Source abstract
Abstract
Rational heterostructure design can bring interfacial polarization relaxation to significantly enhance the electromagnetic wave (EMW) absorption performance. However, intelligently building a homogeneous heterostructure with superior EMW absorption properties remains a great challenge. Herein, a typical conductive metal–organic framework Cu3(HHTP)2 (hexahydroxytriphenylene, HHTP) is delicately packed onto a polypyrrole (PPy) conductive polymer surface via a one‐step in situ polymerization approach. Results show that Cu3(HHTP)2 is well packed on the PPy surface to form an elegant Cu3(HHTP)2@PPy hybrids interfacial microstructure with a unique superiority regarding EMW absorption compared with single components of PPy and Cu3(HHTP)2. Interestingly, the interfacial microstructure of Cu3(HHTP)2@PPy hybrids can be tuned by adjusting the composition of the PPy and Cu3(HHTP)2, resulting in the improvement of impedance matching, conductive loss, and enhancement of interfacial polarization relaxation, endowing the optimization of the EM wave absorption properties of the Cu3(HHTP)2@PPy. The broad effective absorption bandwidth covers a range as broad as 6.68 GHz (11.00–17.68 GHz), which is higher than most reported metal‐organic frameworks (MOFs) and conductive polymer‐based EM absorbing materials. Herein, new insight for developing highly efficient EMW absorption materials through hybridized interfacial microstructure engineering is provided.
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Research context
OpenAlex topics: Electromagnetic wave absorption materials · Advanced Antenna and Metasurface Technologies · Metamaterials and Metasurfaces Applications
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Affiliations
MIIT Key Laboratory of Advanced Display Materials and Devices Institute of Optoelectronics and Nanomaterials College of Materials Science and Engineering Nanjing University of Science and Technology Nanjing 210094 China
School of Chemistry and Chemical Engineering Nanjing University of Science and Technology Nanjing 210094 China
School of Mechanical Engineering Nanjing University of Science and Technology Nanjing 210094 China
School of Safety Science and Engineering Nanjing University of Science and Technology Nanjing 210094 China
Funding
National Natural Science Foundation of China · Fundamental Research Funds for the Central Universities
References (31)
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