN R. Design, preparation and properties of non-oxide CMCs for application in engines and nuclear reactors: an overview. Composites Science and Technology, 2004, 64(2):155.10.1016/S0266-3538(03)00230-6 ↗
47. ZHAO D, ZHANG C, HU H, et al. Preparation and characterization of three-dimensional carbon fiber reinforced zirconium carbide composite by precursor infiltration and pyrolysis process. Ceramics International, 2011, 37(7): 2089.10.1016/j.ceramint.2011.02.024 ↗
48. YANG Y, JAYARAMAN S, KIM D Y, et al. CVD growth kinetics of HfB2 thin films from the single-source precursor Hf(BH4)4. Chemistry of Materials, 2006, 18(21):5088.10.1021/cm0605421 ↗
49. WANG H, CHEN X, GAO B, et al. Synthesis and characterization of a novel precursor-derived ZrC/ZrB2 ultra-high-temperature ceramic composite. Applied Organometallic Chemistry, 2013, 27(2):79.10.1002/aoc.2943 ↗
50. ZHOU H, YANG J, LE G, et al. Effect of ZrC amount and distribution on the thermomechanical properties of Cf/SiC-ZrC composites. International Journal of Applied Ceramic Technology, 2019, 16(4):1321.10.1111/ijac.13217 ↗
51. NISAR A, ZHANG C, BOESL B, et al. A perspective on challenges and opportunities in developing high entropy-ultra high temperature ceramics. Ceramics International, 2020, 46(16):25845.10.1016/j.ceramint.2020.07.066 ↗
52. TONG Y, BAI S, CHEN K. C/C-ZrC composite prepared by chemical vapor infiltration combined with alloyed reactive melt infiltration. Ceramics International, 2012, 38(7):5723.10.1016/j.ceramint.2012.04.017 ↗
53. CHEN X, FENG Q, GAO L, et al. Interphase degradation of three-dimensional Cf/SiC-ZrC-ZrB2 composites fabricated via reactive melt infiltration. Journal of the American Ceramic Society, 2017, 100(10):4816.10.1111/jace.14983 ↗
54. KÜTEMEYER M, SCHOMER L, HELMREICH T, et al. Fabrication of ultra high temperature ceramic matrix composites using a reactive melt infiltration process. Journal of the European Ceramic Society, 2016, 36(15):3647.10.1016/j.jeurceramsoc.2016.04.039 ↗
55. VINCI A, ZOLI L, GALIZIA P, et al. Reactive melt infiltration of carbon fibre reinforced ZrB2/B composites with Zr2Cu. Composites Part A: Applied Science and Manufacturing, 2020, 137: 105973.10.1016/j.compositesa.2020.105973 ↗
56. Ceramic-matrix-composites[2023-12-31]. https://ultramet.com/ceramic-matrix-composites/.
57. ZOU L, WALI N, YANG J M, et al. Microstructural characterization of a Cf/ZrC composite manufactured by reactive melt infiltration. International Journal of Applied Ceramic Technology, 2011, 8(2):329.10.1111/j.1744-7402.2010.02580.x ↗
58. Liquid-rocket-engines[2023-12-31]. https://ultramet.com/propulsion-system-components/liquid-rocket-engines/.
59. CHEN B W, NI D W, WANG J X, et al. Ablation behavior of Cf/ZrC-SiC-based composites fabricated by an improved reactive melt infiltration. Journal of the European Ceramic Society, 2019, 39(15):4617.10.1016/j.jeurceramsoc.2019.07.007 ↗
60. BINNER J, PORTER M, BAKER B, et al. Selection, processing, properties and applications of ultra-high temperature ceramic matrix composites, UHTCMCs—a review. International Materials Reviews, 2020, 65(7):389.10.1080/09506608.2019.1652006 ↗
61. RUBIO V, RAMANUJAM P, BINNER J. Ultra-high temperature ceramic composite. Advances in Applied Ceramics, 2018, 117(sup1):s56.10.1080/17436753.2018.1475140 ↗
62. REN J, FENG E, ZHANG Y, et al. Microstructure and anti-ablation performance of HfC-TaC and HfC-ZrC coatings synthesized by CVD on C/C composites. Ceramics International, 2020, 46(8):10147.10.1016/j.ceramint.2020.01.006 ↗
63. TONG M, FU Q, ZHOU L, et al. Ablation behavior of a novel HfC-SiC gradient coating fabricated by a facile one-step chemical vapor co-deposition. Journal of the European Ceramic Society, 2018, 38(13):4346.10.1016/j.jeurceramsoc.2018.05.034 ↗
64. HU H, ZHANG Y, HE X, et al. Rapid densification of C/SiC composites by joint processes of CLVD and PIP. Materials Letters, 2011, 65(19/20):3137.10.1016/j.matlet.2011.06.100 ↗
65. VIGNOLES G L, DUCLOUS R, GAILLARD S. Analytical stability study of the densification front in carbon-or ceramic- matrix composites processing by TG-CVI. Chemical Engineering Science, 2007, 62(22):6081.10.1016/j.ces.2007.06.022 ↗
