journal article·2022-04

Hydrocracking of Waste Palm Cooking Oil into Hydrocarbon Compounds over Mo Catalyst Impregnated on SBA-15

Gesha Desy Alisha, Wega Trisunaryanti, Akhmad Syoufian

Silicon· Volume 14· Issue 5
Publisher page

Abstract

The highest activity and selectivity results were achieved in the presence of Mo metal supported by SBA-15. Mo/SBA-15 catalyst was synthesized using the wet impregnation method. Catalysts were characterized using FTIR, XRD, Surface Area Analyzer (SAA), and SEM-EDX. Mo/SBA-15 has pore diameters, surface area, and Mo metal concentration of 561.4 m2/g, 6.53 nm, and 4.41%, respectively. The hydrocracking process was carried out at a temperature of 500 °C with a ratio of catalyst: feed weight 1: 100. The best catalyst for hydrocracking of waste palm cooking oil was Mo/SBA-15. The presence of Mo metal is role play in the hydrocracking process because it can increase the activity and selectivity of the catalyst. In addition, decreased pore diameter and surface area also affect the hydrocracking process. The total liquid product produced by the Mo/SBA-15 catalyst was 53.86 wt.%. The results of the conversion of liquid products analyzed using GC-MS showed a total hydrocarbon compound of 50.35 wt.%. The fraction of gasoline produced was 42.46 wt.% and the fraction of diesel fuel produced was 7.89 wt.%.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Catalysis and Hydrodesulfurization Studies · Biodiesel Production and Applications · Catalysis for Biomass Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Lam SS, Mahari WAW, Cheng CK, Omar R, Chong CT, Chase HA (2016) Recovery of diesel-like fuel from waste palm oil by pyrolysis using a microwave heated bed of activated carbon. Energy 115:791–799. https://doi.org/10.1016/j.energy.2016.09.07610.1016/j.energy.2016.09.076 ↗
2. Khodadadi MR, Malpartida I, Tsang C, Lin CSK, Len C (2020) Recent advances on the catalytic conversion of waste cooking oil. Mol Catal 494:111128. https://doi.org/10.1016/j.mcat.2020.11112810.1016/j.mcat.2020.111128 ↗
3. Lovas P, Hudec P, Hadinová M, Ház A (2015) Use of ZSM-5 catalyst in deoxygenation of waste cooking oil. Chem Zvesti 69(11):1454–1464. https://doi.org/10.1515/chempap-2015-015910.1515/chempap-2015-0159 ↗
4. Hidalgo JM, Horaček J, Matoušek L, Vráblik A, Tišler Z, Černý R (2018) Catalytic hydrocracking of vacuum residue and waste cooking oil mixtures. Monatsh Chem. 149:1167-1177. https://doi.org/10.1007/s00706-018-2171-510.1007/s00706-018-2171-5 ↗
5. Pacheo-Sosa JG, Castillo-Escobeda AI, Chavrria-Hernandez JC, Díaz-Félix MC, Pérez-Vidal H, Ordónez LC, García-Dávila J, Morales-Ortuno JC, Escobar B (2019) Catalytic deoxygenation of stearic acid and waste cooking oil over Pd/ SBA-15 for obtaining hydrocarbons with potential as renewable liquid fuels. J Porous Mater 26:1541-1557. https://doi.org/10.1007/s10934-019-00749-310.1007/s10934-019-00749-3 ↗
6. Sadrameli SM (2016) Thermal/catalytic cracking of liquid hydrocarbons for the production of olefins: a state-of-the-art review II: Catalytis cracking review. Fuel 173:285–297. https://doi.org/10.1016/j.fuel.2016.01.04710.1016/j.fuel.2016.01.047 ↗
