Diverse polyoxometalate-based cobalt complexes for catalyzing olefin epoxidation reaction at room temperature: regulation of active sites by polyoxometalate templates
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Polyoxometalates: Synthesis and Applications · Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. Bregante DT, Flaherty DW. Periodic trends in olefin epoxidation over group IV and V framework-substituted zeolite catalysts: a kinetic and spectroscopic study. J Am Chem Soc, 2017, 139: 6888–689810.1021/jacs.7b01422 ↗
2. He Q, Pu MP, Jiang Z, et al. Asymmetric epoxidation of alkenes catalyzed by a cobalt complex. J Am Chem Soc, 2023, 145: 15611–1561810.1021/jacs.3c05476 ↗
3. Song F, Wang C, Falkowski JM, et al. Isoreticular chiral metal–organic frameworks for asymmetric alkene epoxidation: tuning catalytic activity by controlling framework catenation and varying open channel sizes. J Am Chem Soc, 2010, 132: 15390–1539810.1021/ja1069773 ↗
4. Fingerhut A, Serdyuk OV, Tsogoeva SB. Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: towards sustainability. Green Chem, 2015, 17: 2042–205810.1039/C4GC02413C ↗
5. Li W, Chen K, Biney BW, et al. Hydrophobic and dispersible Cu(I) desulfurization adsorbent prepared from Pistia stratiotes for efficient desulfurization. Sci Total Environ, 2022, 819: 15305610.1016/j.scitotenv.2022.153056 ↗
6. Kamata K, Yonehara K, Sumida Y, et al. Efficient epoxidation of olefins with ⩾99% selectivity and use of hydrogen peroxide. Science, 2003, 300: 964–96610.1126/science.1083176 ↗
7. Tian S, Peng C, Dong J, et al. High-loading single-atomic-site silver catalysts with an Ag1–C2N1 structure showing superior performance for epoxidation of styrene. ACS Catal, 2021, 11: 4946–495410.1021/acscatal.1c00455 ↗
8. Liu H, Liu W, Xue G, et al. Modulating charges of dual sites in multivariate metal–organic frameworks for boosting selective aerobic epoxidation of alkenes. J Am Chem Soc, 2023, 145: 11085–1109610.1021/jacs.3c00460 ↗
9. Liu X, Wang Z, Yan T, et al. Simple synthesis of hierarchical Co-Meso-UTL zeolite for efficient epoxidation of styrene. Chem Eng J, 2023, 478: 14745510.1016/j.cej.2023.147455 ↗
10. Song X, Hu D, Yang X, et al. Polyoxomolybdic cobalt encapsulated within Zr-based metal–organic frameworks as efficient heterogeneous catalysts for olefins epoxidation. ACS Sustain Chem Eng, 2019, 7: 3624–363110.1021/acssuschemeng.8b06736 ↗
11. Madadi S, Bergeron JY, Kaliaguine S. Kinetic investigation of aerobic epoxidation of limonene over cobalt substituted mesoporous SBA-16. Catal Sci Technol, 2021, 11: 594–61110.1039/D0CY01700K ↗
12. Vanoye L, Wang J, Pablos M, et al. Epoxidation using molecular oxygen in flow: facts and questions on the mechanism of the Mukaiyama epoxidation. Catal Sci Technol, 2016, 6: 4724–473210.1039/C6CY00309E ↗
13. Hu N, Du J, Ma YY, et al. Unravelling the role of polyoxovanadates in electrocatalytic water oxidation reaction: active species or precursors. Appl Surf Sci, 2021, 540: 14830610.1016/j.apsusc.2020.148306 ↗
14. Van Santen R. The mechanism of ethylene epoxidation. J Catal, 1986, 98: 530–53910.1016/0021-9517(86)90341-6 ↗
15. Nijhuis TA, Makkee M, Moulijn JA, et al. The production of propene oxide: catalytic processes and recent developments. Ind Eng Chem Res, 2006, 45: 3447–345910.1021/ie0513090 ↗
16. Liu X, Huang J, Tao L, et al. Oxygen atom transfer mechanism for vanadium-oxo porphyrin complexes mediated aerobic olefin epoxidation. Chin J Chem, 2022, 40: 115–12210.1002/cjoc.202100576 ↗
17. Mekrattanachai P, Liu J, Li Z, et al. Extremely low loading of Ru species on hydroxyapatite as an effective heterogeneous catalyst for olefin epoxidation. Chem Commun, 2018, 54: 1433–143610.1039/C7CC08554K ↗
18. Muratsugu S, Weng Z, Tada M. Surface functionalization of supported Mn clusters to produce robust Mn catalysts for selective epoxidation. ACS Catal, 2013, 3: 2020–203010.1021/cs400053f ↗
19. Bagherzadeh M, Ghanbarpour A, Khavasi HR. Highly efficient aerobic epoxidation of cyclic olefins in mild conditions by a novel binuclear manganese(II) complex containing N-(4-nitrophenyl)picolinamide ligand. Catal Commun, 2015, 65: 72–7510.1016/j.catcom.2015.02.023 ↗
20. Blanckenberg A, Malgas-Enus R. Olefin epoxidation with metal-based nanocatalysts. Catal Rev, 2018, 61: 27–8310.1080/01614940.2018.1492503 ↗
21. Ishikawa S, Maegawa Y, Waki M, et al. Well-controlled radical-based epoxidation catalyzed by copper complex immobilized on bipyridineperiodic mesoporous organosilica. Appl Catal A-Gen, 2019, 575: 87–9210.1016/j.apcata.2019.02.007 ↗
