journal article·2024-10

Switchable K–O bonds unveiling anomalous ferroelastic transitions in a polar hybrid crystal

Yao-Bin Li, Wei-Jian Xu, Xiao-Xian Chen, De-Xuan Liu, Zhi-Shuo Wang, Wei-Xiong Zhang

Science China Materials· Volume 67· Issue 10
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Solid-state spectroscopy and crystallography · Crystal Structures and Properties · Acoustic Wave Resonator Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. Aizu K. Possible species of “ferroelastic” crystals and of simultaneously ferroelectric and ferroelastic crystals. J Phys Soc Jpn, 1969, 27: 387–39610.1143/JPSJ.27.387 ↗
2. Salje EKH. Ferroelastic materials. Annu Rev Mater Res, 2012, 42: 265–28310.1146/annurev-matsci-070511-155022 ↗
3. Liu M, Howe BM, Grazulis L, et al. Voltage-impulse-induced nonvolatile ferroelastic switching of ferromagnetic resonance for reconfigurable magnetoelectric microwave devices. Adv Mater, 2013, 25: 4886–489210.1002/adma.201301989 ↗
4. Baek SH, Jang HW, Folkman CM, et al. Ferroelastic switching for nanoscale non-volatile magnetoelectric devices. Nat Mater, 2010, 9: 309–31410.1038/nmat2703 ↗
5. Zhang Y, Han MG, Garlow JA, et al. Deterministic ferroelastic domain switching using ferroelectric bilayers. Nano Lett, 2019, 19: 5319–532610.1021/acs.nanolett.9b01782 ↗
6. Hu Y, You L, Xu B, et al. Ferroelastic-switching-driven large shear strain and piezoelectricity in a hybrid ferroelectric. Nat Mater, 2021, 20: 612–61710.1038/s41563-020-00875-3 ↗
7. He X, Chen C, Wang L, et al. Giant electromechanical response in layered ferroelectrics enabled by asymmetric ferroelastic switching. Mater Today, 2022, 58: 48–5610.1016/j.mattod.2022.07.010 ↗
8. Liang BD, Fan CC, Liu CD, et al. Near-room-temperature martensitic actuation profited from one-dimensional hybrid perovskite structure. Nat Commun, 2022, 13: 659910.1038/s41467-022-34356-9 ↗
9. Lu X, Chen Z, Cao Y, et al. Mechanical-force-induced non-local collective ferroelastic switching in epitaxial lead-titanate thin films. Nat Commun, 2019, 10: 395110.1038/s41467-019-11825-2 ↗
10. Park SK, Sun H, Chung H, et al. Super- and ferroelastic organic semiconductors for ultraflexible single-crystal electronics. Angew Chem, 2020, 132: 13104–1311210.1002/ange.202004083 ↗
11. Yue Z, Wu F, Li X, et al. Centimeter-sized single crystal of a lead-free halide double perovskite with ferroelastic phase transition-triggered switchable dielectric properties. Sci China Mater, 2023, 66: 3977–398310.1007/s40843-023-2541-8 ↗
12. Liu DX, Yu ZH, Chen XX, et al. Crystal structures and phase transitions in two new hybrid crystals: (Me3NCH2CH2X)4[Ni(NCS)6] (X = Cl and Br). Chin Chem Lett, 2023, 34: 10731010.1016/j.cclet.2022.03.033 ↗
13. Wojciechowska M, Gągor A, Piecha-Bisiorek A, et al. Ferroelectricity and ferroelasticity in organic inorganic hybrid (pyrrolidinium)3-[Sb2Cl9]. Chem Mater, 2018, 30: 4597–460810.1021/acs.chemmater.8b00962 ↗
14. Chen XX, Liu DX, Gong YP, et al. Above-room-temperature ferroelastic phase transitions in two tetrafluoroborate-based hexagonal molecular perovskites. Inorg Chem, 2022, 61: 2219–222610.1021/acs.inorgchem.1c03506 ↗
15. Su CY, Yao YF, Zhang ZX, et al. The construction of a two-dimensional organic–inorganic hybrid double perovskite ferroelastic with a high Tc and narrow band gap. Chem Sci, 2022, 13: 4794–480010.1039/D1SC07045B ↗
16. Yuan W, Zeng Y, Tan YY, et al. A new ferroelastic hybrid material with a large spontaneous strain: (Me3NOH)2[ZnCl4]. Chem Commun, 2019, 55: 8983–898610.1039/C9CC03862K ↗
17. Ye H, Chen XX, Liu DX, et al. Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic. Chem Sci, 2022, 13: 14124–1413110.1039/D2SC04112J ↗
18. Bari M, Bokov AA, Ye ZG. Ferroelasticity, domain structures and phase symmetries in organic–inorganic hybrid perovskite methylammonium lead chloride. J Mater Chem C, 2020, 8: 9625–963110.1039/D0TC02124E ↗