66. TANG Z H, QU D N, XIONG J, et al. Effects of infiltration conditions on the densification behavior of carbon/carbon composites prepared by a directional-flow thermal gradient CVI process. Carbon, 2003, 41(14):2703.10.1016/S0008-6223(03)00374-9 ↗
67. TAGUCHI T, NOZAWA T, IGAWA N, et al. Fabrication of advanced SiC fiber/F-CVI SiC matrix composites with SiC/C multi- layer interphase. Journal of Nuclear Materials, 2004, 329: 572.10.1016/j.jnucmat.2004.04.120 ↗
68. VENKATACHALAM V, BLEM S, GÜLHAN A, et al. Thermal qualification of the UHTCMCs produced using RF-CVI technique with VMK facility at DLR. Journal of Composites Science, 2022, 6(1):24.10.3390/jcs6010024 ↗
69. NASLAIN R R, PAILLER R, BOURRAT X, et al. Synthesis of highly tailored ceramic matrix composites by pressure-pulsed CVI. Solid State Ionics, 2001, 141: 541.10.1016/S0167-2738(01)00743-3 ↗
70. CHENG Y, HU P, ZHANG W, et al. One-step introduction of ZrC-SiC inside carbon fabric to fabricate high homogeneous and damage-tolerant composite inspired by vibration. Journal of the European Ceramic Society, 2019, 39(7):2251.10.1016/j.jeurceramsoc.2019.02.030 ↗
71. HU P, CHENG Y, ZHANG D, et al. From ferroconcrete to Cf/UHTC-SiC: a totally novel densification method and mechanism at 1300 °C without pressure. Composites Part B: Engineering, 2019, 174: 107023.10.1016/j.compositesb.2019.107023 ↗
72. HU P, ZHANG D, DONG S, et al. A novel vibration-assisted slurry impregnation to fabricate Cf/ZrB2-SiC composite with enhanced mechanical properties. Journal of the European Ceramic Society, 2019, 39(4):798.10.1016/j.jeurceramsoc.2018.10.029 ↗
73. ZHANG D, HU P, DONG S, et al. Oxidation behavior and ablation mechanism of Cf/ZrB2-SiC composite fabricated by vibration- assisted slurry impregnation combined with low-temperature hot pressing. Corrosion Science, 2019, 161: 108181.10.1016/j.corsci.2019.108181 ↗
74. ZHANG D, FENG J, HU P, et al. Enhanced mechanical properties and thermal shock resistance of Cf/ZrB2-SiC composite via an efficient slurry injection combined with vibration-assisted vacuum infiltration. Journal of the European Ceramic Society, 2020, 40(15):5059.10.1016/j.jeurceramsoc.2020.07.003 ↗
75. SUN J, YU S, WADE-ZHU J, et al. 3D printing of layered ceramic/carbon fiber composite with improved toughness. Additive Manufacturing, 2022, 50: 102543.10.1016/j.addma.2021.102543 ↗
76. FU H, ZHU W, XU Z, et al. Effect of silicon addition on the microstructure, mechanical and thermal properties of Cf/SiC composite prepared via selective laser sintering. Journal of Alloys and Compounds, 2019, 792: 1045.10.1016/j.jallcom.2019.04.129 ↗
77. LV X, YE F, CHENG L, et al. 3D printing “wire-on-sphere” hierarchical SiC nanowires/SiC whiskers foam for efficient high-temperature electromagnetic wave absorption. Journal of Materials Science & Technology, 2022, 109: 94.10.1016/j.jmst.2021.08.054 ↗
78. ZHAO Z, ZHOU G, YANG Z, et al. Direct ink writing of continuous SiO2 fiber reinforced wave-transparent ceramics. Journal of Advanced Ceramics, 2020, 9: 403.10.1007/s40145-020-0380-y ↗
79. KEMP J W, DIAZ A A, MALEK E C, et al. Direct ink writing of ZrB2-SiC chopped fiber ceramic composites. Additive Manufacturing, 2021, 44: 102049.10.1016/j.addma.2021.102049 ↗
80. MEI H, YAN Y, FENG L, et al. First printing of continuous fibers into ceramics. Journal of the American Ceramic Society, 2019, 102(6):3244.10.1111/jace.16234 ↗
81. HAN J, LIU C, BRADFORD-VIALVA R L, et al. Additive manufacturing of advanced ceramics using preceramic polymers. Materials, 2023, 16(13):4636.10.3390/ma16134636 ↗
82. LIU Y, CHENG Y, MA D, et al. Continuous carbon fiber reinforced ZrB2-SiC composites fabricated by direct ink writing combined with low-temperature hot-pressing. Journal of the European Ceramic Society, 2022, 42(9):3699.10.1016/j.jeurceramsoc.2022.03.045 ↗
83. ALFANO D, GARDI R, SCATTEIA L, et al. UHTC-based hot structures: characterization, design, and on-ground/in-flight testing. Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications, 2014: 416.10.1002/9781118700853.ch16 ↗
84. 张东洋.多维度Cf/ZrB2-SiC复合材料的微结构构筑及性能研究. 哈尔滨: 哈尔滨工业大学博士论文, 2020.
