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journal article·2023-10Open access

Nanographene‐Based Decoration as a Panchromatic Antenna for Metalloporphyrin Conjugates (Small 42/2023)

Saül Garcia‐Orrit, Victor Vega‐Mayoral, Qiang Chen, Gianluca Serra, Giuseppe M. Paternò, Enrique Cánovas, Akimitsu Narita, Klaus Müllen, Matteo Tommasini, Juan Cabanillas‐González

Small· Volume 19· Issue 42
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Source abstract

Abstract

Metalloporphyrin Conjugates In article number 2301596, Matteo Tommasini, Juan Cabanillas-González, and co-workers reveal the photophysics of a fused nanographene–metalloporphyrin. The diagram shows the unveiled relaxation pathways of excited states. Photoexcitation populates ligand-centered singlets, transitioning via intersystem crossing to metal-centered triplets, then relaxing to ligand-centered triplets. Molecular orbital configurations are likened to a butterfly's wings, resembling open-closed positions.
Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials

OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Electrochemical sensors and biosensors · Surface Chemistry and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Madrid Institute for Advanced Studies IMDEA Nanociencia c/Faraday 9 Campus de Cantoblanco Madrid 28049 Spain

Max Planck Institute for Polymer Research Ackermannweg 10 55128 Mainz Germany

Dipartimento di Chimica Materiali ed Ingegneria Chimica “G. Natta” Politecnico di Milano Piazza Leonardo da Vinci 32 Milano 20133 Italy

Physics Department Politecnico di Milano Piazza Leonardo Da Vinci 32 Milano 20133 Italy

Organic and Carbon Nanomaterials Unit Okinawa Institute of Science and Technology Graduate University Okinawa 904‐0495 Japan

Institute for Physical Chemistry Johannes Gutenberg University Mainz Duesbergweg 10–14 55128 Mainz Germany<?vsp 90pt?>

References

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