journal article·2017-01-02

On the steady shear behavior of hydrophobic fumed silica suspensions in PPG and PEG of low molecular weight

F. J. Rubio-Hernández, A. I. Gómez-Merino, N. M. Páez-Flor, J. F. Velázquez-Navarro

Soft Materials· Volume 15· Issue 1
Publisher page

Abstract

Fumed silica with n-hexadecane molecules anchored onto its surface (Aerosil®R816) was dispersed in polypropylene glycol of low molecular weight (PPG400). This system showed a complex steady shear behavior: shear-thickening between two shear-thinning regions. Only shear-thinning behavior was observed when R816 was dispersed in polyethylene glycol of low molecular weight (PEG200). To conciliate both experimental results, Raman spectra of linear hexadecane, n-hexadecane/PPG400, and n-hexadecane/PEG200 mixtures were obtained. Results pointed out a distinct population of conformers could exist in each n-hexadecane-polymer mixture. More specifically, alkyl chains acquired straighter conformation in the PPG400 solvent, while the same alkyl chains showed globular conformations in PEG200.
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Research context

OpenAlex topics: Surfactants and Colloidal Systems · Advanced Polymer Synthesis and Characterization · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

DECEM, Universidad de las Fuerzas Armadas, Sangolquí, Ecuador

Departamento de Física Aplicada II, Universidad de Málaga, Málaga, Spain

Departamento de Ingeniería Mecánica, Térmica y de Fluidos, Universidad de Málaga, Málaga, Spain

Funding

Secretaría de Educación Superior, Ciencia, Tecnología e Innovación

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