7. Prado CMR, Filho NRA (2009) Production and characterization of the biofuels obtained by thermal cracking and thermal catalytic cracking of vegetable oils. J Anal Appl Pyrolisis 86:338–347. https://doi.org/10.1016/j.jaap.2009.08.00510.1016/j.jaap.2009.08.005 ↗
8. Zhao Y, Wang W, Jing X, Gong X, Wen H, Deng Y (2020) Catalytic cracking of polypropylene by using Fe-SBA-15 synthesiezed in an acid-free medium for production of lighy hydrocarbon oils. J Anal Appl Pyrolisis 146:104755. https://doi.org/10.1016/j.jaap.2019.10475510.1016/j.jaap.2019.104755 ↗
9. Sriningsih W, Saerodji MG, Trisunaryanti W, Triyono AR, Falah II (2014) Fuel production from LDPE plastic waste over natural zeolite supported Ni, Ni-Mo, co, and co-Mo metals. Procedia Environ Sci 20:215–224. https://doi.org/10.1016/j.proenv.2014.03.02810.1016/j.proenv.2014.03.028 ↗
10. Zhao X, Wei L, Julson J, Gu Z, Cao Y (2015) Catalytic cracking of inedible camelina oils to hydrocarbon fuels over bifunctional Zn/ZSM-5 catalysts. Korean J Chem Eng 32(8):1528–1541. https://doi.org/10.1007/s11814-015-0028-810.1007/s11814-015-0028-8 ↗
11. Chumachenko VA, Lavrenov AV, Buluchevskii EA, Arbuzov AB, Gulyaeva TI, Drozdov VA (2016) Hydrocracking of vegetable oil on boron-containing catalyst: effect of the nature and content of a hydrogenation component. Catal Ind 8:56–74. https://doi.org/10.1134/S207005041601003710.1134/S2070050416010037 ↗
12. Trisunaryanti W, Suarsih E, Triyono FII (2019) Well-dispersed nickel nanoparticles on the external and internal surfaces of SBA-15 for hydrocracking of pyrolyzed α-celluose. RSC Adv 9:1230–1237. https://doi.org/10.1039/c8ra09034c10.1039/c8ra09034c ↗
13. Restrepo-Garcia JR, Baldovino-Medrano VG, Giraldo SA (2016) Improving the selectivity in hydrocracking of phenathrene over mesoporous Al-SBA-15 based Fe-W catalysts by enhacing mesoporosity and acidity. Appl Catal A Gen 510:98–109. https://doi.org/10.1016/j.apcata.2015.10.05110.1016/j.apcata.2015.10.051 ↗
14. Li J, Fang X, Bian J, Guo Y, Li C (2018) Microalgae hydrothermal liquefaction and derived biocrude upgrading with modified SBA-15 catalysts. Bioresour Technol 266:541–547. https://doi.org/10.1016/j.biortech10.1016/j.biortech ↗
15. Hidalgo JM, Pineda A, Arancon RAD, Cerny R, Climent MS, Romero AA, Luque R (2015) Continuous-flow Hydroisomerization of C5–C7 alkanes using mechanochemically synthesized supported Pt and Pd–SBA-15 materials. J Flow Chem 5(1):11–16. https://doi.org/10.1556/JFC-D-14-0002910.1556/JFC-D-14-00029 ↗
16. Zhang X, Zhang F, Yan X, Zhang Z, Sun F, Wang Z, Zhao D (2008) Hydrocracking of heavy oil using zeolites Y/AL-SBA-15 composites as catalyst supports. J Porous Mater 15:145–150. https://doi.org/10.1007/s10934-007-9114-610.1007/s10934-007-9114-6 ↗
17. Qiu S, Zhang Q, Lv W, Wang T, Zhang Q, Ma L (2017) Simply packaging Ni nanoparticles inside SBA-15 channels by co-impregnation for dry reforming of methane. RSC Adv 7:24551–24560. https://doi.org/10.1039/c7ra00149e10.1039/c7ra00149e ↗
