Layering of bidisperse charged nanoparticles in sedimentation
Source abstract
Abstract
Bidisperse mixtures of charged nanoparticles form separate layers upon centrifugation as a result of minimization of the system's free energy in sedimentation-diffusion equilibrium. Different factors were investigated experimentally for their effects on the layering, and are supported by theoretical calculations of the full sedimentation profiles. Surprisingly, lighter/smaller nanoparticles can even sink below heavier/larger ones when the particle surface charge is carefully tuned. This study provides deeper insights into the control of layering in polydisperse particle mixtures during sedimentation.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrostatics and Colloid Interactions · Field-Flow Fractionation Techniques · Material Dynamics and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory of Physical Chemistry
Department of Chemical Engineering and Chemistry
Eindhoven University of Technology
5612 AE Eindhoven
The Netherlands
Wetsus
European Centre of Excellence for Sustainable Water Technology
8911 MA Leeuwarden
Physical Chemistry
University of Konstanz
78457 Konstanz
Germany
Institute for Molecules and Materials
Radboud University
6525 AJ Nijmegen
Funding
H2020 Marie Skłodowska-Curie Actions
References (34)
Show source-provided references
1. Brown · J. Inst. Fuel · 1939 · 13 · 15
2. Möbius · Nature · 2001 · 414 · 27010.1038/35104697 ↗
3. Rosato · Phys. Rev. Lett. · 1987 · 58 · 103810.1103/PhysRevLett.58.1038 ↗
4. Huerta · Phys. Rev. Lett. · 2004 · 92 · 11430110.1103/PhysRevLett.92.114301 ↗
5. Breu · Phys. Rev. Lett. · 2003 · 90 · 01430210.1103/PhysRevLett.90.014302 ↗
6. Shinbrot · Nature · 2004 · 429 · 35210.1038/429352b ↗
7. Serrano · Nat. Mater. · 2011 · 10 · 71610.1038/nmat3068 ↗
8. H. Cölfen , in Analytical Ultracentrifugation: Techniques and Methods , ed. D. J. Scott and others, Royal Society of Chemistry , Cambridge, UK , 2005 , vol. 23, pp. 501–583
9. Xu · Nano Lett. · 2019 · 19 · 113610.1021/acs.nanolett.8b04496 ↗
10. Xu · ChemPhysChem · 2019 · 20 · 179910.1002/cphc.201900299 ↗
11. Van Blaaderen · Langmuir · 1992 · 8 · 292110.1021/la00048a013 ↗
12. Verhaegh · Langmuir · 1994 · 10 · 142710.1021/la00017a019 ↗
13. Ma · Chem. Mater. · 2015 · 27 · 411910.1021/acs.chemmater.5b01222 ↗
14. S. Uchiyama , F.Arisaka , W. F.Stafford and T.Laue , Analytical Ultracentrifugation , Springer , Tokyo , 201610.1007/978-4-431-55985-6 ↗
15. Pearson · Anal. Chem. · 2018 · 90 · 128010.1021/acs.analchem.7b04056 ↗
16. Zhao · Curr. Protoc. Protein Sci. · 2013 · 71 · 20.12.110.1002/0471140864.ps2012s71 ↗
17. Biesheuvel · J. Phys.: Condens. Matter · 2004 · 16 · L499
18. Spruijt · J. Phys.: Condens. Matter · 2014 · 26 · 075101
19. P. Y. Julien , Erosion and sedimentation , Cambridge University Press , 201010.1017/CBO9780511806049 ↗
20. van der Hoeven · Nanoscale · 2019 · 11 · 530410.1039/C8NR09753D ↗
21. Osseo-Asare · Colloids Surf. · 1990 · 50 · 32110.1016/0166-6622(90)80273-7 ↗
22. Giesche · J. Eur. Ceram. Soc. · 1994 · 14 · 18910.1016/0955-2219(94)90087-6 ↗
23. Bryant · Phys. Rev. E · 2002 · 66 · 6050110.1103/PhysRevE.66.060501 ↗
24. Royall · Soft Matter · 2013 · 9 · 1710.1039/C2SM26245B ↗
25. van der Linden · Soft Matter · 2013 · 9 · 1161810.1039/c3sm51752g ↗
26. Pusey · Nature · 1986 · 320 · 34010.1038/320340a0 ↗
27. Soda · J. Phys. Chem. · 1967 · 71 · 427410.1021/j100872a018 ↗
28. Correia · Biophys. Chem. · 1976 · 5 · 25510.1016/0301-4622(76)80038-5 ↗
29. Johnston · Trans. Faraday Soc. · 1945 · 41 · 58810.1039/tf9454100588 ↗
30. Dhont · J. Phys. Chem. · 2004 · 120 · 163210.1063/1.1633546 ↗
31. Pham · Aust. J. Chem. · 2007 · 60 · 66210.1071/CH07138 ↗
32. Chen · J. Am. Chem. Soc. · 2009 · 131 · 421810.1021/ja900809z ↗
33. Sun · Angew. Chem., Int. Ed. · 2009 · 48 · 93910.1002/anie.200805047 ↗
34. Qiu · Adv. Mater. · 2011 · 23 · 488010.1002/adma.201102636 ↗