journal article·2012-03

Application of nanoindentation to investigate chemomechanical properties change of cement paste in the carbonation reaction

JianDe Han, GangHua Pan, Wei Sun, CaiHui Wang, Dong Cui

Publisher page

Abstract

Nanoindentation technique was adopted to investigate the chemomechanical properties change of hardened cement paste before and after carbonation. It was found that the mean elastic modulus and mean hardness obviously increase after the carbonation reaction. Specifically, the probability of the elastic modulus showed a sharp reduction for the elastic modulus at the range of 7–34 and 83–160 GPa, in comparison of a large increase for the elastic modulus between 34–83 GPa. For the same reason, the probability of the hardness showed a large decrease when the hardness fell within 0.15–1.75 and 4.15–8.20 GPa and a dramatic increase for the hardness at the range of 1.75–4.15 GPa. In addition, low density C-S-H was affected by the carbonation degradation more seriously than high density C-S-H. The carbonation reaction led to distinct decrease of the number and size of unhydrated cement paste particles.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Concrete Properties and Behavior

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Ishida T, Maekawa K, Soltani M. Theoretically identified strong coupling of carbonation rate and thermodynamic moisture states in micropores of concrete. JACT, 2004, 2: 213–222
2. Papadakis V G, Vayenas C G, Fardis M N. Fundamental modeling and experimental investigation of concrete carbonation. ACI Mater J, 1991, 88: 363–373
3. Papadakis V G, Vayenas C G, Fardis M N. Experimental investigation and mathematical modeling of the concrete carbonation problems. Chem Eng Sci, 1991, 46: 1333–133810.1016/0009-2509(91)85060-B ↗
4. Han J D, Pan G H, Sun W. Investigation on carbonation induced meso-defects changes of cement mortar using 3D X-ray computed tomography. J Chinese Ceramic Society, 2011, 39: 75–79
5. Rozière E, Loukili A, Cussigh F. A performance based approach for durability of concrete exposed to carbonation. Constr Build Mater, 2009, 23: 190–19910.1016/j.conbuildmat.2008.01.006 ↗
6. Ba M F, Qian C X, Gao G B. Influence of absolute basicity and capillary porosity on carbonation of concrete. J Wuhan Univ Technol-Mater Sci Ed, 2010, 25: 889–89210.1007/s11595-010-0114-z ↗
7. Constantinides G, Ulm F J, Vliet K V. On the use of nanoindentation for cementitious materials. Mater Struct, 2002, 36: 191–19610.1007/BF02479557 ↗
8. Velez K, Maximilien S, Damodot D, et al. Determination by nanoindentation of elastic modulus and hardness of pure constituents of Portland cement clinker. Cem Concr Res, 2001, 31: 555–56110.1016/S0008-8846(00)00505-6 ↗
9. Constantinides G, Ulm F J. The effect of two types of C-S-H on the elasticity of cement-based materials: Results from nanoindentation and micromechanical modeling. Cem Concr Res, 2004, 34: 67–8010.1016/S0008-8846(03)00230-8 ↗
10. Jennings H M, Thomas J J, Gevrenov J S, et al. A multi-technique investigation of nanoporosity of cement paste. Cem Concr Res, 2007, 37: 329–33610.1016/j.cemconres.2006.03.021 ↗
11. Zhu W, Hughes J J, Bicanic N, et al. Nanoindentation mapping of mechanical properties of cement paste and natural rocks. Mater Charact, 2007, 58: 1189–119810.1016/j.matchar.2007.05.018 ↗
12. Dejong M J, Ulm F J. The nanogranular behavior of C-S-H at elevated temperatures (up to 700°C). Cem Concr Res, 2007, 37: 1–1210.1016/j.cemconres.2006.09.006 ↗
