Optical Spectroscopic Analysis of High Density Lead Borosilicate Glasses
Source abstract
Abstract
Lead borosilicate glasses, of chemical composition 20SiO2-xPbO-(15 + x)B2O3-5WO2-10ZnO-(50-2x) Na2O (where x = 5, 10, 15, 20, 25) were prepared using the normal melt-quenching technique. The samples were examined using a Philips Analytical X-ray diffraction system in order to check their amorphous nature. The effect of increasing B2O3 and PbO content on glass transition temperature was examined using Differential Thermal Analysis measurements (DTA). The results of DTA showed that both melting and glass transition temperatures decrease with increase of lead and boron oxides. Density and its related parameters have been determined to study the effect of lead-boron content on the structural properties of the prepared samples. Based on the density and DTA results, the network forming role of Pb and B ions was proved. The optical properties of the glass samples have been obtained using UV-VIS measurements. The optical parameters, such as optical band gap, Urbach energy, refractive index, and electronic polarizability were deduced based on the optical data. The observed increase in optical band gap and decrease in Urbach energy as well as the red shift in the absorption spectra arise due to the formation of non-bridging oxygen.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Phase-change materials and chalcogenides
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References (28)
Show source-provided references
1. Rayan DA, Elbashar YH, Rashad MM, El-Korashy A (2013) Spectroscopic Analysis of Phosphate Barium Glass DopedCupric Oxide for Bandpass Absorption Filter. J Non-Cryst Solids 382 :52–5610.1016/j.jnoncrysol.2013.10.002 ↗
2. Elhaes H, Attallah M, Elbashar Y, Al-Alousi A, El-Okr M, Ibrahim M (2014) Modeling and Optical Properties of P2 O 5 -ZnO-CaO-Na2 O Glasses Doped with Copper Oxide. J Comput Theor Nanosci 11(10):2079–208410.1166/jctn.2014.3608 ↗
3. Aboulfotoh N, Elbashar Y, Ibrahem M, Elokr M (2014) Characterization of Copper Doped Phosphate Glasses for Optical Applications. J Ceram Int 40(7):10395–1039910.1016/j.ceramint.2014.02.125 ↗
4. Saeed A, El Shazly RM, Elbashar YH, Abou El-Azm AM, El-Okr MM, Comsan MNH, Osman AM, Abdal-monem AM, El-Sersy AR (2014) Gamma Ray Attenuation in Developed Borate Glassy. J Radiat Phys Chem 102:167–17010.1016/j.radphyschem.2014.04.032 ↗
5. Abdelghany AM (2013) Novel Method for Early Investigation of Bioactivity in Different Borate Bio-Glasses. Spectrochim Acta A 100:120–12610.1016/j.saa.2012.02.051 ↗
6. Kaundal RS, Kaur S, Singh N, Singh KJ (2010) Investigation of structural properties of Lead Strontium Borate Glasses for Gamma-Ray Shielding Applications. J Phys Chem Solids 71:1191–119510.1016/j.jpcs.2010.04.016 ↗
7. Bhatia B, parihar V, Singh S, Verma AS (2013) Spectroscopic Properties of Pr 3+ in Lithium Bismuth Borate Glasses. Am J Condens Matter Phys 3(3):80–88
8. Haralampieva A, Simeonova Lozanova I, Dimitrov V (2012) Optical Properties and Structure of BaO-V2 o 5 and Fe2 O 3-BaO-V2 O5 Glasses. J Univ Chem Technol Metall 47 (4):392–397
9. El-Batal HA, Abdelghany AM, El-Batala FH, Ezz El-Din FM (2012) Gamma Rays Interactions with WO3-Doped Lead Borate Glasses. Mater Chem Phys 134:542–54810.1016/j.matchemphys.2012.03.032 ↗
10. Zawisky M, Basturk M, Rehacek J, Hardil Z (2004) Neutron Tomographic Investigations of Boron-Alloyed Steels. J Nucl Mater 327:188–19310.1016/j.jnucmat.2004.02.011 ↗
