Hierarchical electrospun nanofibers treated by solvent vapor annealing as air filtration mat for high-efficiency PM2.5 capture
Source abstract
Abstract
Recently, air pollution has become more serious and started to have a dramatic effect on the health of humans in many large cities. Generally, outdoor personal protection, such as commercial masks, cannot effectively prevent the inhalation of many pollutants. Particulate matter (PM) pollutants are a particularly serious threat to human health. Here we introduce a new efficient air filtration mat that can be used for outdoor protection. The new efficient air filter’s nanocomposite materials were successfully fabricated from poly( e -caprolactone)/polyethylene oxide (PCL/PEO) using an electrospinning technique and solvent vapor annealing (SVA). SVA treatment endows the wrinkled fiber surface and enhances the PM2.5 capture capacity of protective masks. This nanowrinkled air filtration mat can effectively filter PM2.5 with a removal efficiency of 80.01% under seriously polluted conditions (PM2.5 particle concentration above 225 mg m−3). Our field test in Qinhuangdao indicated that the air filtration mat had a high PM2.5 removal efficiency under thick haze. Compared to commercial masks, the fabricated SVA-treated PCL/PEO air filter mat demonstrated a simpler and ecofriendly preparation process with excellent degradation characteristics, showing wide potential applications with a high filtration efficiency.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Gas Sensing Nanomaterials and Sensors · Catalytic Processes in Materials Science
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (82)
Show source-provided references
1. Zhang R, Jing J, Tao J, et al. Chemical characterization and source apportionment of PM2.5 in Beijing: seasonal perspective. Atmos Chem Phys, 2013, 13: 7053–707410.5194/acp-13-7053-2013 ↗
2. Li K, Jiao T, Xing R, et al. Fabrication of tunable hierarchical MXene@AuNPs nanocomposites constructed by self-reduction reactions with enhanced catalytic performances. Sci China Mater, 2018, 61: 728–73610.1007/s40843-017-9196-8 ↗
3. Cheng C. Interfacial behaviors of PMMA-PEO block copolymers at the air/water interface. Sci China Ser B, 2005, 48: 567–57310.1360/042004-84 ↗
4. Zhao H, Jiao T, Zhang L, et al. Preparation and adsorption capacity evaluation of graphene oxide-chitosan composite hydrogels. Sci China Mater, 2015, 58: 811–81810.1007/s40843-015-0090-x ↗
5. Sun Z, Liao T, Kou L. Strategies for designing metal oxide nanostructures. Sci China Mater, 2017, 60: 1–2410.1007/s40843-016-5117-0 ↗
6. Liang Q, Li Z, Bai Y, et al. Reduced-sized monolayer carbon nitride nanosheets for highly improved photoresponse for cell imaging and photocatalysis. Sci China Mater, 2017, 60: 109–11810.1007/s40843-016-5131-9 ↗
7. Wang D, Wang R, Liu L, et al. Down-shifting luminescence of water soluble NaYF4:Eu3+@Ag core-shell nanocrystals for fluorescence turn-on detection of glucose. Sci China Mater, 2017, 60: 68–7410.1007/s40843-016-5145-1 ↗
8. Streets DG, Wu Y, Chin M. Two-decadal aerosol trends as a likely explanation of the global dimming/brightening transition. Geophys Res Lett, 2006, 33: 292–30610.1029/2006GL026471 ↗
9. Harrison RM, Yin J. Particulate matter in the atmosphere: which particle properties are important for its effects on health? Sci Total Environ, 2000, 249: 85–10110.1016/S0048-9697(99)00513-6 ↗
10. Chow JC, Watson JG, Mauderly JL, et al. Health effects of fine particulate air pollution: lines that connect. J Air Waste Manage Association, 2006, 56: 1368–138010.1080/10473289.2006.10464545 ↗
