Self-carbonization of soluble organic cathodes enables stable Na-ion batteries
Source abstract
Abstract
为了解决小分子有机正极在钠离子电池(SIBs)中的溶解问题, 我们提出了一种有效的有机电极表面自碳化策略, 并制备了新型可溶性小分子有机化合物NTCDI-DAQ对该策略进行验证. 通过对惰性气氛下碳化温度和碳化时间的精确控制, 在NTCDI-DAQ颗粒表面成功形成了厚度为30–40 nm的碳层, 可在不影响NTCDI-DAQ电化学行为的前提下, 有效消除其溶解问题. 在半电池中, NTCDI-DAQ@C在1 A g−1下循环10,000次后仍能保持155 mA h g−1的优异放电容量. 在使用Na3Bi为负极的全电池中, NTCDI-DAQ@C可以提供高达245 mA h g−1cathode的峰值放电容量, 且在0.1 A g−1下循环200次后仍保持了223 mA h g−1的超稳定容量. 据我们所知, NTCDI-DAQ@C是SIBs中最好的小分子有机正极之一, NTCDI-DAQ@C//Na3Bi SIBs的卓越综合性能也可与目前最先进的SIBs相媲美.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. Hu J, Hong Y, Guo M, et al. Emerging organic electrodes for Na-ion and K-ion batteries. Energy Stor Mater, 2023, 56: 267–299
2. Lee M, Hong J, Lopez J, et al. High-performance sodium-organic battery by realizing four-sodium storage in disodium rhodizonate. Nat Energy, 2017, 2: 861–86810.1038/s41560-017-0014-y ↗
3. Abouimrane A, Weng W, Eltayeb H, et al. Sodium insertion in carboxylate based materials and their application in 3.6 V full sodium cells. Energy Environ Sci, 2012, 5: 963210.1039/c2ee22864e ↗
4. Ren W, Zhang H, Guan C, et al. Ultrathin MoS2 nanosheets@metal organic framework-derived N-doped carbon nanowall arrays as sodium ion battery anode with superior cycling life and rate capability. Adv Funct Mater, 2017, 27: 170211610.1002/adfm.201702116 ↗
5. Chen Y, Tang M, Wu Y, et al. A one-dimensional π-d conjugated coordination polymer for sodium storage with catalytic activity in Negishi coupling. Angew Chem Int Ed, 2019, 58: 14731–1473910.1002/anie.201908274 ↗
6. Hu Y, Gao Y, Fan L, et al. Electrochemical study of poly(2,6-anthraquinonyl sulfide) as cathode for alkali-metal-ion batteries. Adv Energy Mater, 2020, 10: 200278010.1002/aenm.202002780 ↗
7. Li L, Zuo Z, Wang F, et al. In situ coating graphdiyne for high-energy-density and stable organic cathodes. Adv Mater, 2020, 32: 200014010.1002/adma.202000140 ↗
8. Kapaev RR, Scherbakov AG, Shestakov AF, et al. m-Phenylenediamine as a building block for polyimide battery cathode materials. ACS Appl Energy Mater, 2021, 4: 4465–447210.1021/acsaem.1c00092 ↗
9. Wang C, Tang W, Jia S, et al. Benzene-bridged anthraquinones as a high-rate and long-lifespan organic cathode for advanced Na-ion batteries. Chem Eng J, 2021, 426: 13125110.1016/j.cej.2021.131251 ↗
10. Luo W, Allen M, Raju V, et al. An organic pigment as a high-performance cathode for sodium-ion batteries. Adv Energy Mater, 2014, 4: 140055410.1002/aenm.201400554 ↗
11. Wang H, Yuan S, Ma D, et al. Tailored aromatic carbonyl derivative polyimides for high-power and long-cycle sodium-organic batteries. Adv Energy Mater, 2014, 4: 130165110.1002/aenm.201301651 ↗
12. Hu J, Liang R, Tang W, et al. Synthesis of polyanionic anthraquinones as new insoluble organic cathodes for organic Na-ion batteries. Int J Hydrogen Energy, 2020, 45: 24573–2458110.1016/j.ijhydene.2020.06.151 ↗
