Cu-Sn-S system: Vibrational properties and coexistence of the Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds
Source abstract
Abstract
Abstract In the present study the transformation between Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds is analyzed by means of X-ray diffraction and Raman scattering spectroscopy. A detailed analysis of the X-ray diffractograms showed the dependence of formation of the indicated compositional phases from the [Cu]/[Sn] ratio, which was also correlated with the evolution of the Raman spectra. The results are complemented with the detailed analysis of microscopic Raman imaging. Finally, fingerprint Raman spectrum for each compositional polymorph is presented, which should exclude any misinterpretations during phase analysis in future works.
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Research context
OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications
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References (28)
Show source-provided references
1. Reddy Minnam Reddy · J. Ind. Eng. Chem. · 2019 · 76 · 3910.1016/j.jiec.2019.03.035 ↗
2. Nakashima · Phys. Status Solidi C · 2015 · 12 · 76110.1002/pssc.201400269 ↗
3. Umehara · Appl. Phys. Express · 2013 · 610.7567/APEX.6.045501 ↗
4. Lokhande · RSC Adv. · 2017 · 7 · 3373710.1039/C7RA05194H ↗
5. Lokhande · J. Alloy Compd. · 2017 · 709 · 9210.1016/j.jallcom.2017.03.135 ↗
6. Schorr · Thin Solid Film · 2009 · 517 · 246110.1016/j.tsf.2008.11.053 ↗
7. Fairbrother · Sol. Energy Mater. Sol. Cell · 2013 · 112 · 9710.1016/j.solmat.2013.01.015 ↗
8. Berg · Thin Solid Film · 2014 · 569 · 11310.1016/j.tsf.2014.08.028 ↗
9. Oliva · J. Mater. Chem. A · 2017 · 5 · 2386310.1039/C7TA08705E ↗
10. Chalapathi · Vacuum · 2016 · 131 · 2210.1016/j.vacuum.2016.05.028 ↗
11. Chalapathi · Sol. Energy · 2017 · 155 · 33610.1016/j.solener.2017.06.051 ↗
12. Xu · J. Mater. Sci.: Mater. Electron. · 2017 · 28 · 3481
13. Ko · Cryst. Eng. Comm. · 2017 · 19 · 576410.1039/C7CE01261F ↗
14. Chalapathi · J. Mater. Sci.: Mater. Electron. · 2018 · 29 · 1451
15. Cheng · Sci. Technol. A · 2011 · 29
16. Onoda · Mater. Res. Bull. · 2000 · 35 · 156310.1016/S0025-5408(00)00347-0 ↗
17. Crystal Structures and Band-Gap Energies of Cu2Sn(S,Se)3 (0 ≤ x ≤ 1.0) Solid Solution10.1002/pssc.201200867 ↗
18. Dzhagan · J. Phys. Chem. C · 2014 · 118 · 2755410.1021/jp509035f ↗
19. Jaulmes · Acta Crystallogr. B · 1977 · 33 · 54010.1107/S0567740877004002 ↗
20. Zawadzki · Appl. Phys. Lett. · 2013 · 10310.1063/1.4851896 ↗
21. Avellaneda · J. Electrochem. Soc. · 2010 · 157 · D34610.1149/1.3384660 ↗
22. Chakrabarti · Bulletin of Alloy Phase Diagrams · 1983 · 4 · 25410.1007/BF02868665 ↗
23. Andrade-Arvizu · J. Mater. Sci.: Mater. Electron. · 2015 · 26 · 4541
24. Guc · Acta Mater. · 2020 · 183 · 110.1016/j.actamat.2019.11.016 ↗
25. Geetha Vani · ISRN Condensed Matter Physics · 2013 · 2013
26. Julien · Solid State Ionics · 1996 · 89 · 33710.1016/0167-2738(96)00270-6 ↗
27. Wang · Chem. Phys. Lett. · 2002 · 357 · 37110.1016/S0009-2614(02)00495-5 ↗
28. Kim · J. Alloy Compd. · 2019 · 770 · 95910.1016/j.jallcom.2018.08.206 ↗