11. Betha R, Behera SN, Balasubramanian R. 2013 Southeast Asian smoke haze: Fractionation of particulate-bound elements and associated health risk. Environ Sci Technol, 2014, 48: 4327–433510.1021/es405533d ↗
12. Wu S, Deng F, Wei H, et al. Association of cardiopulmonary health effects with source-appointed ambient fine particulate in Beijing, China: A combined analysis from the healthy volunteer natural relocation (HVNR) study. Environ Sci Technol, 2014, 48: 3438–344810.1021/es404778w ↗
13. Brook RD, Rajagopalan S, Pope CA, et al. Particulate matter air pollution and cardiovascular disease: an update to the scientific statement from the American Heart Association. Circulation, 2010, 121: 2331–237810.1161/CIR.0b013e3181dbece1 ↗
14. Anenberg SC, Horowitz LW, Tong DQ, et al. An estimate of the global burden of anthropogenic ozone and fine particulate matter on premature human mortality using atmospheric modeling. Environ Health Perspect, 2010, 118: 1189–119510.1289/ehp.0901220 ↗
15. Timonen KL, Vanninen E, de Hartog J, et al. Effects of ultrafine and fine particulate and gaseous air pollution on cardiac autonomic control in subjects with coronary artery disease: The ULTRA study. J Expo Sci Environ Epidemiol, 2006, 16: 332–34110.1038/sj.jea.7500460 ↗
16. Reneker DH, Chun I. Nanometre diameter fibres of polymer, produced by electrospinning. Nanotechnology, 1996, 7: 216–22310.1088/0957-4484/7/3/009 ↗
17. Si Y, Wang X, Li Y, et al. Optimized colorimetric sensor strip for mercury(II) assay using hierarchical nanostructured conjugated polymers. J Mater Chem A, 2014, 2: 645–65210.1039/C3TA13867D ↗
18. Li D, Xia Y. Electrospinning of nanofibers: reinventing the wheel? Adv Mater, 2004, 16: 1151–117010.1002/adma.200400719 ↗
19. Lin J, Ding B, Yang J, et al. Subtle regulation of the micro- and nanostructures of electrospun polystyrene fibers and their application in oil absorption. Nanoscale, 2012, 4: 176–18210.1039/C1NR10895F ↗
20. Matulevicius J, Kliucininkas L, Prasauskas T, et al. The comparative study of aerosol filtration by electrospun polyamide, polyvinyl acetate, polyacrylonitrile and cellulose acetate nanofiber media. J Aerosol Sci, 2016, 92: 27–3710.1016/j.jaerosci.2015.10.006 ↗
21. Li J, Gao F, Liu LQ, et al. Needleless electro-spun nanofibers used for filtration of small particles. Express Polym Lett, 2013, 7: 683–68910.3144/expresspolymlett.2013.65 ↗
22. Kim HJ, Pant HR, Choi NJ, et al. Composite electrospun fly ash/polyurethane fibers for absorption of volatile organic compounds from air. Chem Eng J, 2013, 230: 244–25010.1016/j.cej.2013.06.090 ↗
23. Scholten E, Bromberg L, Rutledge GC, et al. Electrospun polyurethane fibers for absorption of volatile organic compounds from air. ACS Appl Mater Interfaces, 2011, 3: 3902–390910.1021/am200748y ↗
24. Sambaer W, Zatloukal M, Kimmer D. 3D air filtration modeling for nanofiber based filters in the ultrafine particle size range. Chem Eng Sci, 2012, 82: 299–31110.1016/j.ces.2012.07.031 ↗
25. Barhate RS, Loong CK, Ramakrishna S. Preparation and characterization of nanofibrous filtering media. J Membrane Sci, 2006, 283: 209–21810.1016/j.memsci.2006.06.030 ↗
26. Gibson P, Schreuder-Gibson H, Rivin D. Transport properties of porous membranes based on electrospun nanofibers. Colloids Surfs A-Physicochem Eng Aspects, 2001, 187–188: 469–48110.1016/S0927-7757(01)00616-1 ↗
27. Liu C, Hsu PC, Lee HW, et al. Transparent air filter for highefficiency PM2.5 capture. Nat Commun, 2015, 6: 620510.1038/ncomms7205 ↗