19. Chen XX, Zhang XY, Liu DX, et al. Room-temperature ferroelectric and ferroelastic orders coexisting in a new tetrafluoroborate-based perovskite. Chem Sci, 2021, 12: 8713–872110.1039/D1SC01345A ↗
20. Xiong R, Lu S, Zhang Z, et al. A chiral thermochromic ferroelastic with seven physical channel switches. Angew Chem Int Ed, 2020, 59: 9574–957810.1002/anie.202000290 ↗
21. Meng QR, Xu WJ, Hu WH, et al. An unprecedented hexagonal double perovskite organic–inorganic hybrid ferroelastic material: (Piperidinium)2[KBiCl6]. Chem Commun, 2021, 57: 6292–629510.1039/D1CC02085D ↗
22. Zhang HY, Hu CL, Hu ZB, et al. Narrow band gap observed in a molecular ferroelastic: Ferrocenium tetrachloroferrate. J Am Chem Soc, 2020, 142: 3240–324510.1021/jacs.9b13446 ↗
23. Gong Y, Chen X, Zhao B, et al. Ferroelastic phase transitions in three new layered perovskites: (3-XC6H5CH2CH2NH3)2[CdCl4] (X = F, Cl, and Br). Chin Chem Lett, 2023, 34: 10828210.1016/j.cclet.2023.108282 ↗
24. Luo W, Wang N, Li HK, et al. Fast rotating dipole array inducing large dielectric response in a Ruddlesden–Popper hybrid perovskite ferroelastic. Inorg Chem Front, 2023, 10: 5082–508810.1039/D3QI01000G ↗
25. Xu WJ, Zelenovskii P, Tselev A, et al. A hybrid double perovskite ferroelastic exhibiting the highest number of orientation states. Chem Commun, 2023, 59: 11264–1126710.1039/D3CC02645K ↗
26. Zhang H, Li QL, Tan YH, et al. High-temperature ferroelasticity and photoluminescence in a 2D monolayer perovskite compound: (C5NH8Br)2PbBr4. Inorg Chem, 2023, 62: 10847–1085310.1021/acs.inorgchem.3c01552 ↗
27. Gong YP, Chen XX, Huang GZ, et al. Ferroelasticity, thermochromism, semi-conductivity, and ferromagnetism in a new layered perovskite: (4-Fluorophenethylaminium)2[CuCl4]. J Mater Chem C, 2022, 10: 5482–548810.1039/D2TC00335J ↗
28. He L, Shi PP, Zhao MM, et al. Emergent chirality and nonlinear optical switching in a ferroelastic molecular perovskite solid solution. Chem Mater, 2021, 33: 799–80510.1021/acs.chemmater.0c04735 ↗
29. Zhang HY, Zhang N, Zhang Y, et al. Ferroelectric phase transition driven by switchable covalent bonds. Phys Rev Lett, 2023, 130: 17680210.1103/PhysRevLett.130.176802 ↗
30. Li R, Zhu T, Zhu ZK, et al. Unique perovskitizer N–Pb bond switching induced polar photovoltaic effect in trilayered hybrid perovskite. Small, 2024, 20: 230682510.1002/smll.202306825 ↗
31. Xu WJ, Li PF, Tang YY, et al. A molecular perovskite with switchable coordination bonds for high-temperature multiaxial ferroelectrics. J Am Chem Soc, 2017, 139: 6369–637510.1021/jacs.7b01334 ↗
32. Xu WJ, Romanyuk K, Zeng Y, et al. Statics and dynamics of ferroelectric domains in molecular multiaxial ferroelectric (Me3NOH)2-[KCo(CN)6]. J Mater Chem C, 2021, 9: 10741–1074810.1039/D1TC01261D ↗
33. Xu WJ, Zeng Y, Yuan W, et al. A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism. Chem Commun, 2020, 56: 10054–1005710.1039/D0CC04092D ↗
34. Chen XG, Zhang ZX, Zeng YL, et al. H/F substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic. Chem Commun, 2022, 58: 3059–306210.1039/D2CC00586G ↗
35. Aizu K. Determination of the state parameters and formulation of spontaneous strain for ferroelastics. J Phys Soc Jpn, 1970, 28: 706–71610.1143/JPSJ.28.706 ↗
36. Hoshino N, Akutagawa T. Inversion symmetry breaking in orderdisorder transitions of globular ligands coordinating to cobalt(II) and nickel(II) bisacetylacetonato complexes during heating. Chem Eur J, 2021, 27: 4064–406910.1002/chem.202004492 ↗
37. Szafrański M. Reverse group-subgroup relation at the ferroelastic phase transition in [(C2H5)4N][(CH3)4N]MnBr4. Cryst Growth Des, 2016, 16: 3771–377610.1021/acs.cgd.6b00279 ↗
38. Wang N, Luo W, Shen H, et al. Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chin Chem Lett, 2024, 35: 10869610.1016/j.cclet.2023.108696 ↗
39. Miao LP, Chu LL, Han XB, et al. A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking. Inorg Chem Front, 2021, 8: 2809–281610.1039/D1QI00309G ↗
