Cobalt-decorated carbon nanotube bottlebrushes for boosting polysulfide conversion in lithium-sulfur batteries
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Abstract
开发具有多层次结构(包括多孔结构、杂化骨架和/或拓扑形貌)的超结构碳材料, 对于满足电化学储能和转换系统中复杂催化反应的需求非常关键. 在本文中, 我们以钴纳米颗粒为催化位点, 在杂化碳纳米管骨架表面可控接枝毛发状碳纳米管, 开发了一类层次化多孔的钴修饰碳纳米管瓶刷(Co/CNTBs). 其中, 精确的瓶刷状拓扑形貌和分级多孔结构能够有效地提供可及表/界面和高导电网络, 钴修饰的杂化骨架可以促进硫的氧化还原反应动力学. 因此, 基于Co/CNTBs功能化隔膜的锂硫电池具有优异的倍率性能(在10 C下比容量为707 mA h g−1)和长效的循环稳定性. 更重要的是, 基于Co/CNTBs催化剂的高硫载量电池(6.72 mg cm−2)在0.1 C下循环100圈后仍具有4.81 mA h cm−2的高面积容量. 本工作为高性能超结构杂化碳材料的原位接枝合成策略带来了新的思路, 有望用于众多具有挑战性的应用.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research
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References (73)
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1. Dunn B, Kamath H, Tarascon JM. Electrical energy storage for the grid: A battery of choices. Science, 2011, 334: 928–93510.1126/science.1212741 ↗
2. Lim WG, Kim S, Jo C, et al. A comprehensive review of materials with catalytic effects in Li-S batteries: Enhanced redox kinetics. Angew Chem Int Ed, 2019, 58: 18746–1875710.1002/anie.201902413 ↗
3. Fan L, Li M, Li X, et al. Interlayer material selection for lithium-sulfur batteries. Joule, 2019, 3: 361–38610.1016/j.joule.2019.01.003 ↗
4. Zhang Y, Li X, Fan L, et al. Ultrathin and super-tough membrane for anti-dendrite separator in aqueous zinc-ion batteries. Cell Rep Phys Sci, 2022, 3: 10082410.1016/j.xcrp.2022.100824 ↗
5. Liang Y, Chen L, Zhuang D, et al. Fabrication and nanostructure control of super-hierarchical carbon materials from heterogeneous bottlebrushes. Chem Sci, 2017, 8: 2101–210610.1039/C6SC03961H ↗
6. Liu S, Li J, Yan X, et al. Superhierarchical cobalt-embedded nitrogen-doped porous carbon nanosheets as two-in-one hosts for high-performance lithium-sulfur batteries. Adv Mater, 2018, 30: 170689510.1002/adma.201706895 ↗
7. Wu D, Xu F, Sun B, et al. Design and preparation of porous polymers. Chem Rev, 2012, 112: 3959–401510.1021/cr200440z ↗
8. Lu Y, Tang Y, Liu R, et al. Multifunctional templating strategy for fabrication of Fe, N-codoped hierarchical porous carbon nanosheets. Chin J Polym Sci, 2021, 40: 2–610.1007/s10118-022-2656-x ↗
9. Li W, Chen K, Xu Q, et al. Mo2C/C hierarchical double-shelled hollow spheres as sulfur host for advanced Li-S batteries. Angew Chem Int Ed, 2021, 60: 21512–2152010.1002/anie.202108343 ↗
10. Guo Y, Tang J, Henzie J, et al. Assembly of hollow mesoporous nanoarchitectures composed of ultrafine Mo2C nanoparticles on N-doped carbon nanosheets for efficient electrocatalytic reduction of oxygen. Mater Horiz, 2017, 4: 1171–117710.1039/C7MH00586E ↗
11. Cheng Y, Gong J, Cao B, et al. An ingenious strategy to integrate multiple electrocatalytically active components within a well-aligned nitrogen-doped carbon nanotube array electrode for electrocatalysis. ACS Catal, 2021, 11: 3958–397410.1021/acscatal.0c04975 ↗
12. Xie W, Li J, Song Y, et al. Hierarchical carbon microtube@nanotube core-shell structure for high-performance oxygen electrocatalysis and Zn-air battery. Nano-Micro Lett, 2020, 12: 9710.1007/s40820-020-00435-z ↗
