journal article·2026Open access

Mean-field model for the bubble size distribution in coarsening wet foams

Jacob Morgan, Simon Cox

Soft Matter· Volume 22· Issue 7

Abstract

Aqueous foams are subject to coarsening, whereby gas from the bubbles diffuses through the liquid phase. Gas is preferentially transported from small to large bubbles, resulting in a gradual decrease of the number of bubbles and an increase in the average bubble size. Coarsening foams are expected to approach a scaling state at late times in which their statistical properties are invariant. However, a model predicting the experimentally observed bubble-size distribution in the scaling state of foams with moderate liquid content, as a function of the liquid fraction ϕ, has not yet been developed. To this end, we propose a three-dimensional mean-field bubble growth law for foams without inter-bubble adhesion, validated against bubble-scale simulations, and use it to derive a prediction of the scaling-state bubble-size distribution for any ϕ from zero up to the unjamming transition ϕc ≈ 36%. We verify that the derived scaling state is approached from a variety of initial conditions using mean-field simulations implementing the proposed growth law. Comparing our predicted bubble-size distribution with previous simulations and experimental results, we likewise find a large population of small bubbles when ϕ > 0, but there are qualitative differences from prior results which we attribute to the absence of rattlers, i.e. bubbles not pressed into contact with their neighbours, in our model.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Pickering emulsions and particle stabilization · Enhanced Oil Recovery Techniques · Fluid Dynamics and Mixing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mathematics, Aberystwyth University, Aberystwyth, UK

Funding

Horizon 2020 Framework Programme · European Space Agency · Engineering and Physical Sciences Research Council

References (80)

