One-step synthesis of dual-ligand 2D conductive metal-organic framework for high-performance lithium storage
Source abstract
Abstract
基于双氧化还原活性有机配体的二维导电金属-有机框架(2D c-MOFs)是极具潜力的锂离子电池(LIBs)电极材料. 然而, 双配体竞争配 位导致该类材料合成具有极大挑战性. 本文以乙二胺为调节剂, 发展了 一步法合成双配体基2D c-MOF Cu3(HHTP)(THQ) (HHTP = 2,3,6,7,10,11-六羟基三亚苯, THQ = 四羟基-1,4-苯醌). 所得 Cu3(HHTP)(THQ)具有良好的导电性、丰富的活性位点和优异的化学 稳定性, 其作为LIBs负极材料展现出高比容量、良好的倍率性能和长 循环稳定性. 实验结果和理论计算表明, Cu3(HHTP)(THQ)中CuO4活 性位点和苯环单元均参与了锂存储, 从而优化了储锂性能. 该工作为构 筑双配体基2D c-MOFs和高性能LIBs电极材料提供了新的途径.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Tian Y, Zeng G, Rutt A, et al. Promises and challenges of next-generation “beyond Li-ion” batteries for electric vehicles and grid decarbonization. Chem Rev, 2021, 121: 1623–166910.1021/acs.chemrev.0c00767 ↗
2. Wu F, Maier J, Yu Y. Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries. Chem Soc Rev, 2020, 49: 1569–161410.1039/C7CS00863E ↗
3. Zhang K, Hu Z, Tao Z, et al. Inorganic & organic materials for rechargeable Li batteries with multi-electron reaction. Sci China Mater, 2014, 57: 42–5810.1007/s40843-014-0006-0 ↗
4. Zeng X, Li M, Abd El-Hady D, et al. Commercialization of lithium battery technologies for electric vehicles. Adv Energy Mater, 2019, 9: 190016110.1002/aenm.201900161 ↗
5. Liu B, Zhang JG, Xu W. Advancing lithium metal batteries. Joule, 2018, 2: 833–84510.1016/j.joule.2018.03.008 ↗
6. Li M, Lu J, Chen Z, et al. 30 Years of lithium-ion batteries. Adv Mater, 2018, 30: 180056110.1002/adma.201800561 ↗
7. Zhang Y, Yi L, Zhang J, et al. Advances in flexible lithium metal batteries. Sci China Mater, 2022, 65: 2035–205910.1007/s40843-022-2100-6 ↗
8. Liu J, Song X, Zhang T, et al. 2D conductive metal-organic frameworks: An emerging platform for electrochemical energy storage. Angew Chem Int Ed, 2021, 60: 5612–562410.1002/anie.202006102 ↗
9. Majumder M, Santosh MS, Viswanatha R, et al. Two-dimensional conducting metal-organic frameworks enabled energy storage devices. Energy Storage Mater, 2021, 37: 396–41610.1016/j.ensm.2021.02.027 ↗
10. Yan J, Cui Y, Xie M, et al. Immobilizing redox-active tricycloquinazoline into a 2D conductive metal-organic framework for lithium storage. Angew Chem Int Ed, 2021, 60: 24467–2447210.1002/anie.202110373 ↗
11. Yin J, Li N, Liu M, et al. Stabilizing redox-active hexaazatriphenylene in a 2D conductive metal-organic framework for improved lithium storage performance. Adv Funct Mater, 2023, 33: 221195010.1002/adfm.202211950 ↗
12. Sheberla D, Bachman JC, Elias JS, et al. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat Mater, 2017, 16: 220–22410.1038/nmat4766 ↗
13. Wu Z, Adekoya D, Huang X, et al. Highly conductive two-dimensional metal-organic frameworks for resilient lithium storage with superb rate capability. ACS Nano, 2020, 14: 12016–1202610.1021/acsnano.0c05200 ↗
14. Wada K, Sakaushi K, Sasaki S, et al. Multielectron-transfer-based rechargeable energy storage oftwo-dimensional coordination frameworks with non-innocent ligands. Angew Chem Int Ed, 2018, 57: 8886–889010.1002/anie.201802521 ↗
15. Park J, Lee M, Feng D, et al. Stabilization of hexaaminobenzene in a 2D conductive metal-organic framework for high power sodium storage. J Am Chem Soc, 2018, 140: 10315–1032310.1021/jacs.8b06020 ↗
