Cationic and anionic energetic materials based on a new amphotère
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Abstract
本文报道了5,5ʹ-二氨基-4,4ʹ-二硝氨基-3,3ʹ-双-1,2,4-三唑( 1 )的第一种阳离子形式及其合成和表征. 化合物 1 与硝酸反应生成了 5 , 与RDX相比, 这是一种具有更高的分解温度和更好爆轰性能的炸药, 与HMX相比其感度更低. 1 的阴离子作为配体和钾离子的自组装合成了起爆药 4 , 与目前广泛使用的Pb(N3)2相比较, 它的性能更加优异. 两性化合物 1 的两个衍生物的分离具有重要意义: (1) 说明了化合物 1 的两性性质; (2) 开启了它们作为有前景的含能前体的研究, 为更多含能离子盐的合成提供参考.
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OpenAlex topics: Energetic Materials and Combustion · Rocket and propulsion systems research · Thermal and Kinetic Analysis
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References (39)
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