Show source-provided references
1. D.Weaire and S.Hutzler , The Physics of Foams , Oxford University Press , Oxford (GB) , 1999
2. I.Cantat , S.Cohen-Addad , F.Elias , F.Graner , R.Höhler , O.Pitois , F.Rouyer and A.Saint-Jalmes , Foams: Structure and Dynamics , Oxford University Press , Oxford (GB) , 201310.1093/acprof:oso/9780199662890.001.0001 ↗
3. Stewart · Annu. Rev. Fluid Mech. · 2023 · 55 · 32310.1146/annurev-fluid-032822-125417 ↗
4. T. J.Martin , in Foam Engineering: Fundamentals and Applications , ed. P. Stevenson , John Wiley & Sons Ltd , Chichester (GB) , 2012 , ch. 17, pp. 411–45710.1002/9781119954620.ch17 ↗
5. P.Stevenson and N. W. A.Lambert , in Foam Engineering: Fundamentals and Applications , ed. P. Stevenson , John Wiley & Sons Ltd , Chichester (GB) , 2012 , ch. 11, pp. 229–24910.1002/9781119954620 ↗
6. Lemlich · Ind. Eng. Chem. Fundam. · 1978 · 17 · 8910.1021/i160066a003 ↗
7. Schimming · Phys. Rev. E · 2017 · 96 · 03280510.1103/PhysRevE.96.032805 ↗
8. Isert · Eur. Phys. J. E:Soft Matter Biol. Phys. · 2013 · 36 · 11610.1140/epje/i2013-13116-x ↗
9. Roth · Phys. Rev. E · 2013 · 87 · 04230410.1103/PhysRevE.87.042304 ↗
10. Born · Rev. Sci. Instrum. · 2021 · 92 · 12450310.1063/5.0062946 ↗
11. Lifshitz · J. Exp. Theor. Phys. · 1959 · 35 · 331
12. Wagner · Z. Elektrochem. · 1961 · 65 · 581
13. Mullins · J. Appl. Phys. · 1986 · 59 · 134110.1063/1.336528 ↗
14. Glazier · J. Phys.: Condens. Matter · 1992 · 4 · 1867
15. Stavans · Rep. Prog. Phys. · 1993 · 56 · 73310.1088/0034-4885/56/6/002 ↗
16. Thomas · Phys. Rev. E · 2006 · 74 · 02140710.1103/PhysRevE.74.021407 ↗
17. Lambert · Phys. Rev. Lett. · 2010 · 104 · 24830410.1103/PhysRevLett.104.248304 ↗
18. Pasquet · Soft Matter · 2023 · 19 · 626710.1039/D3SM00535F ↗
19. Fortuna · Phys. Rev. Lett. · 2012 · 108 · 24830110.1103/PhysRevLett.108.248301 ↗
20. Thomas · Colloids Surf., A · 2015 · 473 · 10910.1016/j.colsurfa.2015.02.015 ↗
21. Khakalo · Phys. Rev. E · 2018 · 98 · 01260710.1103/PhysRevE.98.012607 ↗
22. Galvani · Proc. Natl. Acad. Sci. U. S. A. · 2023 · 120 · e230655112010.1073/pnas.2306551120 ↗
23. Galvani · J. Colloid Interface Sci. · 2025 · 696 · 13766110.1016/j.jcis.2025.137661 ↗
24. D. J.Durian , arXiv , 2023 , preprint, arXiv:2304.00415 10.48550/arXiv.2304.0041510.48550/arXiv.2304.00415 ↗
25. Marqusee · J. Chem. Phys. · 1983 · 79 · 37310.1063/1.445532 ↗
26. Morgan · J. Fluid Mech. · 2024 · 999 · A1010.1017/jfm.2024.756 ↗
27. Bolton · Philos. Mag. B · 1991 · 63 · 79510.1080/13642819108205538 ↗
28. White · Mater. Sci. Eng. · 1979 · 40 · 1510.1016/0025-5416(79)90004-1 ↗
29. Li · Acta Mater. · 2022 · 237 · 11819610.1016/j.actamat.2022.118196 ↗
30. Gardiner · J. Phys.: Condens. Matter · 1999 · 11 · 5437
31. Princen · J. Phys. Chem. · 1968 · 72 · 334210.1021/j100855a050 ↗
32. Cox · Soft Matter · 2018 · 14 · 592210.1039/C8SM00739J ↗
33. Princen · J. Colloid Interface Sci. · 1979 · 71 · 5510.1016/0021-9797(79)90221-2 ↗
34. Yarranton · J. Colloid Interface Sci. · 1997 · 196 · 15710.1006/jcis.1997.5186 ↗
35. Chieco · Phys. Rev. E · 2023 · 108 · 03460610.1103/PhysRevE.108.034606 ↗
36. Hillert · Acta Metall. · 1965 · 13 · 22710.1016/0001-6160(65)90200-2 ↗
37. Ardell · Acta Metall. · 1972 · 20 · 6110.1016/0001-6160(72)90114-9 ↗
38. Streitenberger · Acta Mater. · 2013 · 61 · 502610.1016/j.actamat.2013.04.042 ↗
39. Höhler · Soft Matter · 2021 · 17 · 699510.1039/D1SM00823D ↗
40. De Smet · Langmuir · 1997 · 13 · 688410.1021/la970379b ↗
41. Brown · Acta Metall. · 1989 · 37 · 7110.1016/0001-6160(89)90267-8 ↗
