journal article·2016-08

Window p-layer in amorphous pin solar cells using ZnO as Transparent Conductive Oxide

B. Mereu, O. Caglar, J.S. Cashmore, P.A. Losio, A. Salabas, I. Sinicco

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Abstract

Abstract The main steps of p-layer development in pin thin film amorphous silicon solar cell at TEL Solar are presented. First, the implementation of a new PECVD reactor is shown to contribute to an improvement in amorphous silicon carbide (a-SiC) p-layer quality probably by reducing the porosity and leading to an increased open circuit voltage after the solar cell is subjected to light soaking. Second, an alternative high flow deposition regime for the p-doped a-SiC layer was successfully developed improving the layer purity and electrical conductivity. And third, a softer deposition regime for the very first part of the p-layer, the contact layer, which plays a crucial role in the release of Zn from the TCO, contributes to a decreased overall Zn contamination.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Thin-Film Transistor Technologies · Silicon and Solar Cell Technologies · Silicon Carbide Semiconductor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Substitutional doping of amorphous silicon10.1016/0038-1098(75)90284-7 ↗
2. 2010
3. Street · 1991
4. a-SiC:H/a-Si:H heterojunction solar cell having more than 7.1% conversion efficiency10.1063/1.92692 ↗
5. Photoemission studies of amorphous semiconductor heterojunctions10.1016/0022-3093(85)90823-3 ↗
6. Theory of band lineups in amorphous semiconductor heterojunctions10.1016/0022-3093(87)90207-9 ↗
7. Amorphous silicon oxide window layers for high-efficiency silicon heterojunction solar cells10.1063/1.4861404 ↗
8. M. Kubon, E. Boehmer, M. Gastel, F. Siebke, W. Beyer, C. Beneking, et al., Solution of the ZnO/p contact problem in a-Si:H solar cells, in: Proceedings of the IEEE, 1994, pp. 500–503. 〈http://dx.doi.org/10.1109/WCPEC.1994.520007〉.10.1109/WCPEC.1994.520007 ↗
9. Critical concentration of Zinc in amorphous silicon solar cells10.1016/j.solmat.2015.08.003 ↗
10. H. Goldbach, T. Roschek, S. Benagli, B. Mereu, Photovoltaic Cell And Method of Manufacturing a Photovoltaic Cell, 2010. 〈http://www.google.com.ar/patents/WO2010020469A3?cl=en〉.
11. Tobias Roschek, Marco Apolloni, Antonio Braga, Adrian Brunner, Onur Caglar, Julian S. Cashmore, et al., MICROMORPH Technology: Introduction and the Path to Record Efficiencies, 2015. 〈http://dx.doi.org/10.13140/RG.2.1.1628.8804〉.
12. Chapter 2: the optical absorption edge of a-Si: H10.1016/S0080-8784(08)62910-5 ↗
13. P.A. Losio, L. Wang, S. Smith, S. Biswas, Accurate SIMS Quantification Dopants Impurities Thin Film Amorphous Silicon Microcrystals Silicon Solar Cells, 2010. 〈http://dx.doi.org/10.4229/25thEUPVSEC2010-3AV.1.60〉.
14. Improved conversion efficiencies of thin-film silicon tandem (MICROMORPH™) photovoltaic modules10.1016/j.solmat.2015.08.022 ↗
15. Record 12.34% stabilized conversion efficiency in a large area thin-film silicon tandem (MICROMORPH™) module: 12.34% stabilized efficiency in a large area module10.1002/pip.2642 ↗
16. Optical properties of porous silicon (1984–1993): correlation with microstructure
17. Reactor design for a-Si:H deposition
18. Amorphous silicon p-i-n solar cells with graded interface10.1063/1.97430 ↗
19. Open-circuit voltage physics in amorphous silicon solar cells10.1557/PROC-609-A18.3 ↗
20. Fluorine counter doping effect in B-doped Si10.1063/1.2790373 ↗
21. Hydrogen passivation and thermal reactivation of zinc double acceptors in silicon10.1016/0921-5107(89)90211-0 ↗