11. Gupta S, Sidhu GS (2012) Energy Absorption Buildup factor for some Oxide Glasses: Penetration Depth, Photon Energy and Effective Atomic Number Dependence. International Journal of Scientific and Research Publications 2:1–710.15373/22778179/OCT2013/123 ↗
12. Kaewkhao J, Pokaipisit A, Limsuwan P (2010) Study on Borate Glass System Containing with Bi2 O 3 and BaO for Gamma-rays Shielding Materials: Comparison with PbO. J Nucl Mater 399:38–4010.1016/j.jnucmat.2009.12.020 ↗
13. Middle East Company for chemicals, 10 Rashedy street, Manial, Cairo, Egypt, Tel.: (+ 202 236 507 38), Email: middle4east@yahoo.com
14. Tuscharoen S, Kaewkhao J, Limsuwan P, Chewpraditkul W (2011) Development of BaO:B2 O 3 :Flyash Glass System for Gamma-rays shielding Materials. Prog Nucl Sci Technol 1:110–11310.15669/pnst.1.110 ↗
15. Kridtachanthima N, Kaewkhao J, Kedkaew C, Chewpraditkul W, Pokaipisit A, Limsuwan P (2011) Study on Interaction of Bi2 O 3, PbO and BaO in Silicate Glass System at 662 keV for Development of Gamma-Rays Shielding Materials. Prog Nucl Sci Technol 1:106–10910.15669/pnst.1.106 ↗
16. Abdelghany AM, Hammad AH (2015) The Effect of WO3 Dopant on The Structural and Optical Properties of ZnO–P2 O 5 Glass and The Effect of Gamma Irradiation. J Mol Struct 1081:342–34710.1016/j.molstruc.2014.10.055 ↗
17. Limkitjaroenporn P, Kaewkhao J, Limsuwan P, Chewpraditk W (2011) Physical, Optical, Structural and Gamma-ray Shielding Properties of Lead Sodium Borate Glasses. J Phys Chem Solids 72:245–25110.1016/j.jpcs.2011.01.007 ↗
18. Morsi RMM, Abdelghany AM, Morsi MM (2015) Dielectric, Electrical and Spectroscopic Properties of Barium Borates of Low WO3 Content. J Mater Sci Mater Electron 26(7):5120–512810.1007/s10854-015-3039-7 ↗
19. Kaur S, Singh KJ, Kaundal RS, Anand V, Kaur K (2013) Investigation of structural properties of Bismuth Silicate Glass System as Gamma ray Shielding Materials. Asian J Appl Sci 1:99–103
20. Insiripong S, Chimalawong P, Kaewkhao J, Limsuwan P (2011) Optical and physical properties of Bismuth Borate Glasses Doped with Dy 3+. Am J Appl Sci 8(6):574–57810.3844/ajassp.2011.574.578 ↗
21. Singh DP, Singh GP (2013) Conversion of Covalent to Ionic Behavior of Fe2 O 3-CeO2-PbO-B2 O 3 Glasses for Ionic and Photonic Application. J Alloys Compd 546:224–22810.1016/j.jallcom.2012.08.105 ↗
22. Prajna Shree M, Wagh A, Raviprakash Y, Sangeetha B, Kamath SD (2013) Characterization Of Pr6O11 Doped Zinc Fluoroborate Glass. European Scientific Journal 9(18):83–92
23. Çelikbilek M, Ersundu AE, Aydin S (2013) Preparation and characterization of TeO2-WO3-Li2O glasses. J Non-Cryst Solids 378:247–25310.1016/j.jnoncrysol.2013.07.020 ↗
24. Rajiv A, Sudhakara Reddy M, Uchil J, Narayana Reddy C (2014) Thermal and optical properties of Sodium-Phospho-Zinc-Neodymium Oxide Glass System. Journal of Advanced Scientific Research 5(2):32–39
25. Osipov AA, Osipov LM (2013) Raman scattering study of Barium Borate Glasses and Melts. J Phys Chem Solids 74:971–97810.1016/j.jpcs.2013.02.014 ↗
26. Prajna Shree M, Wagh A, Raviprakash Y, Sangeetha B, Kamath SD (2013) Characterization Of Pr6O11 Doped Zinc Fluoroborate Glass. European Scientific Journal 9(18):83–92
27. Saeed A, Elbashar YH, El Kameesy SU (2015) Study of Gamma Ray Attenuation of High-Density Bismuth Silicate Glass for shielding applications. Research Journal of Pharmaceutical, Biological and Chemical Sciences (RJPBCS) 6(4):1830–1837
28. Saeed A, Elbashar YH, El Kameesy SU (2015) Towards modeling of copper-phosphate glass for optical bandpass absorption filter. Research Journal of Pharmaceutical, Biological and Chemical Sciences (RJPBCS) 6:1390–1397