13. Xia D, Tang F, Yao X, et al. Seeded growth of branched iron-nitrogen-doped carbon nanotubes as a high performance and durable non-precious fuel cell cathode. Carbon, 2020, 162: 300–30710.1016/j.carbon.2020.02.046 ↗
14. Luo H, Jiang WJ, Niu S, et al. Self-catalyzed growth of Co-N-C nanobrushes for efficient rechargeable Zn-air batteries. Small, 2020, 16: 200117110.1002/smll.202001171 ↗
15. Guo K, Xi B, Wei R, et al. Hierarchical microcables constructed by CoP@Cccarbon framework intertwined with carbon nanotubes for efficient lithium storage. Adv Energy Mater, 2020, 10: 190291310.1002/aenm.201902913 ↗
16. Cheng N, Wang N, Ren L, et al. In-situ grafting of N-doped carbon nanotubes with Ni encapsulation onto MOF-derived hierarchical hybrids for efficient electrocatalytic hydrogen evolution. Carbon, 2020, 163: 178–18510.1016/j.carbon.2020.03.017 ↗
17. Du M, Song D, Huang A, et al. Stereoselectively assembled metal-organic framework (MOF) host for catalytic synthesis of carbon hybrids for alkaline-metal-ion batteries. Angew Chem Int Ed, 2019, 58: 5307–531110.1002/anie.201900240 ↗
18. Zou L, Hou CC, Liu Z, et al. Superlong single-crystal metal-organic framework nanotubes. J Am Chem Soc, 2018, 140: 15393–1540110.1021/jacs.8b09092 ↗
19. Li G, Lei W, Luo D, et al. Stringed “tube on cube” nanohybrids as compact cathode matrix for high-loading and lean-electrolyte lithium-sulfur batteries. Energy Environ Sci, 2018, 11: 2372–238110.1039/C8EE01377B ↗
20. Davis BF, Yan X, Muralidharan N, et al. Electrically conductive hierarchical carbon nanotube networks with tunable mechanical response. ACS Appl Mater Interfaces, 2016, 8: 28004–2801110.1021/acsami.6b10726 ↗
21. Gupta B, Hossain MA, Riaz A, et al. Recent advances in materials design using atomic layer deposition for energy applications. Adv Funct Mater, 2021, 32: 210910510.1002/adfm.202109105 ↗
22. Carter R, Davis B, Oakes L, et al. A high areal capacity lithium-sulfur battery cathode prepared by site-selective vapor infiltration of hierarchical carbon nanotube arrays. Nanoscale, 2017, 9: 15018–1502610.1039/C7NR02368E ↗
23. Lai Q, Zhao Y, Liang Y, et al. In situ confinement pyrolysis transformation of ZIF-8 to nitrogen-enriched meso-microporous carbon frameworks for oxygen reduction. Adv Funct Mater, 2016, 26: 8334–834410.1002/adfm.201603607 ↗
24. Wang H, Li S, Wang Y, et al. Bioinspired fluffy fabric with in situ grown carbon nanotubes for ultrasensitive wearable airflow sensor. Adv Mater, 2020, 32: 190821410.1002/adma.201908214 ↗
25. Na Z, Yao R, Yan Q, et al. Identification of catalytic sites for cerium redox reactions in a metal-organic framework derived powerful electrocatalyst. Energy Storage Mater, 2020, 32: 11–1910.1016/j.ensm.2020.06.022 ↗
26. Mofokeng TP, Tetana ZN, Ozoemena KI. Defective 3D nitrogen-doped carbon nanotube-carbon fibre networks for high-performance supercapacitor: Transformative role of nitrogen-doping from surface-confined to diffusive kinetics. Carbon, 2020, 169: 312–32610.1016/j.carbon.2020.07.049 ↗
27. Jo MS, Lee JS, Jeong SY, et al. Golden bristlegrass-like hierarchical graphene nanofibers entangled with N-doped CNTs containing CoSe2 nanocrystals at each node as anodes for high-rate sodium-ion batteries. Small, 2020, 16: 200339110.1002/smll.202003391 ↗
