journal article·2019-10Open access

Removal of heavy metals from aqueous solutions by adsorption using single and mixed pillared clays

S. Mnasri-Ghnimi, N. Frini-Srasra

Abstract

This work concerns the application of single and mixed pillared clays in adsorption of inorganic pollutant in the water: the cadmium, the cobalt, and the copper. Adsorption experiments were conducted under various conditions, i.e., pH, contact time, initial concentration, and temperature. A comparison of the adsorption of the three metals onto pillared clays and natural clays suggested that pillared clays had higher adsorption affinity for metals than the unpillared clays. The experimental results indicated that the pillared clays rich on cerium show better properties on Cd2+, Co2+, and Cu2+ adsorption than those without cerium, which made them the promising recycling metals adsorbents. The equilibrium isotherm data were analyzed using the Langmuir and Freundlich isotherm equations. In all cases, the adsorption process fitted the second-order kinetics well, and the isotherm equation due to Langmuir showed good fits with the experimental data.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Clay minerals and soil interactions · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (81)

Show source-provided references
1. Adsorption of heavy metals on Na-montmorillonite. Effect of pH and organic substances10.1016/S0043-1354(02)00524-9 ↗
2. Thermodynamic features associated with intercalation of some N-alkylmonoamines into bariumphosphate10.1016/j.jct.2005.04.008 ↗
3. Removal of heavy metals from waste waters by natural and Na-exchanged bentonites10.1346/CCMN.2003.0510501 ↗
4. The influence of temperature on the adsorption of Cadmium(II) and Cobalt(II) on kaolinite10.1006/jcis.1998.5549 ↗
5. A novel method of Al-pillared montmorillonite preparation for potential industrial up-scaling10.1016/j.clay.2004.02.003 ↗
6. Kinetics of Cu2+ and Cd2+ adsorption by an italian soil10.1097/00010694-198503000-00002 ↗
7. ATSDR · 1999
8. Low-cost adsorbent for heavy metal uptake from contaminated water: a review10.1016/S0304-3894(02)00263-7 ↗
9. 1976
10. Baes · 1976
11. Adsorption of lead and cadmium ions from aqueous solution to the montmorillonite: water interface10.1016/S0927-7757(99)00501-4 ↗
12. Iron-doped pillared laponites as catalysts for the selective conversion of syngas into light alkenes10.1039/c39880001403 ↗
13. Kaolinite, montmorillonite, and their modified derivatives as adsorbents for removal of Cu(II) from aqueous solution10.1016/j.seppur.2005.12.014 ↗
14. Adsorption of Co(II) from aqueous medium on natural and acid activated kaolinite and montmorillonite10.1080/01496390701515136 ↗
15. Influence of acid activation on adsorption of Ni(II) and Cu(II) on kaolinite and montmorillonite: Kinetic and thermodynamic study10.1016/j.cej.2007.03.005 ↗
16. Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: a review10.1016/j.cis.2007.12.008 ↗
17. Synthesis and characterization of PILC with single and mixed oxide pillars prepared from two different bentonites. A comparative study10.1016/S1387-1811(98)00295-9 ↗
18. Adsorption of ethoxylated sulfonate and nonionic on coal10.1016/0021-9797(89)90456-6 ↗
19. Surface modification of a granular activated carbon by citric acid for enhancement of copper adsorption10.1016/S0008-6223(03)00197-0 ↗
20. A new vanadium-pillared montmorillonite catalyst for the regioselective epoxidation of allylic alcohols10.1039/c39900000721 ↗
21. Pillar effects in MoS2 catalysts supported on Al and Zr pillared clays in a hydrotreatment reaction. A preliminary study10.1016/j.apsusc.2004.05.296 ↗