42. Svoboda · Acta Mater. · 2022 · 235 · 11808510.1016/j.actamat.2022.118085 ↗
43. Princen · Langmuir · 1986 · 2 · 51910.1021/la00070a023 ↗
44. Kraynik · Phys. Rev. Lett. · 2004 · 93 · 20830110.1103/PhysRevLett.93.208301 ↗
45. Markworth · J. Colloid Interface Sci. · 1985 · 107 · 56910.1016/0021-9797(85)90211-5 ↗
46. Brakke · Exp. Math. · 1992 · 1 · 14110.1080/10586458.1992.10504253 ↗
47. K. A.Brakke , Surface Evolver v2.70 a, 2013 , https://kenbrakke.com/evolver/evolver.html , (accessed August 2023)
48. Kähärä · Phys. Rev. E · 2014 · 90 · 03230710.1103/PhysRevE.90.032307 ↗
49. Boromand · Phys. Rev. Lett. · 2018 · 121 · 24800310.1103/PhysRevLett.121.248003 ↗
50. J.Morgan and S.Cox , Data for: Effects of liquid fraction and contact angle on structure and coarsening in two-dimensional foams , 2023, Aberystwyth University (PURE) 10.20391/b2be2c00-151e-43df-90ed-5c900af5516010.20391/b2be2c00-151e-43df-90ed-5c900af55160 ↗
51. SciPy contributors, SciPy v1.10.1 , 2023 , https://scipy.org , (accessed July 2025)
52. Mukesh · Langmuir · 1992 · 8 · 80710.1021/la00039a014 ↗
53. K.Khakalo , K.Baumgarten , B. P.Tighe and A.Puisto , arXiv , 2017 , preprint, arXiv:1706.03932 10.48550/arXiv.1706.0393210.48550/arXiv.1706.03932 ↗
54. Wang · Soft Matter · 2021 · 17 · 990110.1039/D1SM01228B ↗
55. Van Liedekerke · Biomech. Model. Mechanobiol. · 2020 · 19 · 18910.1007/s10237-019-01204-7 ↗
56. Quey · Comput. Method. Appl. Mech. Eng. · 2011 · 200 · 172910.1016/j.cma.2011.01.002 ↗
57. R.Quey , Neper v4.5.0, 2022, https://neper.info , (accessed Sep 2025)
58. Lambert · Phys. Rev. Lett. · 2007 · 99 · 05830410.1103/PhysRevLett.99.058304 ↗
59. Maestro · Soft Matter · 2013 · 9 · 253110.1039/c2sm27668b ↗
60. Binder · Phys. Rev. B · 1977 · 15 · 442510.1103/PhysRevB.15.4425 ↗
61. Streitenberger · Scr. Mater. · 2006 · 55 · 46110.1016/j.scriptamat.2006.05.009 ↗
62. Zöllner · Scr. Mater. · 2006 · 54 · 169710.1016/j.scriptamat.2005.12.042 ↗
63. Requier · J. Colloid Interface Sci. · 2025 · 696 · 13782510.1016/j.jcis.2025.137825 ↗
64. Lambert · Europhys. Lett. · 2012 · 99 · 4800310.1209/0295-5075/99/48003 ↗
65. NumPy contributors, NumPy v1.24.3 , 2023 , https://numpy.org , (accessed July 2025)
66. Quey · Comput. Method. Appl. Mech. Eng. · 2018 · 330 · 30810.1016/j.cma.2017.10.029 ↗
67. R. A.Adams and C.Essex , Calculus: A Complete Course , Pearson , Toronto (CA) , 8th edn, 2013
68. Gardiner · Philos. Mag. A · 2000 · 80 · 98110.1080/01418610008212094 ↗
69. Feng · Int. J. Multiphase Flow · 2021 · 143 · 10378210.1016/j.ijmultiphaseflow.2021.103782 ↗
70. Petit · Phys. Rev. Res. · 2025 · 7 · L02207310.1103/mtcv-dbpd ↗
71. Boromand · Soft Matter · 2019 · 15 · 585410.1039/C9SM00775J ↗
72. Durian · Phys. Rev. Lett. · 1995 · 75 · 478010.1103/PhysRevLett.75.4780 ↗
73. Batchelor · J. Fluid Mech. · 1970 · 41 · 54510.1017/S0022112070000745 ↗
74. Evans · Phys. Rev. Lett. · 2013 · 111 · 13830110.1103/PhysRevLett.111.138301 ↗
75. Jorjadze · Phys. Rev. Lett. · 2013 · 110 · 04830210.1103/PhysRevLett.110.048302 ↗
76. Princen · Langmuir · 1988 · 4 · 16410.1021/la00079a030 ↗
77. L. D.Landau , E. M.Lifshitz , A. M.Kosevich and L. P.Pitaevskiĭ , Theory of Elasticity , Elsevier , Oxford (GB) , 3rd edn, 1986
78. D.Exerowa and P. M.Kruglyakov , Foam and Foam Films: Theory, Experiment, Application , Elsevier , Amsterdam (NL) , 1998 , p. 90
79. Dittmann · J. Colloid Interface Sci. · 2016 · 467 · 14810.1016/j.jcis.2015.12.055 ↗
80. Zimnyakov · Phys. D · 2019 · 398 · 17110.1016/j.physd.2019.03.008 ↗