85. ASL M S, KAKROUDI M G, NOORI S. Hardness and toughness of hot pressed ZrB2-SiC composites consolidated under relatively low pressure. Journal of Alloys and Compounds, 2015, 619: 481.10.1016/j.jallcom.2014.09.006 ↗
86. KIM S, CHAE J M, LEE S M, et al. Change in microstructures and physical properties of ZrB2-SiC ceramics hot-pressed with a variety of SiC sources. Ceramics International, 2014, 40(2):3477.10.1016/j.ceramint.2013.09.082 ↗
87. SILVESTRONI L, SCITI D, MELANDRI C, et al. Toughened ZrB2- based ceramics through SiC whisker or SiC chopped fiber additions. Journal of the European Ceramic Society, 2010, 30(11): 2155.10.1016/j.jeurceramsoc.2009.11.012 ↗
88. SCITI D, PIENTI L, DALLE FABBRICHE D, et al. Combined effect of SiC chopped fibers and SiC whiskers on the toughening of ZrB2. Ceramics International, 2014, 40(3):4819.10.1016/j.ceramint.2013.09.031 ↗
89. GOLLA B R, MUKHOPADHYAY A, BASU B, et al. Review on ultra-high temperature boride ceramics. Progress in Materials Science, 2020, 111: 100651.10.1016/j.pmatsci.2020.100651 ↗
90. VAFA N P, KAKROUDI M G, ASL M S. Advantages and disadvantages of graphite addition on the characteristics of hot-pressed ZrB2-SiC composites. Ceramics International, 2020, 46(7):8561.10.1016/j.ceramint.2019.12.086 ↗
91. CHENG Y, LYU Y, ZHOU S, et al. Non-axially aligned ZrB2-SiC/ZrB2-SiC-graphene short fibrous monolithic ceramics with isotropic in-plane properties. Ceramics International, 2019, 45(3):4113.10.1016/j.ceramint.2018.10.250 ↗
92. FARAHBAKHSH I, AHMADI Z, ASL M S. Densification, microstructure and mechanical properties of hot pressed ZrB2-SiC ceramic doped with nano-sized carbon black. Ceramics International, 2017, 43(11):8411.10.1016/j.ceramint.2017.03.188 ↗
93. CHENG Y, HU P, ZHOU S, et al. Using macroporous graphene networks to toughen ZrC-SiC ceramic. Journal of the European Ceramic Society, 2018, 38(11):3752.10.1016/j.jeurceramsoc.2018.04.037 ↗
94. TIAN W B, KAN Y M, ZHANG G J, et al. Effect of carbon nanotubes on the properties of ZrB2-SiC ceramics. Materials Science and Engineering: A, 2008, 487(1/2):568.10.1016/j.msea.2007.11.027 ↗
95. JIN H, MENG S, XIE W, et al. HfB2-CNTs composites with enhanced mechanical properties prepared by spark plasma sintering. Ceramics International, 2017, 43(2): 2170.10.1016/j.ceramint.2016.10.200 ↗
96. ZHOU P, HU P, ZHANG X, et al. R-curve behavior of laminated ZrB2-SiC ceramic with strong interfaces. International Journal of Refractory Metals and Hard Materials, 2015, 52: 12.10.1016/j.ijrmhm.2015.04.002 ↗
97. GUI K, LIU F, WANG G, et al. Microstructural evolution and performance of carbon fiber-toughened ZrB2 ceramics with SiC or ZrSi2 additive. Journal of Advanced Ceramics, 2018, 7: 343.10.1007/s40145-018-0284-2 ↗
98. KARIMIRAD S, BALAK Z. Characteristics of spark plasma sintered ZrB2-SiC-SCFs composites. Ceramics International, 2019, 45(5):627510.1016/j.ceramint.2018.12.109 ↗
99. YANG F, ZHANG X, HAN J, et al. Characterization of hot-pressed short carbon fiber reinforced ZrB2-SiC ultra-high temperature ceramic composites. Journal of Alloys and Compounds, 2009, 472: 395.10.1016/j.jallcom.2008.04.092 ↗
100. MOR M, VINCI A, FAILLA S, et al. A novel approach for manufacturing of layered, ultra-refractory composites using pliable, short fibre-reinforced ceramic sheets. Journal of Advanced Ceramics, 2023, 12(1):155.10.26599/JAC.2023.9220674 ↗