13. Wang H, Zhang X. Organic carbonyl compounds for sodium-ion batteries: Recent progress and future perspectives. Chem Eur J, 2018, 24: 18235–1824510.1002/chem.201802517 ↗
14. Sakaushi K, Hosono E, Nickerl G, et al. Bipolar porous polymeric frameworks for low-cost, high-power, long-life all-organic energy storage devices. J Power Sources, 2014, 245: 553–55610.1016/j.jpowsour.2013.07.007 ↗
15. Wang S, Wang L, Zhu Z, et al. All organic sodium-ion batteries with Na4C8H2O6. Angew Chem Int Ed, 2014, 53: 5892–589610.1002/anie.201400032 ↗
16. Kim H, Kwon JE, Lee B, et al. High energy organic cathode for sodium rechargeable batteries. Chem Mater, 2015, 27: 7258–726410.1021/acs.chemmater.5b02569 ↗
17. Wang C, Fang Y, Xu Y, et al. Manipulation of disodium rhodizonate: Factors for fast-charge and fast-discharge sodium-ion batteries with long-term cyclability. Adv Funct Mater, 2016, 26: 1777–178610.1002/adfm.201504537 ↗
18. Feng X, Wu X, Chen X, et al. A bipolar organic molecule toward a universal pseudocapacitive cathode for stable dual ion charge storage. Energy Storage Mater, 2021, 42: 454–46310.1016/j.ensm.2021.08.003 ↗
19. Hu Y, Yu Q, Tang W, et al. Ultra-stable, ultra-long-lifespan and ultra-high-rate Na-ion batteries using small-molecule organic cathodes. Energy Storage Mater, 2021, 41: 738–74710.1016/j.ensm.2021.07.008 ↗
20. Liu T, Kim KC, Lee B, et al. Self-polymerized dopamine as an organic cathode for Li- and Na-ion batteries. Energy Environ Sci, 2017, 10: 205–21510.1039/C6EE02641A ↗
21. Zhao Q, Lu Y, Chen J. Advanced organic electrode materials for rechargeable sodium-ion batteries. Adv Energy Mater, 2017, 7: 160179210.1002/aenm.201601792 ↗
22. Tang M, Zhu S, Liu Z, et al. Tailoring π-conjugated systems: From π−π stacking to high-rate-performance organic cathodes. Chem, 2018, 4: 2600–261410.1016/j.chempr.2018.08.014 ↗
23. Xu S, Dai H, Zhu S, et al. A branched dihydrophenazine-based polymer as a cathode material to achieve dual-ion batteries with high energy and power density. eScience, 2021, 1: 60–6810.1016/j.esci.2021.08.002 ↗
24. Bhosale ME, Chae S, Kim JM, et al. Organic small molecules and polymers as an electrode material for rechargeable lithium ion batteries. J Mater Chem A, 2018, 6: 19885–1991110.1039/C8TA04906H ↗
25. Rajagopalan R, Tang Y, Jia C, et al. Understanding the sodium storage mechanisms of organic electrodes in sodium ion batteries: Issues and solutions. Energy Environ Sci, 2020, 13: 1568–159210.1039/C9EE03637G ↗
26. Wang X, Tang W, Hu Y, et al. Insoluble small-molecule organic cathodes for highly efficient pure-organic Li-ion batteries. Green Chem, 2021, 23: 6090–610010.1039/D1GC01927A ↗
27. Song Z, Zhan H, Zhou Y. Polyimides: Promising energy-storage materials. Angew Chem Int Ed, 2010, 49: 8444–844810.1002/anie.201002439 ↗
28. Nokami T, Matsuo T, Inatomi Y, et al. Polymer-bound pyrene-4,5,9,10-tetraone for fast-charge and -discharge lithium-ion batteries with high capacity. J Am Chem Soc, 2012, 134: 19694–1970010.1021/ja306663g ↗
