journal article·2018-05Open access

High-performance of sodium carboxylate-derived materials for electrochemical energy storage

Yong Xu, Jun Chen, Caijian Zhu, Pengwei Zhang, Guoxiang Jiang, Chunxiang Wang, Qian Zhang, Nengwen Ding, Yaxiang Huang, Shengwen Zhong

Science China Materials· Volume 61· Issue 5

Abstract

Four types of sustainable sodium carboxylate-derived materials are investigated as novel electrodes with high performance for lithium-ion batteries. Benefiting from the porous morphology provided by their intermolecular interactions, increasing capacity, excellent cycle stability and superior rate performance are observed for the sodium carboxylate- derived materials. The sodium oxalate (SO) electrodes displayed an increasing discharging capacity at a current density of 50 mA g−1 with with maximum values of 242.9 mA h g−1 for SO-631 and 373.9 mA h g−1 for SO-541 during the 100th cycle. In addition, the SO-541, SC-541 (sodium citrate), ST- 541 (sodium tartrate) and SP-541 (sodium pyromellitate) electrode materials displayed high initial capacities of 619.6, 392.3, 403.7 and 278.1 mA h g−1, respectively, with capacity retentions of 179%, 148%, 173% and 108%, respectively, after 200 cycles at 50 mA g−1 with. Even at a high current density of 2,000 mA g−1 with, the capacities remain 157.6, 131.3, 146.6 and 137.0 mA h g−1, respectively. With these superior electrochemical properties, the sodium carboxylate-derived materials could be considered as promising organic electrode materials for large-scale sustainable lithium-ion batteries.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

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