28. Sun M, Boo C, Shi W, et al. Engineering carbon nanotube forest superstructure for robust thermal desalination membranes. Adv Funct Mater, 2019, 29: 190312510.1002/adfm.201903125 ↗
29. Li T, Luo G, Liu K, et al. Encapsulation of Ni3Fe nanoparticles in N-doped carbon nanotube-grafted carbon nanofibers as high-efficiency hydrogen evolution electrocatalysts. Adv Funct Mater, 2018, 28: 180582810.1002/adfm.201805828 ↗
30. Liu S, Wang Z, Zhou S, et al. Metal-organic-framework-derived hybrid carbon nanocages as a bifunctional electrocatalyst for oxygen reduction and evolution. Adv Mater, 2017, 29: 170087410.1002/adma.201700874 ↗
31. Ju Z, Li P, Ma G, et al. Few layer nitrogen-doped graphene with highly reversible potassium storage. Energy Storage Mater, 2018, 11: 38–4610.1016/j.ensm.2017.09.009 ↗
32. Zhang W, Jiang X, Wang X, et al. Spontaneous weaving of graphitic carbon networks synthesized by pyrolysis of ZIF-67 crystals. Angew Chem Int Ed, 2017, 56: 8435–844010.1002/anie.201701252 ↗
33. Wang S, Qin J, Meng T, et al. Metal-organic framework-induced construction of actiniae-like carbon nanotube assembly as advanced multifunctional electrocatalysts for overall water splitting and Zn-air batteries. Nano Energy, 2017, 39: 626–63810.1016/j.nanoen.2017.07.043 ↗
34. Li D, Jia Y, Chang G, et al. A defect-driven metal-free electrocatalyst for oxygen reduction in acidic electrolyte. Chem, 2018, 4: 2345–235610.1016/j.chempr.2018.07.005 ↗
35. Li X, Li K, Zhu S, et al. Fiber-in-tube design of Co9S8-carbon/Co9S8: Enabling efficient sodium storage. Angew Chem Int Ed, 2019, 58: 6239–624310.1002/anie.201900076 ↗
36. Yan D, Li Y, Huo J, et al. Defect chemistry of nonprecious-metal electrocatalysts for oxygen reactions. Adv Mater, 2017, 29: 160645910.1002/adma.201606459 ↗
37. Wang R, Luo C, Wang T, et al. Bidirectional catalysts for liquid-solid redox conversion in lithium-sulfur batteries. Adv Mater, 2020, 32: 200031510.1002/adma.202000315 ↗
38. Yue XY, Zhang J, Bao J, et al. Sputtered MoN nanolayer as a multifunctional polysulfide catalyst for high-performance lithium-sulfur batteries. eScience, 2022, 2: 329–33810.1016/j.esci.2022.03.003 ↗
39. Jiang B, Tian D, Qiu Y, et al. High-index faceted nanocrystals as highly efficient bifunctional electrocatalysts for high-performance lithium-sulfur batteries. Nano-Micro Lett, 2021, 14: 4010.1007/s40820-021-00769-2 ↗
40. Fan FY, Carter WC, Chiang YM. Mechanism and kinetics of Li2S precipitation in lithium-sulfur batteries. Adv Mater, 2015, 27: 5203–520910.1002/adma.201501559 ↗
41. Sun X, Tian D, Song X, et al. In situ conversion to construct fast ion transport and high catalytic cathode for high-sulfur loading with lean electrolyte lithium-sulfur battery. Nano Energy, 2022, 95: 10697910.1016/j.nanoen.2022.106979 ↗
42. Wang P, Xi B, Zhang Z, et al. Atomic tungsten on graphene with unique coordination enabling kinetically boosted lithium-sulfur batteries. Angew Chem Int Ed, 2021, 60: 15563–1557110.1002/anie.202104053 ↗