18. Ameen M, Azizan MT, Ramli A, Yusup S, Abdullah A (2020) The effect of metal loading over Ni/γ-Al2O3 and Mo/γ-Al2O3 catalysts on reaction routes of hydrodeoxygenation of rubber seed oil for green diesel production. Catal Today 355:51–64. https://doi.org/10.1016/j.cattod.2019.03.02810.1016/j.cattod.2019.03.028 ↗
19. Ramesh A, Tamizhdurai P, Krishnan PS, Ponnusamy VK, Sakthinathan S, Shanthi K (2020) Catalytic transformation of non-edible oils to biofuels through hydrodeoxygenation using Mo-Ni/mesoporous alumina-silica catalysts. Fuel 262:116494. https://doi.org/10.1016/j.fuel.2019.11649410.1016/j.fuel.2019.116494 ↗
20. Yan L, Kui W, Xuan-lin G, Wei-yan W, Yun-quan Y (2018) A comparison of MoS 2 catalysts hydrothermally synthesized from different sulfur precursors in their morphology and hydrodeoxygenation activity. J Fuel Chem Technol 46(5):535–542. https://doi.org/10.1016/S1872-5813(18)30023-910.1016/S1872-5813(18)30023-9 ↗
21. Santi D, Trisunaryanti W, Falah II (2020) Hydrocracking of pyrolyzed α-cellulose to hydrocarbon over MxOy/Mesoporous carbon catalyst ( M = co and Mo ): synthesis and characterization of carbon-based catalyst support from saw waste of Merbau. J Environ Chem Eng 8(3):103735. https://doi.org/10.1016/j.jece.2020.10373510.1016/j.jece.2020.103735 ↗
22. Escola JM, Serrano DP, Arroyo M, Alba A (2014) Conversion of LDPE into transportation fuels by a two-stage process using Ni/Al-SBA-15 as catalyst. J Mater Cycles Waste Manag 16:435–441. https://doi.org/10.1007/s10163-014-0249-710.1007/s10163-014-0249-7 ↗
23. Jiang B, Zhu T, Song H, Li F (2019) Hydrodeoxygenation and hydrodesulfurization over Fe promoted Ni2P/SBA-15 catalyst. J Alloys Compd 806:254–262. https://doi.org/10.1016/j.jallcom.2019.07.24210.1016/j.jallcom.2019.07.242 ↗
24. Barbosa FA, Santos ACB, Silva MIP, Stumbo AM (2004) Resistabce to poisoning by nitrogen compounds of NiMo/Al-MCM-41 hydrocracking catalysts. Catal Today 98:109–113. https://doi.org/10.1016/j.cattod.2004.07.02510.1016/j.cattod.2004.07.025 ↗
25. Chen L, Hu J, Qi Z, Fang Y, Richards R (2011) Gold nanoparticles intercalated into the walls of mesoporous silica as verssatile redox catalyst. Ind Eng Chem Res 50:13642–16349. https://doi.org/10.1021/ie200606t10.1021/ie200606t ↗
26. Ghosh BK, Hazra S, Naik B, Ghosh NN (2015) Preparation of Cu nanoparticle loaded SBA-15 and their excellent catalytic activity in reduction of variety of dyes. Powder Technol 209:371–378. https://doi.org/10.1016/j.powder.2014.09.02710.1016/j.powder.2014.09.027 ↗
27. Dong W, Mansour AN, Dunn B (2001) Structural and electrochemichal properties of amorphous and crystalline molybdenum oxide aerogels. Solid State Ionics 144:31–40. https://doi.org/10.1016/S0167-2738(01)00901-810.1016/S0167-2738(01)00901-8 ↗
28. Ballesteros-plata D, Infantes-molina A, Rodríguez-castellón E (2019) Study of bifunctionality of Pt / SBA-15 catalysts for HDO of Dibenzofuran reaction : addition of Mo or use of an acidic support. Appl Catal A Gen 580:93–101. https://doi.org/10.1016/j.apcata.2019.05.00210.1016/j.apcata.2019.05.002 ↗
