Nanocomposite polyacrylonitrile filaments with titanium dioxide and silver nanoparticles for multifunctionality
Source abstract
Abstract
Nanocomposite polyacrylonitrile filaments containing titanium dioxide and silver nanoparticles were produced by wet-spinning method with the aim of developing multifunctional filaments showing antibacterial activity, photocatalytic activity, and electrical conductivity. The nanocomposite filaments were characterized regarding their morphology, composition, nanoparticle dispersion, tensile properties, crystallinity, conductivity, thermal properties, photocatalytic, and antibacterial activity. The nanoparticles were observed to be well dispersed. The composite filaments with 3 wt% silver nitrate showed improved crystallinity. The highest breaking tenacity of 8.72 cN/tex was observed for the filament with 1 wt% TiO 2 and 3 wt% AgNO 3 . The conductivity of the nanocomposite filaments were on the order of 10 −4 S/cm, which is in the semiconductive range. The nanocomposite filaments displayed both antibacterial and photocatalytic activity. This study showed the possibility of producing multifunctional filaments with the simultaneous addition of different types of nanoparticles into the filament structure.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Microplastics and Plastic Pollution · Nanoparticles: synthesis and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Textile Engineering, Istanbul Technical University, Istanbul, Turkey
Department of Chemistry, Istanbul Technical University, Istanbul, Turkey
References (100+)
Show source-provided references
1. 10.1080/00405167.2011.57002710.1080/00405167.2011.570027 ↗
2. 10.1177/004051750809106610.1177/0040517508091066 ↗
3. 10.1177/004051750935765210.1177/0040517509357652 ↗
4. Joshi M. The impact of nanotechnology on polyesters, polyamides and other textiles. In: Deopura BL, Alagirusamy R, Joshi M, et al. (eds) Polyesters and Polyamides. 2008th ed. Cambridge, England: CRC, 2008, pp. 354–416.10.1533/9781845694609.2.354 ↗
5. 10.1002/app.3321810.1002/app.33218 ↗
6. 10.3390/coatings403067010.3390/coatings4030670 ↗
7. 10.1016/j.apsusc.2006.07.08610.1016/j.apsusc.2006.07.086 ↗
8. Taher FA · Aust J Basic Appl Sci · 2012 · 6 · 596
9. Kizildag N and Ucar N. Investigation of the properties of PAN/f-MWCNTs/AgNPs composite nanofibers. J Ind Text 2017; 47: 149–172.10.1177/1528083716632807 ↗
10. 10.1007/s10853-014-8748-410.1007/s10853-014-8748-4 ↗
11. Cho U. Novel antimicrobial textiles . PhD Thesis, Auburn University, USA, 2003.
12. 10.1023/A:102376782865610.1023/A:1023767828656 ↗
13. 10.1007/s10853-005-4339-810.1007/s10853-005-4339-8 ↗
14. 10.1016/j.matlet.2005.02.03310.1016/j.matlet.2005.02.033 ↗
15. Yazdanshenas ME · J Eng Fiber Fabr · 2012 · 7 · 69
16. 10.1002/pen.2217910.1002/pen.22179 ↗
17. Sun H · J Appl Polym Sci · 2016 · 134 · 4450110.1002/app.44501 ↗
18. Abdulbaki MK and Tung WH. Synthetic fibers with enhanced soil resistance and methods for production and use thereof. Patent WO 2016179384 A1, USA, 2016.
19. 10.1016/j.compscitech.2004.03.01010.1016/j.compscitech.2004.03.010 ↗
20. 10.4028/www.scientific.net/SSP.151.4310.4028/www.scientific.net/SSP.151.43 ↗
21. Maeda N. Far infra-red radiant composite fiber. Patent. US 4999243 A, USA, 1995.
22. 10.4236/ojopm.2012.2200510.4236/ojopm.2012.22005 ↗
23. 10.1021/ja044619310.1021/ja0446193 ↗
24. 10.1177/095400830934191910.1177/0954008309341919 ↗
25. 10.1002/pi.166110.1002/pi.1661 ↗
26. 10.1002/app.2816410.1002/app.28164 ↗
27. 10.1111/cote.1217910.1111/cote.12179 ↗
28. Dastjerdi R · J Eng Fiber Fabr · 2014 · 9 · 39
29. Smole MS, Hribernik S, Veronovski N, et al. Electrokinetic properties of nanocomposite fibres. In: Reddy B (ed) Advances in Nanocomposites—Synthesis, Characterization and Industrial Applications . Crotia: InTech, 2011, pp. 403–428.
