journal article·2019-04Open access

A new path to design near-infrared persistent luminescence materials using Yb3+-doped rare earth oxysulfides

Ian Pompermayer Machado, Cássio Cardoso Santos Pedroso, José Miranda de Carvalho, Verônica de Carvalho Teixeira, Lucas Carvalho Veloso Rodrigues, Hermi Felinto Brito

Scripta Materialia· Volume 164

Abstract

Abstract RE2O2S:Yb3+ and RE2O2S:Yb3+,Ti,Mg2+ near-infrared persistent luminescence materials (RE3+: La, Gd, Y) were designed based on the efficient red-emitting RE2O2S:Eu3+,Ti,Mg2+, due to the similar ground state level positions between Eu3+ and Yb3+. The Y2O2S:Yb3+,Ti,Mg2+ showed the longest near-infrared (~983 nm) persistent luminescence time (~1 h) when excited at the charge transfer transition, demonstrating that Ti,Mg2+ co-doping enhances the persistent luminescence only for the Y2O2S host. The unprecedented relationship between Eu3+ and Yb3+ persistent luminescence opens a new path in the systematic design of efficient Yb3+-activated persistent luminescence materials e.g. Y2O2S:Yb3+,Ti,Mg2+, which present potential for photonic applications such as bioimaging probes.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Luminescence and Fluorescent Materials · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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