Stable Low‐Temperature Al Batteries Enabled by Integrating Polydopamine‐Derived N‐Doped Carbon Nanospheres With Flake Graphite

Abstract The battery performance declines significantly in severely cold areas, especially discharge capacity and cycle life, which is the most significant pain point for new energy consumers. To address this issue and improve the low‐temperature characteristic of aluminum‐ion batteries, in this work, polydopamine‐derived N‐doped carbon nanospheres are utilized to modify the most promising graphite material. More active sites are introduced into graphite, more ion transport channels are provided, and improved ionic conductivity is achieved in a low‐temperature environment. Due to the synergistic effect of the three factors, the ion diffusion resistance is significantly reduced and the diffusion coefficient of aluminum complex ions in the active material become larger at low temperatures. Therefore, the battery delivers an improved capacity retention rate from 23% to 60% at −20 °C and excellent ultra‐long cycling stability over 5500 cycles at −10 °C. This provides a novel strategy for constructing low‐temperature aluminum‐ion batteries with high energy density, which is conducive to promoting the practicality of aluminum‐ion batteries.