30. 10.1002/masy.20045062910.1002/masy.200450629 ↗
31. 10.1002/app.2331210.1002/app.23312 ↗
32. 10.1002/app.3095010.1002/app.30950 ↗
33. 10.1007/s11051-010-0100-610.1007/s11051-010-0100-6 ↗
34. 10.1002/pat.136010.1002/pat.1360 ↗
35. 10.1007/s12221-016-6314-110.1007/s12221-016-6314-1 ↗
36. 10.1155/2012/71821410.1155/2012/718214 ↗
37. 10.1016/j.jphotochem.2004.11.01010.1016/j.jphotochem.2004.11.010 ↗
38. 10.1016/j.molcata.2005.03.04010.1016/j.molcata.2005.03.040 ↗
39. 10.1021/jp050219610.1021/jp0502196 ↗
40. 10.1177/00405175030730091210.1177/004051750307300912 ↗
41. Rios PF · Polym Advan Technol · 2008 · 19 · 168410.1002/pat.1208 ↗
42. Kan CW · Int J Chem Eng Appl · 2014 · 5 · 219
43. 10.1016/j.surfcoat.2014.05.03510.1016/j.surfcoat.2014.05.035 ↗
44. 10.1016/j.dyepig.2013.01.01510.1016/j.dyepig.2013.01.015 ↗
45. Quiñones-Jurado ZV · Mater Sci Appl · 2014 · 5 · 895
46. Kulthong K · Part Fibre Toxicol · 2010 · 7 · 110.1186/1743-8977-7-8 ↗
47. Meric Z. Antistatic applications: metal coated fibers by magnetron sputtering . PhD Thesis, Izmir Institute of Technology, Izmir, 2011.
48. 10.1177/002199831663573110.1177/0021998316635731 ↗
49. Shayestehfar S · J Eng Fiber Fabr · 2014 · 9 · 158
50. http://textilelibrary.weebly.com/polyacrylonitrile-pan-mfg-process.html (accessed 11 January 2017).
51. https://www.gore.com/resources/data-sheet-woven-homopolymer-acrylic-polyphenylene-sulfide-filter-bag-305-g-m2-9-oz-yd2 (accessed 11 January 2017).
52. http://www.sefar.com.au/en/388/Filtration-Filter-fabrics-for-Filtration-separation.htm? Article=1280905 (accessed 11 January 2017).
53. ASTM International, D3822. Standard test method for tensile properties of single textile fibers, developed by subcommittee: D13.58, Book of Standards Volume: 07.01.
54. ASTM International, D257. Standard test methods for DC resistance or conductance of insulating materials. Developed by subcommittee: D09.12, Book of Standards Volume: 10.01.
55. ASTM International, D4496. Standard test method for DC resistance or conductance of moderately conductive materials. Standard test method for D-C resistance or conductance of moderately conductive materials. Developed by subcommittee: D09.12, Book of Standards Volume: 10.02.
56. 10.1016/0032-3861(78)90167-210.1016/0032-3861(78)90167-2 ↗
57. ASTM International, E2149. Standard test method for determining the antimicrobial activity of antimicrobial agents under dynamic contact conditions. Developed by subcommittee: E35.15, Book of Standards Volume: 11.05.
