Molecular engineering toward sustainable development of multiple-doped hierarchical porous carbons for superior zinc ion storage
Source abstract
Abstract
具备低价、优异倍率性能、长寿命、高安全性的水系锌离子混 合电容器(ZHSCs)是理想的下一代能量存储器件. 高比表面积、多级 孔、富缺陷的掺杂分级多孔碳(HD-HPCs)是非常有前景的ZHSCs正极 材料. 但是, 可持续且可控原位构筑同时具备多种结构组分优势的HDHPCs 仍然面临挑战. 本文提出一种新的分子工程化策略, 即直接碳化 富含多种异质原子的超分子前驱体, 便可实现原位构筑多元掺杂HDHPCs. 该绿色可持续策略具有多种优势, 包括不需要额外的成孔技 术、活化剂、模板剂、以及复杂且危险的清洗过程. 由于富杂原子超 分子前驱体具有较高的活性, 高温碳化过程中杂原子以及邻近杂原子 的碳原子很容易从碳骨架中脱离, 形成丰富的微介孔结构. 因此, 活性 结构与组分优化后的正极材料在水系ZHSCs中0.5和20 A g−1下容量分 别达到139.2和88.9 mA h g−1, 在准固态ZHSCs中0.5 A g−1下容量也能够 达到111.5 mA h g−1. 此外, 水系和准固态ZHSCs也具备高能量和功率密 度, 以及长循环稳定性. 理论计算表明多原子掺杂能够协同提升碳材料 的导电性, 且降低锌离子与碳之间的相互作用能垒, 因而提升锌离子的 吸附性能. 本工作为直接制备HD-HPCs及其电化学储能应用提供了新 思路.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Advancements in Battery Materials
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References (74)
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