DataVXSoft MaterialsPaper
journal article·2017-07-03Open access

Two-component organogels of phosphorous-based organic acids and diamine

Kaiqi Fan, Xiaobo Wang, Guanglu Han, Libo Niu, Xuzhao Yang, Zhigang Yin, Jian Song

Soft Materials· Volume 15· Issue 3
Publisher pageOpen full text
Source abstract

Abstract

Phosphorous-based organic acids (P) and diamine (M) were used to produce a supramolecular PM complex at a 2:1 molar ratio, which then formed a stable gel in dimethyl sulfoxide (DMSO) and N, N-dimethylformamide (DMF). According to SEM, the morphologies of the aggregates depended on the steric substitute of phosphorous-based organic acids and the structure of the complementary diamine. 31P NMR and FTIR spectroscopies revealed that hydrogen bonding within the PM complex was the main driving force for the self-aggregation. XRD studies revealed that the two-component gelators mainly assemble into a stricter lamellar structure when increasing the rigidity of the complementary component. In contrast, the gelators with the aliphatic unit mainly assembled into a random lamellar structure and showed more possibility of deforming. As such, the results in this paper demonstrate how structure effects in two-component gel system of phosphorous-based organic acids and diamine can control self-assembly process.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Polydiacetylene-based materials and applications · Lipid Membrane Structure and Behavior

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou PR China

Journal Editorial Department, Zhengzhou University of Light Industry, Zhengzhou PR China

Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, Baoding PR China

School of Chemical Engineering and Technology, Tianjin University, Tianjin China

Funding

College Innovation Program · the National Natural Science Foundation of China · Foundation of He’nan Educational Committee · Science and Technique Foundation of He’nan Province of China · Research Fund of Zhengzhou University of Light Industry · Scientific Research Foundation for the Doctoral Program

References (28)

Show source-provided references
1. 10.1016/j.jconrel.2007.09.01410.1016/j.jconrel.2007.09.014 ↗
2. Buerkle L.E. · Chemical Sciences · 2012 · 3 · 564
3. 10.1021/ja027277e10.1021/ja027277e ↗
4. 10.1002/zaac.20057004610.1002/zaac.200570046 ↗
5. Vemula P.K. · Communication · 2006 · 2218
6. 10.1021/cr970028210.1021/cr9700282 ↗
7. 10.1039/b807346e10.1039/b807346e ↗
8. 10.1002/chem.20050024110.1002/chem.200500241 ↗
9. Bag B.G. · Letters · 2006 · 8 · 5457
10. 10.1039/b715462c10.1039/b715462c ↗
11. 10.1021/om200298710.1021/om2002987 ↗
12. 10.1021/om200331710.1021/om2003317 ↗
13. 10.1002/adma.20130191410.1002/adma.201301914 ↗
14. 10.1002/chem.20100059610.1002/chem.201000596 ↗
15. 10.1039/C6RA19492C10.1039/C6RA19492C ↗
16. 10.1039/c3993000138210.1039/c39930001382 ↗
17. Maitra U. · Communication · 1999 · 595
18. 10.1039/C6SM00372A10.1039/C6SM00372A ↗
19. 10.1002/chem.20130210010.1002/chem.201302100 ↗
20. 10.1002/chem.20080147510.1002/chem.200801475 ↗
21. 10.1021/la025514l10.1021/la025514l ↗
22. 10.1039/c3sm27421g10.1039/c3sm27421g ↗
23. 10.1039/c3sm50814e10.1039/c3sm50814e ↗
24. 10.1016/0022-1902(57)80016-510.1016/0022-1902(57)80016-5 ↗
25. 10.1039/c3tc31595a10.1039/c3tc31595a ↗
26. 10.1021/jp400813f10.1021/jp400813f ↗
27. 10.1021/ja036111q10.1021/ja036111q ↗
28. 10.1016/j.jcis.2009.04.05510.1016/j.jcis.2009.04.055 ↗