28. Wang Z, Zhao C, Pan Z. Porous bead-on-string poly(lactic acid) fibrous membranes for air filtration. J Colloid Interface Sci, 2015, 441: 121–12910.1016/j.jcis.2014.11.041 ↗
29. Huang ZM, Zhang YZ, Kotaki M, et al. A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Composites Sci Tech, 2003, 63: 2223–225310.1016/S0266-3538(03)00178-7 ↗
30. Ramakrishna S, Fujihara K, Teo WE, et al. Electrospun nanofibers: solving global issues. Mater Today, 2006, 9: 40–5010.1016/S1369-7021(06)71389-X ↗
31. Bhardwaj N, Kundu SC. Electrospinning: A fascinating fiber fabrication technique. Biotech Adv, 2010, 28: 325–34710.1016/j.biotechadv.2010.01.004 ↗
32. Kaur S, Sundarrajan S, Rana D, et al. Review: the characterization of electrospun nanofibrous liquid filtration membranes. J Mater Sci, 2014, 49: 6143–615910.1007/s10853-014-8308-y ↗
33. Uyar T, Havelund R, Nur Y, et al. Molecular filters based on cyclodextrin functionalized electrospun fibers. J Membrane Sci, 2009, 332: 129–13710.1016/j.memsci.2009.01.047 ↗
34. Desai K, Kit K, Li J, et al. Nanofibrous chitosan non-wovens for filtration applications. Polymer, 2009, 50: 3661–366910.1016/j.polymer.2009.05.058 ↗
35. Kadam VV, Wang L, Padhye R. Electrospun nanofibre materials to filter air pollutants–A review. J Industrial Textiles, 2018, 47: 2253–228010.1177/1528083716676812 ↗
36. Wang N, Zhu Z, Sheng J, et al. Superamphiphobic nanofibrous membranes for effective filtration of fine particles. J Colloid Interface Sci, 2014, 428: 41–4810.1016/j.jcis.2014.04.026 ↗
37. Wang N, Raza A, Si Y, et al. Tortuously structured polyvinyl chloride/polyurethane fibrous membranes for high-efficiency fine particulate filtration. J Colloid Interface Sci, 2013, 398: 240–24610.1016/j.jcis.2013.02.019 ↗
38. Kayaci F, Uyar T. Electrospun polyester/cyclodextrin nanofibers for entrapment of volatile organic compounds. Polym Eng Sci, 2014, 54: 2970–297810.1002/pen.23858 ↗
39. Vanangamudi A, Hamzah S, Singh G. Synthesis of hybrid hydrophobic composite air filtration membranes for antibacterial activity and chemical detoxification with high particulate filtration efficiency (PFE). Chem Eng J, 2015, 260: 801–80810.1016/j.cej.2014.08.062 ↗
40. Casper CL, Stephens JS, Tassi NG, et al. Controlling surface morphology of electrospun polystyrene fibers: effect of humidity and molecular weight in the electrospinning process. Macromolecules, 2004, 37: 573–57810.1021/ma0351975 ↗
41. Lee KH, Kim HY, Bang HJ, et al. The change of bead morphology formed on electrospun polystyrene fibers. Polymer, 2003, 44: 4029–403410.1016/S0032-3861(03)00345-8 ↗
42. Xu X, Wang H, Jiang L, et al. Comparison between cellulose nanocrystal and cellulose nanofibril reinforced poly(ethylene oxide) nanofibers and their novel shish-kebab-like crystalline structures. Macromolecules, 2014, 47: 3409–341610.1021/ma402627j ↗
43. Wang B, Li B, Xiong J, et al. Hierarchically ordered polymer nanofibers via electrospinning and controlled polymer crystallization. Macromolecules, 2008, 41: 9516–952110.1021/ma801971r ↗
44. Chen X, Wang W, Cheng S, et al. Mimicking bone nanostructure by combining block copolymer self-assembly and 1D crystal nucleation. ACS Nano, 2013, 7: 8251–825710.1021/nn403742f ↗
45. Liu J, Bauer AJP, Li B. Solvent vapor annealing: an efficient approach for inscribing secondary nanostructures onto electrospun fibers. Macromol Rapid Commun, 2014, 35: 1503–150810.1002/marc.201400274 ↗
46. Wang L, Pai CL, Boyce MC, et al. Wrinkled surface topographies of electrospun polymer fibers. Appl Phys Lett, 2009, 94: 15191610.1063/1.3118526 ↗