22. Adsorption of cu ions onto a 1.10 phenanthroline-grafted brazilian bentonite10.1346/CCMN.2003.510107 ↗
23. Hydrolysis of titanium(IV) in aqueous (Na, H)Cl solution10.1039/dt9790001917 ↗
24. Effect of the atomic active metal ratio in Al/Fe-, Al/Cu- and Al/(Fe–Cu)-intercalating solutions on the physicochemical properties and catalytic activity of pillared clays in the CWPO of methyl orange10.1016/j.apcatb.2010.08.003 ↗
25. Main factors controlling the texture of zirconia and alumina pillared clays10.1016/S1387-1811(99)00166-3 ↗
26. Effect of the Si/Al ratio on the textural and surface properties of silica-alumina-pillared clays10.1016/j.jcat.2004.10.013 ↗
27. Influence of the acid activation of pillared smectites fromAmazon (Brazil) in adsorption process with butylamine10.1016/j.poly.2006.04.015 ↗
28. Adsorptive, thermodynamic and kinetic performances of Al/Ti and Al/Zr-pillared clays from the Brazilian Amazon region for zinc cation removal10.1016/j.jhazmat.2007.11.054 ↗
29. Citation review of Lagergren kinetic rate equation on adsorption reactions10.1023/B:SCIE.0000013305.99473.cf ↗
30. Batch lead(ii) removal from aqueous solution by peat: equilibrium and kineticsTrans
31. The removal of cobalt(II) from water by activated carbon
32. Cadmium sorption by hydroxy-aluminium interlayered montmorillonite10.1023/A:1011928829059 ↗
33. Adsorption of heavy metals by clay–aluminum hydroxide complexes
34. Thermodynamic and kinetic investigations of uranium adsorption on amberlite IR-118H resin10.1016/S0969-8043(02)00316-0 ↗
35. The removal of iron and cobalt from aqueous solutions by ion exchange with Na–Y–Zeolite batch, semibatch and continuous operation10.1002/jctb.618 ↗
36. Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust Desalination
37. About the Theory of So-called adsorption of soluble substances
38. Copper adsorption on chitosan–cellulose hydrogel beads: behaviors and mechanisms10.1016/j.seppur.2004.08.002 ↗
39. Adsorption of cadmium onto Al13-pillared acid-activated montmorillonite10.1016/j.jhazmat.2007.12.045 ↗
40. Heavy metal removal from water by sorption using surfactant-modified montmorillonite10.1016/S0304-3894(02)00026-2 ↗
41. Immobilization of heavy metals by polynuclear aluminum and montmorillonite compounds10.1021/es960697h ↗
42. The relation between the synthesis of pillared clays and their resulting porosity10.1016/S0169-1317(96)00036-1 ↗
43. Adsorption performance of Al-pillared bentonite clay for the removal of cobalt(II) from aqueous phase10.1016/j.clay.2005.08.008 ↗
44. McBride · 1994 · 240
45. Sorption of metal ions by chitosan
46. Michelson · 1975
47. Influence of synthesis conditions and cerium incorporation on the properties of Zr-pillared clays10.1023/A:1026027628370 ↗
48. Physicochemical and catalytic properties of Zr-pillared montmorillonite with varying pillar density10.1016/j.micromeso.2004.02.018 ↗
49. Promoting effect of cerium on the characteristic and catalytic activity of Al, Zr, and Al–Zr pillared clay10.1016/j.clay.2013.10.030 ↗
50. Effect of Al and Ce on Zr-pillared bentonite and their performance in catalytic oxidation of phenol10.1134/S0036024416090272 ↗
51. A comparison of single and mixed pillared clays for zinc and chromium cations removal10.1016/j.clay.2018.03.019 ↗
52. Removal of Cd(II) from wastewater by adsorption on“waste” Fe(III)/Cr(III) hydroxide10.1016/0043-1354(94)00320-7 ↗
53. Adsorption of copper on rubber (Hevea brasiliensis) leaf powder: kinetic, equilibrium and thermodynamic studies10.1016/j.bej.2007.11.006 ↗