29. Li D, Tang W, Tang F, et al. A low-cost Na-ion and K-ion batteries using a common organic cathode and bismuth anode. ChemSusChem, 2021, 14: 3815–382010.1002/cssc.202101386 ↗
30. Miao Y, Zong J, Liu X. Phosphorus-doped pitch-derived soft carbon as an anode material for sodium ion batteries. Mater Lett, 2017, 188: 355–35810.1016/j.matlet.2016.11.110 ↗
31. Zhu Y, Chen M, Li Q, et al. High-yield humic acid-based hard carbons as promising anode materials for sodium-ion batteries. Carbon, 2017, 123: 727–73410.1016/j.carbon.2017.08.030 ↗
32. Zhong X, Wu Y, Zeng S, et al. Carbon and carbon hybrid materials as anodes for sodium-ion batteries. Chem Asian J, 2018, 13: 1248–126510.1002/asia.201800132 ↗
33. Wang Z, Feng X, Bai Y, et al. Probing the energy storage mechanism of quasi-metallic Na in hard carbon for sodium-ion batteries. Adv Energy Mater, 2021, 11: 200385410.1002/aenm.202003854 ↗
34. Yu P, Tang W, Wu FF, et al. Recent progress in plant-derived hard carbon anode materials for sodium-ion batteries: A review. Rare Met, 2020, 39: 1019–103310.1007/s12598-020-01443-z ↗
35. Chen L, He X, Chen H, et al. N-doped carbon encapsulating Bi nanoparticles derived from metal-organic frameworks for high-performance sodium-ion batteries. J Mater Chem A, 2021, 9: 22048–2205510.1039/D1TA06558K ↗
36. Hu Y, Tang W, Yu Q, et al. Novel insoluble organic cathodes for advanced organic K-ion batteries. Adv Funct Mater, 2020, 30: 200067510.1002/adfm.202000675 ↗
37. Tian B, Ning GH, Tang W, et al. Polyquinoneimines for lithium storage: More than the sum of its parts. Mater Horiz, 2016, 3: 429–43310.1039/C6MH00072J ↗
38. Tian B, Zheng J, Zhao C, et al. Carbonyl-based polyimide and polyquinoneimide for potassium-ion batteries. J Mater Chem A, 2019, 7: 9997–1000310.1039/C9TA00647H ↗
39. Sun T, Feng X, Sun Q, et al. Solvation effect on the improved sodium storage performance of N-heteropentacenequinone for sodium-ion batteries. Angew Chem Int Ed, 2021, 60: 26806–2681210.1002/anie.202112112 ↗
40. Ming J, Cao Z, Wahyudi W, et al. New insights on graphite anode stability in rechargeable batteries: Li ion coordination structures prevail over solid electrolyte interphases. ACS Energy Lett, 2018, 3: 335–34010.1021/acsenergylett.7b01177 ↗
41. Fan L, Ma R, Wang J, et al. An ultrafast and highly stable potassium-organic battery. Adv Mater, 2018, 30: 180548610.1002/adma.201805486 ↗
42. Zhang S, Sun L, Yu L, et al. Core-shell CoSe2/WSe2 heterostructures@carbon in porous carbon nanosheets as advanced anode for sodium ion batteries. Small, 2021, 17: 210300510.1002/smll.202103005 ↗
43. Su D, Dou S, Wang G. Bismuth: A new anode for the Na-ion battery. Nano Energy, 2015, 12: 88–9510.1016/j.nanoen.2014.12.012 ↗
44. Zhang L, Wang WA, Lu S, et al. Carbon anode materials: A detailed comparison between Na-ion and K-ion batteries. Adv Energy Mater, 2021, 11: 200364010.1002/aenm.202003640 ↗