47. Bonino CA, Efimenko K, Jeong SI, et al. Three-dimensional electrospun alginate nanofiber mats via tailored charge repulsions. Small, 2012, 8: 1928–193610.1002/smll.201101791 ↗
48. Lin J, Cai Y, Wang X, et al. Fabrication of biomimetic superhydrophobic surfaces inspired by lotus leaf and silver ragwort leaf. Nanoscale, 2011, 3: 1258–126210.1039/c0nr00812e ↗
49. Huang XF, Yun H, Gong ZH, et al. Source apportionment and secondary organic aerosol estimation of PM2.5 in an urban atmosphere in China. Sci China Earth Sci, 2014, 57: 1352–136210.1007/s11430-013-4686-2 ↗
50. Lim CT, Tan EPS, Ng SY. Effects of crystalline morphology on the tensile properties of electrospun polymer nanofibers. Appl Phys Lett, 2008, 92: 14190810.1063/1.2857478 ↗
51. Yian Chew S, Hufnagel TC, Teck Lim C, et al. Mechanical properties of single electrospun drug-encapsulated nanofibres. Nanotechnology, 2006, 17: 3880–389110.1088/0957-4484/17/15/045 ↗
52. Wong SC, Baji A, Leng S. Effect of fiber diameter on tensile properties of electrospun poly(-caprolactone). Polymer, 2008, 49: 4713–472210.1016/j.polymer.2008.08.022 ↗
53. Pitt CG, Chasalow FI, Hibionada YM, et al. Aliphatic polyesters. I. The degradation of poly(ε-caprolactone) in vivo. J Appl Polym Sci, 1981, 26: 3779–3787
54. Zhang Y, Mu Y, Meng F, et al. The pollution levels of BTEX and carbonyls under haze and non-haze days in Beijing, China. Sci Total Environ, 2014, 490: 391–39610.1016/j.scitotenv.2014.05.025 ↗
55. Huang RJ, Zhang Y, Bozzetti C, et al. High secondary aerosol contribution to particulate pollution during haze events in China. Nature, 2014, 514: 218–22210.1038/nature13774 ↗
56. Hou C, Jiao T, Xing R, et al. Preparation of TiO2 nanoparticles modified electrospun nanocomposite membranes toward efficient dye degradation for wastewater treatment. J Taiwan Institute Chem Engineers, 2017, 78: 118–12610.1016/j.jtice.2017.04.033 ↗
57. Bauer AJP, Grim ZB, Li B. Hierarchical polymer blend fibers of high structural regularity prepared by facile solvent vapor annealing treatment. Macromol Mater Eng, 2018, 303: 170048910.1002/mame.201700489 ↗
58. Sepe A, Zhang J, Perlich J, et al. Toward an equilibrium structure in lamellar diblock copolymer thin films using solvent vapor annealing–An in-situ time-resolved GISAXS study. Eur Polymer J, 2016, 81: 607–62010.1016/j.eurpolymj.2015.12.013 ↗
59. Sinturel C, Vayer M, Morris M, et al. Solvent vapor annealing of block polymer thin films. Macromolecules, 2013, 46: 5399–541510.1021/ma400735a ↗
60. Chen L, Zhao K, Chi S, et al. Improving fiber alignment by increasing the planar conformation of isoindigo-based conjugated polymers. Mater Chem Front, 2017, 1: 286–29310.1039/C6QM00024J ↗
61. Bauer AJP, Liu J, Windsor LJ, et al. Current development of collagen- based biomaterials for tissue repair and regeneration. Soft Mater, 2014, 12: 359–37010.1080/1539445X.2014.925474 ↗
62. Gan Z, Jiang B, Zhang J. Poly(ε-caprolactone)/poly(ethylene oxide) diblock copolymer. I. Isothermal crystallization and melting behavior. J Appl Polym Sci, 1996, 59: 961–967
63. Zhou C, Chu R, Wu R, et al. Electrospun polyethylene oxide/cellulose nanocrystal composite nanofibrous mats with homogeneous and heterogeneous microstructures. Biomacromolecules, 2011, 12: 2617–262510.1021/bm200401p ↗
64. Hu C, Cui W. Hierarchical structure of electrospun composite fibers for long-term controlled drug release carriers. Adv Healthcare Mater, 2015, 1: 809–81410.1002/adhm.201200146 ↗
65. Lin J, Tian F, Shang Y, et al. Facile control of intra-fiber porosity and inter-fiber voids in electrospun fibers for selective adsorption. Nanoscale, 2012, 4: 5316–532010.1039/c2nr31515g ↗