29. Dhar GM, Kumaran GM, Kumar M, Rawat KS, Sharma LD, Raju BD, Rao KSR (2005) Physico-chemical characterization and catalysis on SBA-15 supported molybdenum hydrotreating catalysts. Catal Today 99:309–314. https://doi.org/10.1016/j.cattod.2004.10.00510.1016/j.cattod.2004.10.005 ↗
30. Hu Z, Lu S, Huang X, Li J, Duan Y, Yan L Yao Y, Liao X (2018) Molybdenum anchored on NH2-modified spherical SiO2 : A highly efficient and stable catalyst for oxidative desulfurization of fuel oil. Appl Organometal Chem 1–10. https://doi.org/10.1002/aoc.452110.1002/aoc.4521 ↗
31. Bukhari SN, Chong CC, Setiabudi HD, Cheng YW, Teh LP, Jalil AA (2021) Ni/fibrous type SBA-15: highly active and coke resistant catalyst for CO2 methanation. Chem Eng Sci 229:116141. https://doi.org/10.1016/j.ces.2020.11614110.1016/j.ces.2020.116141 ↗
32. Yoon S, Choi WC, Park Y, Kim HY, Lee CW (2010) Catalytic hydrocracking of bitumen at mild experimental condition. Korean J Chem 27(1):62–65. https://doi.org/10.1007/s11814-009-0316-210.1007/s11814-009-0316-2 ↗
33. Peng H, Min L, Qiu-lian C (2020) MoO3/Al-SBA-15 modified catalyst and its application in coal tar hydrocracking. J Fuel Chem Technol 48(9):1079–1086. https://doi.org/10.1016/S1872-5813(20)30072-410.1016/S1872-5813(20)30072-4 ↗
34. Kusumastuti H, Trisunaryanti W, Falah II, Marsuki MF (2018) Synthesis of mesoporous silica-alumina from lapindo mud as a support of Ni and Mo metals catalysts for hydrocracking of pyrolyzed α-cellulose. Rasayan J Chem 11(2):522–530. https://doi.org/10.7324/RJC.2018.112206110.7324/RJC.2018.1122061 ↗
35. Zhao X, Wei L, Cheng S, Kadis E, Cao Y, Boakye E, Gu Z, Julson J (2016) Hydroprocessing of carinata oil for hydrocarbon biofuel over Mo-Zn/Al2O3. Applied Catal B, Environ 196:41–49. https://doi.org/10.1016/j.apcatb.2016.05.02010.1016/j.apcatb.2016.05.020 ↗
36. Ooi XY, Gao W, Ong CH, Lee HV, Juan JC, Chen WH, Lee KT (2019) Overview on catalytic deoxygenation for biofuel synthesis using metal oxide supported catalysts. Renew Sust Energ Rev 112:834–852. https://doi.org/10.1016/jrser.2019.06.03110.1016/jrser.2019.06.031 ↗
37. Galadima A, Muraza O (2015) Catalytic upgrading of vegetable oils into jet fuels range hydrocarbons using heterogeneous catalysts : a review. J Ind Eng Chem 29:12–23. https://doi.org/10.1016/j.jiec.2015.03.03010.1016/j.jiec.2015.03.030 ↗
38. Pongsedana M, Trisunaryanti W, Artanti FW, Falah II, Sutarno (2017) Hydrocracking of waste lubricant into gasoline fraction over CoMo catalyst supported on mesoporous carbon from bovine bone gelatin. Korean J Chem Eng 34:2591–2596. https://doi.org/10.1007/s11814-017-0165-310.1007/s11814-017-0165-3 ↗
39. Permata ML, Trisunaryanti W, Falah II, Hapsari MT, Fatmawati DA (2020) The effect of nickel content impregnated on zeolite toward catalytic activity and selectivity for hydrotreating of cashew nut shell liquid oil 13(1):772-779. https://doi.org/10.31788/RJC.2020.131552910.31788/RJC.2020.1315529 ↗