43. Yao W, Zheng W, Xu J, et al. ZnS-SnS@NC heterostructure as robust lithiophilicity and sulfiphilicity mediator toward high-rate and long-life lithium-sulfur batteries. ACS Nano, 2021, 15: 7114–713010.1021/acsnano.1c00270 ↗
44. Chen P, Wu Z, Guo T, et al. Strong chemical interaction between lithium polysulfides and flame-retardant polyphosphazene for lithium-sulfur batteries with enhanced safety and electrochemical performance. Adv Mater, 2021, 33: 200754910.1002/adma.202007549 ↗
45. Li Y, Gao T, Ni D, et al. Two birds with one stone: Interfacial engineering of multifunctional Janus separator for lithium-sulfur batteries. Adv Mater, 2022, 34: 210763810.1002/adma.202107638 ↗
46. Li P, Lv H, Li Z, et al. The electrostatic attraction and catalytic effect enabled by ionic-covalent organic nanosheets on MXene for separator modification of lithium-sulfur batteries. Adv Mater, 2021, 33: 200780310.1002/adma.202007803 ↗
47. Li Z, Zhou C, Hua J, et al. Engineering oxygen vacancies in a polysulfide-blocking layer with enhanced catalytic ability. Adv Mater, 2020, 32: 190744410.1002/adma.201907444 ↗
48. Li Y, Lin S, Wang D, et al. Single atom array mimic on ultrathin MOF nanosheets boosts the safety and life of lithium-sulfur batteries. Adv Mater, 2020, 32: 190672210.1002/adma.201906722 ↗
49. Li G, Lu F, Dou X, et al. Polysulfide regulation by the zwitterionic barrier toward durable lithium-sulfur batteries. J Am Chem Soc, 2020, 142: 3583–359210.1021/jacs.9b13303 ↗
50. Zhang L, Liu D, Muhammad Z, et al. Single nickel atoms on nitrogen-doped graphene enabling enhanced kinetics of lithium-sulfur batteries. Adv Mater, 2019, 31: 190395510.1002/adma.201903955 ↗
51. Xue W, Yu D, Suo L, et al. Manipulating sulfur mobility enables advanced Li-S batteries. Matter, 2019, 1: 1047–106010.1016/j.matt.2019.07.002 ↗
52. Pei F, Lin L, Fu A, et al. A two-dimensional porous carbon-modified separator for high-energy-density Li-S batteries. Joule, 2018, 2: 323–33610.1016/j.joule.2017.12.003 ↗
53. Yang B, Guo D, Lin P, et al. Hydroxylated multi-walled carbon nanotubes covalently modified with tris(hydroxypropyl) phosphine as a functional interlayer for advanced lithium-sulfur batteries. Angew Chem Int Ed, 2022, 61: e20220432710.1002/anie.202204327 ↗
54. Zhao CX, Li XY, Zhao M, et al. Semi-immobilized molecular electrocatalysts for high-performance lithium-sulfur batteries. J Am Chem Soc, 2021, 143: 19865–1987210.1021/jacs.1c09107 ↗
55. Shi N, Xi B, Liu J, et al. Dual-functional NbN ultrafine nanocrystals enabling kinetically boosted lithium-sulfur batteries. Adv Funct Mater, 2022, 32: 211158610.1002/adfm.202111586 ↗
56. Shi M, Liu Z, Zhang S, et al. A Mott-Schottky heterogeneous layer for Li-S batteries: Enabling both high stability and commercial-sulfur utilization. Adv Energy Mater, 2022, 12: 210365710.1002/aenm.202103657 ↗
57. Park JS, Park DY, Yang SM, et al. Dimension-controlled N-doped graphitic carbon nanostructures through low-temperature metal-catalyzed transformation from C3N4 for high-performance electrochemical barrier in lithium-sulfur batteries. Carbon, 2022, 196: 304–31210.1016/j.carbon.2022.05.001 ↗