66. Lai C, Guo Q, Wu XF, et al. Growth of carbon nanostructures on carbonized electrospun nanofibers with palladium nanoparticles. Nanotechnology, 2008, 19: 19530310.1088/0957-4484/19/19/195303 ↗
67. Lu P, Xia Y. Maneuvering the internal porosity and surface morphology of electrospun polystyrene yarns by controlling the solvent and relative humidity. Langmuir, 2013, 29: 7070–707810.1021/la400747y ↗
68. Guo R, Jiao T, Li R, et al. Sandwiched Fe3O4/carboxylate graphene oxide nanostructures constructed by layer-by-layer assembly for highly efficient and magnetically recyclable dye removal. ACS Sustain Chem Eng, 2018, 6: 1279–128810.1021/acssuschemeng.7b03635 ↗
69. Liu Y, Hou C, Jiao T, et al. Self-assembled AgNP-containing nanocomposites constructed by electrospinning as efficient dye photocatalyst materials for wastewater treatment. Nanomaterials, 2018, 8: 3510.3390/nano8010035 ↗
70. Zhou J, Liu Y, Jiao T, et al. Preparation and enhanced structural integrity of electrospun poly(ε-caprolactone)-based fibers by freezing amorphous chains through thiol-ene click reaction. Colloids Surfs A-Physicochem Eng Aspects, 2018, 538: 7–1310.1016/j.colsurfa.2017.10.077 ↗
71. Song J, Xing R, Jiao T, et al. Crystalline dipeptide nanobelts based on solid–solid phase transformation self-assembly and their polarization imaging of cells. ACS Appl Mater Interfaces, 2018, 10: 2368–237610.1021/acsami.7b17933 ↗
72. Huo S, Duan P, Jiao T, et al. Self-assembled luminescent quantum dots to generate full-color and white circularly polarized light. Angew Chem Int Ed, 2017, 56: 12174–1217810.1002/anie.201706308 ↗
73. Zhou J, Gao F, Jiao T, et al. Selective Cu(II) ion removal from wastewater via surface charged self-assembled polystyrene-Schiff base nanocomposites. Colloids Surfs A-Physicochem Eng Aspects, 2018, 545: 60–6710.1016/j.colsurfa.2018.02.048 ↗
74. Luo X, Ma K, Jiao T, et al. Graphene oxide-polymer composite langmuir films constructed by interfacial thiol-ene photopolymerization. Nanoscale Res Lett, 2017, 12: 9910.1186/s11671-017-1864-8 ↗
75. Sun S, Jiao T, Xing R, et al. Preparation of MoS2-based polydopamine- modified core-shell nanocomposites with elevated adsorption performances. RSC Adv, 2018, 8: 21644–2165010.1039/C8RA02964D ↗
76. Li D, Wang Y, Xia Y. Electrospinning of polymeric and ceramic nanofibers as uniaxially aligned arrays. Nano Lett, 2003, 3: 1167–117110.1021/nl0344256 ↗
77. Guibo Y, Qing Z, Yahong Z, et al. The electrospun polyamide 6 nanofiber membranes used as high efficiency filter materials: Filtration potential, thermal treatment, and their continuous production. J Appl Polym Sci, 2013, 128: 1061–106910.1002/app.38211 ↗
78. Wu H, Kong D, Ruan Z, et al. A transparent electrode based on a metal nanotrough network. Nat Nanotech, 2013, 8: 421–42510.1038/nnano.2013.84 ↗
79. Zhang S, Liu H, Zuo F, et al. A controlled design of ripple-like polyamide-6 nanofiber/nets membrane for high-efficiency air filter. Small, 2017, 13: 160315110.1002/smll.201603151 ↗
80. Vitchuli N, Shi Q, Nowak J, et al. Electrospun ultrathin nylon fibers for protective applications. J Appl Polym Sci, 2010, 116: 2181–218710.1002/app.31825 ↗
81. Wang N, Yang Y, Al-Deyab SS, et al. Ultra-light 3D nanofibre-nets binary structured nylon 6–polyacrylonitrile membranes for efficient filtration of fine particulate matter. J Mater Chem A, 2015, 3: 23946–2395410.1039/C5TA06543G ↗
82. Wang N, Si Y, Wang N, et al. Multilevel structured polyacrylonitrile/silica nanofibrous membranes for high-performance air filtration. Separation Purification Tech, 2014, 126: 44–5110.1016/j.seppur.2014.02.017 ↗