13. Mondal P, Shah S P, Marks L. A reliable technique to determine the local mechanical properties at nanoscale for cementitious materials. Cem Concr Res, 2007, 37: 1440–144410.1016/j.cemconres.2007.07.001 ↗
14. Maria S G K, Metaxa Z S, Shah S P. Multi-scale mechanical and fracture characteristics and early-age strain capacity of high performance carbon nanotube cement nanocomposites. Cem Concr Compos, 2010, 32: 110–11510.1016/j.cemconcomp.2009.10.007 ↗
15. Çdpuroğlu O, Schlangen E. Modeling of frost salt scaling. Cem Concr Res, 2008, 38: 27–3910.1016/j.cemconres.2007.09.003 ↗
16. James V. A Nanochemomechanical Investigation of Carbonated Cement Paste. Dissertation of Doctoral Degree. Massachusetts: Massachusetts Institute of Technology, 2009
17. Xiao H W, Jacobsen S, Jian Y H, et al. Application of nanoindentation testing to study of the interfacial transition zone in steel fiber reinforced mortar. Cem Concr Res, 2008, 39: 701–715
18. Mondal P, Shah S P, Marks L. Nanoscale characterization of cementitious materials. ACI Mater J, 2008, 105: 174–179
19. Oliver W C, Pharr G M. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res, 1992, 7: 1564–158310.1557/JMR.1992.1564 ↗
20. Oliver W C, Pharr G M. On the generality of the relationship among contact stiffness, contact area and elastic modulus during indentation. J Mater Res, 1992, 7: 613–61710.1557/JMR.1992.0613 ↗
21. Sorelli L, Constantinides G, Ulm F J, et al. The nano-mechanical signature of ultra high performance concrete by statistical nanoindentation techniques. Cem Concr Res, 2008, 38: 1447–145610.1016/j.cemconres.2008.09.002 ↗
22. Constantinides G, Ulm F J. The nanogranular nature of C-S-H. J Mech Phys Solids, 2007, 55: 64–9010.1016/j.jmps.2006.06.003 ↗
23. Pharr G M, Bolshakov A. Understanding nanoindentation unloading curves. J Mater Res, 2002, 17: 2660–267110.1557/JMR.2002.0386 ↗
24. Nemecek J. Creep effects in nanoindentation of hydrated phases of cement pastes. Mater Charact, 2009, 60: 1028–103410.1016/j.matchar.2009.04.008 ↗
25. Ulm F J, Vandamme M, Jennings H M, et al. Does microstructure matter for statistical nanoindentation techniques? Cem Concr Compos, 2010, 32: 92–9910.1016/j.cemconcomp.2009.08.007 ↗
26. Miller M, Bobko C, Vandamme M, et al. Surface roughness criteria for cement paste nanoindentation. Cem Concr Res, 2008, 38: 467–47610.1016/j.cemconres.2007.11.014 ↗
27. Acker P. Micromechanical analysis of creep and shrinkage mechanisms. Creep, Shrinkage and Durability Mechanics of Concrete and Other Quasi-Brittle Materials, Oxford, UK, 2001. 15-25
28. Constantinides G, Ulm F J. The Elastic Properties of Calcium Leached Cement Pastes and Mortars: A Multi-scale Investigation. MIT CEE Report R02-01, 2006
29. Beaudoin J. Comparison of mechanical properties of compacted calcium hydroxide and Portland cement paste systems. Cem Concr Res, 2008, 13: 319–32410.1016/0008-8846(83)90030-3 ↗
30. Wittmann F H. Estimation of the modulus of elasticity of calcium hydroxide. Cem Concr Res, 2008, 16: 971–97210.1016/0008-8846(86)90021-9 ↗
31. Monteiro P J M, Chang C T. The elastic-modulus of calcium hydroxide. Cem Concr Res, 1995, 25: 1605–160910.1016/0008-8846(95)00154-9 ↗
32. Yang T, Keller B, Magyari E. Direct observation of the carbonation process on the surface of calcium hydroxide crystals in hardened cement paste using an atomic force microscope. J Mater Sci, 2003, 38: 1909–191610.1023/A:1023544228319 ↗