16. Nam KW, Park SS, dos Reis R, et al. Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries. Nat Commun, 2019, 10: 494810.1038/s41467-019-12857-4 ↗
17. Jiang Q, Xiong P, Liu J, et al. A redox-active 2D metal-organic framework for efficient lithium storage with extraordinary high capacity. Angew Chem Int Ed, 2020, 59: 5273–527710.1002/anie.201914395 ↗
18. Wu AQ, Wang WQ, Zhan HB, et al. Layer-by-layer assembled dual-ligand conductive MOF nano-films with modulated chemiresistive sensitivity and selectivity. Nano Res, 2020, 14: 438–44310.1007/s12274-020-2823-8 ↗
19. Yao MS, Zheng JJ, Wu AQ, et al. A dual-ligand porous coordination polymer chemiresistor with modulated conductivity and porosity. Angew Chem Int Ed, 2020, 59: 172–17610.1002/anie.201909096 ↗
20. Smith MK, Mirica KA. Self-organized frameworks on textiles (SOFT): Conductive fabrics for simultaneous sensing, capture, and filtration of gases. J Am Chem Soc, 2017, 139: 16759–1676710.1021/jacs.7b08840 ↗
21. Liu Y, Li S, Dai L, et al. The synthesis of hexaazatrinaphthylene-based 2D conjugated copper metal-organic framework for highly selective and stable electroreduction of CO2 to methane. Angew Chem Int Ed, 2021, 60: 16409–1641510.1002/anie.202105966 ↗
22. Liang RR, Jiang SY, A RH, et al. Two-dimensional covalent organic frameworks with hierarchical porosity. Chem Soc Rev, 2020, 49: 3920–395110.1039/D0CS00049C ↗
23. Xu L, Xiao X, Tu H, et al. Engineering functionalized 2D metal-organic frameworks nanosheets with fast Li+ conduction for advanced solid Li batteries. Adv Mater, 2023, 35: 230319310.1002/adma.202303193 ↗
24. Liu J, Yang D, Zhou Y, et al. Tricycloquinazoline-based 2D conductive metal-organic frameworks as promising electrocatalysts for CO2 reduction. Angew Chem Int Ed, 2021, 60: 14473–1447910.1002/anie.202103398 ↗
25. Meng Z, Mirica KA. Two-dimensional d–π conjugated metal-organic framework based on hexahydroxytrinaphthylene. Nano Res, 2021, 14: 369–37510.1007/s12274-020-2874-x ↗
26. Cai Y, Wang W, Cao X, et al. Synthesis of tostadas-shaped metal-organic frameworks for remitting capacity fading of Li-ion batteries. Adv Funct Mater, 2021, 32: 210992710.1002/adfm.202109927 ↗
27. Zhai L, Li G, Yang X, et al. 30 Li+-accommodating covalent organic frameworks as ultralong cyclable high-capacity Li-ion battery electrodes. Adv Funct Mater, 2021, 32: 210879810.1002/adfm.202108798 ↗
28. Zhao G, Zhang Y, Gao Z, et al. Dual active site of the azo and carbonyl-modified covalent organic framework for high-performance Li storage. ACS Energy Lett, 2020, 5: 1022–103110.1021/acsenergylett.0c00069 ↗
29. Yu J, Chen X, Wang H, et al. Conjugated ladder-type polymers with multielectron reactions as high-capacity organic anode materials for lithium-ion batteries. Sci China Mater, 2022, 65: 2354–236210.1007/s40843-021-2027-3 ↗
30. Zhao G, Sun Y, Yang Y, et al. Molecular engineering regulation redox-dual-active-center covalent organic frameworks-based anode for high-performance Li storage. EcoMat, 2022, 4: e1222110.1002/eom2.12221 ↗
31. Huang Y, Fang Y, Lu XF, et al. Co3O4 hollow nanoparticles embedded in mesoporous walls of carbon nanoboxes for efficient lithium storage. Angew Chem Int Ed, 2020, 59: 19914–1991810.1002/anie.202008987 ↗
32. Kong L, Zhu J, Shuang W, et al. Nitrogen-doped wrinkled carbon foils derived from MOF nanosheets for superior sodium storage. Adv Energy Mater, 2018, 8: 180151510.1002/aenm.201801515 ↗