58. Rujitanaroj P · J Appl Polym Sci · 2010 · 116 · 196710.1002/app.31498 ↗
59. Kizildag N and Ucar N. Electrospinning functional polyacrylonitrile nanofibers with polyaniline, carbon nanotubes and silver nitrate as additives, In: Haider S and Haider A (eds) Electrospinning—Material, Techniques, and Biomedical Applications . Crotia: InTechOpen, 2016, pp. 25–43.10.5772/65472 ↗
60. 10.1080/0040500950863133710.1080/00405009508631337 ↗
61. 10.1016/j.colsurfb.2010.03.02910.1016/j.colsurfb.2010.03.029 ↗
62. 10.1107/S010876819100335X10.1107/S010876819100335X ↗
63. 10.1177/152808371455369010.1177/1528083714553690 ↗
64. 10.1016/j.matlet.2005.05.01610.1016/j.matlet.2005.05.016 ↗
65. 10.1016/S0167-577X(03)00470-110.1016/S0167-577X(03)00470-1 ↗
66. 10.1016/S0266-3538(97)00156-510.1016/S0266-3538(97)00156-5 ↗
67. 10.1007/BF0268186810.1007/BF02681868 ↗
68. 10.1016/j.compositesb.2012.04.02810.1016/j.compositesb.2012.04.028 ↗
69. Fundamentals of semiconductor physics: Insulator, semiconductor, conductor, http://www.optique-ingenieur.org/en/courses/OPI_ang_M05_C02/co/Contenu_02.html (accessed 12 May 2016).
70. More about materials science: metals, semiconductors and insulators, http://chemed.chem.purdue.edu/genchem/topicreview/bp/materials/defects3.html (accessed 12 May 2016).
71. Cho SH, Song KT and Lee JY. Recent advances in polypyrrole. In: Skotheim TA and Reynold J (eds) Handbook of conducting polymers . 3rd ed. Florida: CRC Press, 2007, pp. 8–41.
72. 10.1016/0008-6223(75)90259-610.1016/0008-6223(75)90259-6 ↗
73. 10.1088/0957-4484/19/8/08560510.1088/0957-4484/19/8/085605 ↗
74. 10.1007/s10904-012-9713-910.1007/s10904-012-9713-9 ↗
75. 10.1021/am100508910.1021/am1005089 ↗
76. 10.1016/j.seppur.2014.06.04010.1016/j.seppur.2014.06.040 ↗
77. 10.1016/j.jhazmat.2007.01.09710.1016/j.jhazmat.2007.01.097 ↗
78. 10.1016/j.colsurfb.2013.03.00810.1016/j.colsurfb.2013.03.008 ↗
79. Sichani GN · J Appl Polym Sci · 2010 · 116 · 102110.1002/app.31436 ↗
80. 10.1016/j.eurpolymj.2011.04.00210.1016/j.eurpolymj.2011.04.002 ↗
81. 10.1002/app.3507610.1002/app.35076 ↗
82. 10.1016/j.jcis.2004.02.01210.1016/j.jcis.2004.02.012 ↗
83. Prabhu S · Int Nano Lett · 2012 · 32 · 2
84. 10.1016/j.saa.2005.05.00210.1016/j.saa.2005.05.002 ↗
85. 10.1016/j.nano.2006.12.00110.1016/j.nano.2006.12.001 ↗
86. 10.1002/1097-4636(20001215)52:4<662::AID-JBM10>3.0.CO;2-310.1002/1097-4636(20001215)52:4<662::AID-JBM10>3.0.CO;2-3 ↗
87. 10.1088/0957-4484/16/10/05910.1088/0957-4484/16/10/059 ↗
88. Kubacka A · Scient Reports · 2014 · 4 · 110.1038/srep04134 ↗
89. 10.1088/0957-4484/23/42/42560610.1088/0957-4484/23/42/425606 ↗
90. 10.1016/j.jphotobiol.2014.12.01010.1016/j.jphotobiol.2014.12.010 ↗
91. 10.1016/j.porgcoat.2011.11.00510.1016/j.porgcoat.2011.11.005 ↗
92. 10.1007/s00253-011-3213-710.1007/s00253-011-3213-7 ↗
93. 10.1021/la046983l10.1021/la046983l ↗
94. Maness PC · Appl Environ Microbiol · 1999 · 65 · 409410.1128/AEM.65.9.4094-4098.1999 ↗
95. 10.1007/s10295-005-0006-y10.1007/s10295-005-0006-y ↗
96. 10.1128/AEM.01079-0710.1128/AEM.01079-07 ↗
97. 10.1016/j.watres.2006.08.00410.1016/j.watres.2006.08.004 ↗
98. 10.2147/IJN.S1457210.2147/IJN.S14572 ↗
99. 10.1128/AEM.02218-0610.1128/AEM.02218-06 ↗
100. 10.1021/la703594910.1021/la7035949 ↗