Modulated bonding interaction in propanediol electrolytes toward stable aqueous zinc-ion batteries
Source abstract
Abstract
水系锌基电池具有低成本和高安全性的优点, 是很有潜力的储能技术. 然而, 枝晶、副反应和较差的低温性能限制了其实际应用, 这与电解液的溶液组成密切相关. 在本工作中, 我们通过调控丙二醇电解液的溶剂结构及键相互作用, 有效抑制了锌枝晶和副反应. 丙二醇具有较高的电子云密度和DN (Donor number) 值, 可以破坏水分子间和水分子与Zn2+间的相互作用, 从而提高H–O共价键的强度, 降低水活性和冰点, 改变Zn2+的溶剂化结构. 制备的电池器件表现出高的循环稳定性(Zn//Zn电池循环超过1000 h), 高可逆性(库伦效率达到98.9%), 高储锌性能(在5 A g−1下比容量为225 mA h g−1, 循环5000圈容量保持率为9 2. 6 %) 和优异的防冻性能(在−20 ° C 下循环5 0 0 圈比容量为190 mA h g−1). 本工作为高性能水系锌离子电池的发展提供了一种有前景的策略.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced battery technologies research · Perovskite Materials and Applications · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
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