58. Mao J, Niu D, Huang G, et al. A Ni/Ni2P heterostructure in modified porous carbon separator for boosting polysulfide catalytic conversion. Sci China Mater, 2022, 65: 2453–246210.1007/s40843-021-1982-5 ↗
59. Dong Y, Cai D, Li T, et al. Sulfur reduction catalyst design inspired by elemental periodic expansion concept for lithium-sulfur batteries. ACS Nano, 2022, 16: 6414–642510.1021/acsnano.2c00515 ↗
60. Zhang X, Li G, Zhang Y, et al. Amorphizing metal-organic framework towards multifunctional polysulfide barrier for high-performance lithium-sulfur batteries. Nano Energy, 2021, 86: 10609410.1016/j.nanoen.2021.106094 ↗
61. Xu J, An S, Song X, et al. Towards high performance Li-S batteries via sulfonate-rich COF-modified separator. Adv Mater, 2021, 33: 210517810.1002/adma.202105178 ↗
62. Wu Z, Chen S, Wang L, et al. Implanting nickel and cobalt phosphide into well-defined carbon nanocages: A synergistic adsorption-electrocatalysis separator mediator for durable high-power Li-S batteries. Energy Storage Mater, 2021, 38: 381–38810.1016/j.ensm.2021.03.026 ↗
63. Wang M, Sun Z, Ci H, et al. Identifying the evolution of selenium-vacancy-modulated MoSe2 precatalyst in lithium-sulfur chemistry. Angew Chem Int Ed, 2021, 60: 24558–2456510.1002/anie.202109291 ↗
64. Lei D, Shang W, Zhang X, et al. Facile synthesis of heterostructured MoS2-MoO3 nanosheets with active electrocatalytic sites for high-performance lithium-sulfur batteries. ACS Nano, 2021, 15: 20478–2048810.1021/acsnano.1c09007 ↗
65. Du Z, Guo Y, Wang H, et al. High-throughput production of 1T MoS2 monolayers based on controllable conversion of Mo-based MXenes. ACS Nano, 2021, 15: 19275–1928310.1021/acsnano.1c05268 ↗
66. Cai Q, Wang J, Jiao Y, et al. All-graphitic multilaminate mesoporous membranes by interlayer-confined molecular assembly. Small, 2021, 17: 210117310.1002/smll.202101173 ↗
67. Zhang S, Zhong N, Zhou X, et al. Comprehensive design of the high-sulfur-loading Li-S battery based on MXene nanosheets. Nano-Micro Lett, 2020, 12: 11210.1007/s40820-020-00449-7 ↗
68. Yu Z, Wang B, Liao X, et al. Boosting polysulfide redox kinetics by graphene-supported Ni nanoparticles with carbon coating. Adv Energy Mater, 2020, 10: 200090710.1002/aenm.202000907 ↗
69. Li Z, Zhang F, Cao T, et al. Highly stable lithium-sulfur batteries achieved by a SnS/porous carbon nanosheet architecture modified celgard separator. Adv Funct Mater, 2020, 30: 200629710.1002/adfm.202006297 ↗
70. Hu X, Zhong L, Shu C, et al. Versatile, aqueous soluble C2N quantum dots with enriched active edges and oxygenated groups. J Am Chem Soc, 2020, 142: 4621–463010.1021/jacs.9b11169 ↗
71. Yuan H, Peng HJ, Li BQ, et al. Conductive and catalytic triple-phase interfaces enabling uniform nucleation in high-rate lithium-sulfur batteries. Adv Energy Mater, 2019, 9: 180276810.1002/aenm.201802768 ↗
72. Xie J, Li BQ, Peng HJ, et al. Implanting atomic cobalt within mesoporous carbon toward highly stable lithium-sulfur batteries. Adv Mater, 2019, 31: 190381310.1002/adma.201903813 ↗
73. Li BQ, Peng HJ, Chen X, et al. Polysulfide electrocatalysis on framework porphyrin in high-capacity and high-stable lithium-sulfur batteries. CCS Chem, 2019, 1: 128–13710.31635/ccschem.019.20180016 ↗