33. Shen Y, Shen X, Yang M, et al. Achieving desirable initial coulombic efficiencies and full capacity utilization of Li-ion batteries by chemical prelithiation of graphite anode. Adv Funct Mater, 2021, 31: 210118110.1002/adfm.202101181 ↗
34. Shi P, Fu ZH, Zhou MY, et al. Inhibiting intercrystalline reactions of anode with electrolytes for long-cycling lithium batteries. Sci Adv, 2022, 8: eabq344510.1126/sciadv.abq3445 ↗
35. Lu LL, Lu YY, Zhu ZX, et al. Extremely fast-charging lithium ion battery enabled by dual-gradient structure design. Sci Adv, 2022, 8: eabm662410.1126/sciadv.abm6624 ↗
36. Wang S, Guan BY, Yu L, et al. Rational design of three-layered TiO2@carbon@MoS2 hierarchical nanotubes for enhanced lithium storage. Adv Mater, 2017, 29: 170272410.1002/adma.201702724 ↗
37. Zhang Y, Qiu T, Jiang F, et al. Spindle-like Ni3(HITP)2 MOFs: Synthesis and Li+ storage mechanism. Appl Surf Sci, 2021, 556: 14981810.1016/j.apsusc.2021.149818 ↗
38. Tong Y, Sun Z, Wang J, et al. Covalent organic framework containing dual redox centers as an efficient anode in Li-ion batteries. SmartMat, 2022, 3: 685–69410.1002/smm2.1115 ↗
39. Liu X, Yang X, Wang H, et al. A robust redox-active hydrogen-bonded organic framework for rechargeable batteries. J Mater Chem A, 2022, 10: 1808–181410.1039/D1TA09194H ↗
40. An Y, Tian Y, Wei H, et al. Porosity- and graphitization-controlled fabrication of nanoporous silicon@carbon for lithium storage and its conjugation with MXene for lithium-metal anode. Adv Funct Mater, 2019, 30: 190872110.1002/adfm.201908721 ↗
41. Kong L, Liu Y, Huang H, et al. Interconnected CoS2/NC-CNTs network as high-performance anode materials for lithium-ion batteries. Sci China Mater, 2020, 64: 820–82910.1007/s40843-020-1477-0 ↗
42. Pu X, Zhao D, Fu C, et al. Understanding and calibration of charge storage mechanism in cyclic voltammetry curves. Angew Chem Int Ed, 2021, 60: 21310–2131810.1002/anie.202104167 ↗
43. Huang H, Kong L, Shuang W, et al. Controlled synthesis of core-shell Fe2O3@N-C with ultralong cycle life for lithium-ion batteries. Chin Chem Lett, 2022, 33: 1037–104110.1016/j.cclet.2021.08.013 ↗
44. Meng Z, Jones CG, Farid S, et al. Unraveling the electrical and magnetic properties of layered conductive metal-organic framework with atomic precision. Angew Chem Int Ed, 2022, 61: e20211356910.1002/anie.202113569 ↗
45. Lei Z, Yang Q, Xu Y, et al. Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry. Nat Commun, 2018, 9: 57610.1038/s41467-018-02889-7 ↗
46. Buyukcakir O, Ryu J, Joo SH, et al. Lithium accommodation in a redox-active covalent triazine framework for high areal capacity and fast-charging lithium-ion batteries. Adv Funct Mater, 2020, 30: 200376110.1002/adfm.202003761 ↗
47. Wang B, Li J, Ye M, et al. Dual-redox sites guarantee high-capacity sodium storage in two-dimension conjugated metal-organic frameworks. Adv Funct Mater, 2022, 32: 211207210.1002/adfm.202112072 ↗
48. Xu X, Zhang S, Xu K, et al. Janus dione-based conjugated covalent organic frameworks with high conductivity as superior cathode materials. J Am Chem Soc, 2023, 145: 1022–103010.1021/jacs.2c10509 ↗
49. Ji K, Han J, Hirata A, et al. Lithium intercalation into bilayer graphene. Nat Commun, 2019, 10: 27510.1038/s41467-018-07942-z ↗