22. Cao J, Zhou Z, Zhang M, et al. Tuning the electronic properties of supported Cu catalysts for efficient epoxidation of long-chain α-olefins. Fuel, 2023, 342: 12782910.1016/j.fuel.2023.127829 ↗
23. Al-Ani A, Freitas C, Zholobenko V. Nanostructured large-pore zeolite: the enhanced accessibility of active sites and its effect on the catalytic performance. Microporous Mesoporous Mater, 2020, 293: 10980510.1016/j.micromeso.2019.109805 ↗
24. Li J, Zhang D, Chi Y, et al. Catalytic application of polyoxovanadates in the selective oxidation of organic molecules. Polyoxometalates, 2022, 1: 914001210.26599/POM.2022.9140012 ↗
25. Hu Q, Li K, Chen X, et al. Polyoxometalate catalysts for the synthesis of N-heterocycles. Polyoxometalates, 2024, 3: 914004810.26599/POM.2023.9140048 ↗
26. Deng X, Yang D, Li W, et al. Chemistry of coordinatively unsaturated centers in zeolites. Trends Chem, 2023, 5: 892–90510.1016/j.trechm.2023.09.005 ↗
27. Li W, Li Z, Zhang H, et al. Efficient catalysts of surface hydrophobic Cu-BTC with coordinatively unsaturated Cu(I) sites for the direct oxidation of methane. Proc Natl Acad Sci USA, 2023, 120: e220661912010.1073/pnas.2206619120 ↗
28. Wang L, Wang H, Cheng R, et al. High-density coordinatively unsaturated Zn catalyst for efficient alkane dehydrogenation. J Am Chem Soc, 2023, 145: 20936–2094210.1021/jacs.3c06311 ↗
29. Li W, Sun L, Xie L, et al. Coordinatively unsaturated sites in zeolite matrix: construction and catalysis. Chin J Catal, 2019, 40: 1255–128110.1016/S1872-2067(19)63381-4 ↗
30. Li N, Zhu Y, Jiao F, et al. Steering the reaction pathway of syngas-to-light olefins with coordination unsaturated sites of ZnGaOx spinel. Nat Commun, 2022, 13: 274210.1038/s41467-022-30344-1 ↗
31. Liu Q, Sun YN, Yang W, et al. Polyoxometalate-based zinc–organic network as a dual-site acid catalyst for the conversion of polyethylene terephthalate plastic to terephthalic acid. Inorg Chem, 2025, 64: 8650–865810.1021/acs.inorgchem.5c00408 ↗
32. Li YY, Li XH, An ZX, et al. Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O2 atmosphere: coordination and structural regulation. Chin Chem Lett, 2025, 36: 10971610.1016/j.cclet.2024.109716 ↗
33. Bai X, Zhu M, Liu Y, et al. Effective oxygen activation on polyoxometalate-based hybrids for epoxidation of alkenes. Dalton Trans, 2024, 53: 6875–688010.1039/D4DT00530A ↗
34. Li S, Huang MY, Cheng W, et al. An unprecedented oxalate-functionalized Ta/W polyoxometalate enabling the self-assembly of a 2D composite for catalytic hydrogenation. Inorg Chem Front, 2024, 11: 7324–733210.1039/D4QI01551G ↗
35. Yang L, Zhang Z, Zhang CN, et al. A bifunctional POM-based Cuviologen complex with mixed octamolybdate clusters for rapid oxidation desulfurization and effective photogeneration of hydrogen. Rare Met, 2023, 43: 236–24610.1007/s12598-023-02435-5 ↗
36. Liu ZX, Du J, Li S, et al. Synergistic crystalline catalysts assembled with Wells–Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C–H bond oxidation. Inorg Chem Front, 2025, 12: 4078–409010.1039/D5QI00430F ↗
37. Ge R, Cai PW, Sun C, et al. Development of non-closed silver clusters by transition-metal-coordination-cluster substituted polyoxometalate templates. Chem Sci, 2024, 15: 12543–1254910.1039/D4SC01502A ↗
38. Bi HX, Guo MS, Du J, et al. Polyoxometalate chemistry of {M[P4Mo6]2}: from structure assembly to functional application. Coord Chem Rev, 2024, 518: 21609210.1016/j.ccr.2024.216092 ↗
39. Li S, Han Q, Ma YY, et al. Polyoxometalate-encapsulated copper-organic complexes for efficient C–H bond oxidation of alkylbenzenes. J Mol Structure, 2025, 1342: 14268610.1016/j.molstruc.2025.142686 ↗
40. Wang X, Zhang M-M, Hao X-L, et al. Polyoxometalate-induced new self-assemblies based on copper ions and bichelate-bridging ligands. Cryst Growth Des, 2013, 13: 3454–346210.1021/cg400353j ↗
41. Zheng Y, Shen Q, Li Z, et al. Two copper-containing polyoxometalate-based metal–organic complexes as heterogeneous catalysts for the C–H bond oxidation of benzylic compounds and olefin epoxidation. Inorg Chem, 2022, 61: 11156–1116410.1021/acs.inorgchem.2c01073 ↗
42. Huang J, Wang Y, Hao Z, et al. A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen peroxide. J Saudi Chem Soc, 2017, 21: 811–81610.1016/j.jscs.2015.12.005 ↗
43. Wang XL, Cui ZW, Lin HY, et al. The rational design of four multifunctional octamolybdate-based complexes for detecting different ions and removing organic dyes from aqueous solution. CrystEngComm, 2021, 23: 2113–212110.1039/D1CE00009H ↗
44. Gong M, Guo Y, Malko D, et al. Using molecular oxygen and Fe–N/C heterogeneous catalysts to achieve Mukaiyama epoxidations via in situ produced organic peroxy acids and acylperoxy radicals. Catal Sci Technol, 2022, 12: 2978–298910.1039/D2CY00356B ↗