40. Chen XR, Liu SX, Ren Q, et al. Wide magnetic thermal memory effect (∼55 K) above room temperature coupled to a structure phase transition of lattice symmetry reduction in high-temperature phase in an S = 1/2 spin chain molecule crystal. J Phys Chem B, 2018, 122: 12428–1243510.1021/acs.jpcb.8b10492 ↗
41. Wang P, Zhang M, Wei Z, et al. 3D perovskite (1,5-3.2.2-H2dabcn) CsBr3 with reverse symmetry breaking. Inorg Chem, 2022, 61: 16414–1642010.1021/acs.inorgchem.2c02497 ↗
42. Jiao S, Sun X, Zhao M, et al. Halide anions tuning of lead-free perovskite-type ferroelectric semiconductors with inverse high-temperature symmetry breaking. Small, 2024, 20: 231076810.1002/smll.202310768 ↗
43. Zhan LY, Zhou Y, Li N, et al. A high working temperature multiferroic induced by inverse temperature symmetry breaking. J Am Chem Soc, 2024, 146: 5414–542210.1021/jacs.3c12842 ↗
44. Solans X, Gonzalez-Silgo C, Ruiz-Pérez C. A structural study on the rochelle salt. J Solid State Chem, 1997, 131: 350–35710.1006/jssc.1997.7394 ↗
45. Zhao BQ, Chen XX, Ye H, et al. An anomalous ferroelastic phase transition arising from an unusual cis-/anti-conformational reversal of polar organic cations. Chem Sci, 2023, 14: 5965–597310.1039/D3SC01101A ↗
46. Liu DX, Chen XX, Ye ZM, et al. High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me3NCH2CH2OH)4[Ni(NCS)6]. Sci China Mater, 2022, 65: 263–26710.1007/s40843-021-1794-1 ↗
47. Li YB, Chen XX, Xu WJ, et al. Designing dynamic coordination bonds in polar hybrid crystals for a high-temperature ferroelastic transition. Chem Sci, 2024, 15: 3661–366910.1039/D3SC06702E ↗
48. Dolomanov OV, Bourhis LJ, Gildea RJ, et al. OLEX2: A complete structure solution, refinement and analysis program. J Appl Crystlogr, 2009, 42: 339–34110.1107/S0021889808042726 ↗
49. Sheldrick GM. SHELXT—Integrated space-group and crystal-structure determination. Acta Crystlogr Found Adv, 2015, 71: 3–810.1107/S2053273314026370 ↗
50. He L, Shi PP, Zhou L, et al. Coexisting ferroelectric and ferroelastic orders in rare 3D homochiral hybrid bimetal halides. Chem Mater, 2021, 33: 6233–623910.1021/acs.chemmater.1c02084 ↗
51. He L, Xu K, Shi PP, et al. A rare 3D hybrid bimetal halide ferroelectric: (3-Hydroxypyrrolidinium)2RbBiBr6. Sci China Mater, 2022, 65: 2879–288310.1007/s40843-022-2030-x ↗
52. Xu WJ, Chen SL, Hu ZT, et al. The cation-dependent structural phase transition and dielectric response in a family of cyano-bridged perovskite-like coordination polymers. Dalton Trans, 2016, 45: 4224–422910.1039/C5DT03481G ↗
53. Peng H, Liu YH, Huang XQ, et al. Homochiral one-dimensional ABX3 lead halide perovskites with high-Tc quadratic nonlinear optical and dielectric switchings. Mater Chem Front, 2021, 5: 4756–476310.1039/D1QM00223F ↗
54. Qiu RG, Chen XX, Huang RK, et al. Nitroprusside as a promising building block to assemble an organic–inorganic hybrid for thermoresponsive switching materials. Chem Commun, 2020, 56: 5488–549110.1039/D0CC01877E ↗
55. Zhao XM, Li D, Zhao HX, et al. Polar molecule-based material with optic–electric switching constructed by polar anions. Inorg Chem, 2020, 59: 5475–548210.1021/acs.inorgchem.0c00096 ↗
56. Han S, Li L, Ji C, et al. Visible-photoactive perovskite ferroelectric-driven self-powered gas detection. J Am Chem Soc, 2023, 145: 12853–1286010.1021/jacs.3c03719 ↗
57. Mao L, Wu Y, Stoumpos CC, et al. White-light emission and structural distortion in new corrugated two-dimensional lead bromide perovskites. J Am Chem Soc, 2017, 139: 5210–521510.1021/jacs.7b01312 ↗
58. Cliffe MJ, Goodwin AL. PASCal: A principal axis strain calculator for thermal expansion and compressibility determination. J Appl Crystlogr, 2012, 45: 1321–132910.1107/S0021889812043026 ↗
59. Spackman MA, Jayatilaka D. Hirshfeld surface analysis. CrystEngComm, 2009, 11: 19–3210.1039/B818330A ↗