54. New routes to the preparation of pillared montmorillonite catalysts10.1016/0304-5102(86)87085-7 ↗
55. Thermal behaviour of montmorillonite pillared with different metal oxides10.1007/BF01981732 ↗
56. Porosity and thermal stability of PILCs prepared with clays from different origins and different metal–polyhydroxycationic species ofAl and Al/Ce.J10.1039/a800891d ↗
57. Removal of Cd2+ from aqueous solution with carbon modified aluminum-pillared montmorillonite10.1016/j.cattod.2008.08.015 ↗
58. Adsorption behavior of cadmium, zinc, and lead on hydroxyaluminum- and hydroxyaluminosilicatemontmorillonite complexes10.2136/sssaj2001.653694x ↗
59. Influence of potassium chloride on desorption of cadmium sorbed on hydroxyaluminosilicate-montmorillonite complex10.1080/00380768.1996.10416316 ↗
60. Preparation of Al-pillared montmorillonite from concentrated dispersions10.1016/S0169-1317(02)00133-3 ↗
61. Interaction of metal ions with clays: I. A case study with Pb(II)10.1016/j.clay.2005.03.008 ↗
62. Synthesis, characterization and application as a mercury(II) sorbent of banana stalk (Musa paradisiaca)—polyacrylamide grafted copolymer bearing carboxyl groups10.1021/ie020245f ↗
63. Preparation and properties of large-pore La–Al-pillared montmorillonite10.1346/CCMN.1991.0390208 ↗
64. Intercalation of [Fe8(μ3–O)2(μ2–OH2)12(tacn)6] 8+ single molecule magnets in saponite clay10.1016/j.jpcs.2006.01.124 ↗
65. Early stage of the hydrolysis of chromium(III) in aqueous solution. 1. Characterization of a tetrameric species10.1021/ic00157a012 ↗
66. A thermal study of Zr-pillared montmorillonite10.1016/S0040-6031(98)00540-1 ↗
67. A review of potentially low-cost sorbents for heavy metals10.1016/S0043-1354(98)00475-8 ↗
68. Thermodynamic studies of Ni(II) adsorption onto bentonite from aqueous solution10.1016/S0021-9614(03)00153-8 ↗
69. Removal of Cd(II) and Pb(II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris10.1016/j.jhazmat.2003.07.009 ↗
70. Effect of the acid–base properties of Zr, Al-pillared clays on the catalytic performances in the reaction of propylene oxide with methanol10.1016/j.apcatb.2011.02.028 ↗
71. Cross-linked smectites. IV. Preparation and properties of hydroxyaluminum-pillared Ce- and La-montmorillonites andfluorinated NH4+-montmorillonites10.1346/CCMN.1985.0330202 ↗
72. Process development for removal and recovery of phosphorus from wastewater by a new adsorbent: 2- adsorption rates and breakthrough curves10.1021/ie00056a033 ↗
73. Al-Pillaring of saponite with the Al polycation [Al13(OH)24(H2O)24]15+ using a new synthetic route10.1346/CCMN.2003.0510206 ↗
74. Relationship between the surface properties and the catalytic performance of Al-, Ga-, and AlGa-pillared saponites10.1021/ie801301a ↗
75. Preparation, characterization and some catalytic properties of different smectites pillared with hydroxyaluminium and hydroxygallium solutions. Preliminary study–pillared layered structures
76. Removal of Copper(II) Ions from aqueous solutions using natural kaolinite
77. Sorption in subsurface systems concept, models and effects on contaminant fate and transport10.1016/0043-1354(91)90125-A ↗
78. Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite10.1016/S0043-1354(02)00409-8 ↗
79. Adsorption of aromatic hydrocarbons on BTEA-betonites10.1260/026361704323150926 ↗
80. Effects of the type and structure of modified clays on adsorption performance10.1080/00207230500242338 ↗
81. The removal of heavy metal from aqueous solutions by sawdust adsorption — removal of copper10.1016/S0304-3894(00)00278-8 ↗