journal article·2023-02

A novel high-entropy alloy with an exceptional combination of soft magnetic properties and corrosion resistance

Jiacheng Duan, Mingliang Wang, Rui Huang, Junwei Miao, Yiping Lu, Tongmin Wang, Tingju Li

Science China Materials· Volume 66· Issue 2
Publisher page

Abstract

耐腐蚀性能差限制了大多数软磁材料在腐蚀环境中的应用, 尤 其是海洋环境. 因此, 提高软磁材料的耐腐蚀性能是其在海洋环境工业 应用的关键. 然而, 磁性能和耐腐蚀性能之间存在矛盾关系, 耐腐蚀性 能的主要贡献元素Cr的反铁磁性会严重损害合金的磁性能. 本研究开 发了一种兼具优异力学性能和耐腐蚀性能的软磁高熵合金(Fe2.25Co1.25-Cr)94Al6, 其综合性能优于绝大多数已报道的传统和高熵合金软磁材料. 该合金的饱和磁化强度高达141.88 emu g−1, 矫顽力仅有2.9 Oe; 其在模 拟海水中的耐腐蚀性能优于大多数已报道的软磁高熵合金和传统304 不锈钢; 同时, 该合金还具有优异的力学性能, 屈服强度高达1.1 Gpa, 压 缩断裂延伸率超过33%, 硬度高于469 HV. 这种新型的耐蚀软磁高熵合 金有望满足海洋环境中的使役要求, 解决软磁材料在海洋腐蚀环境下 的使役难题.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. Gutfleisch O, Willard MA, Brück E, et al. Magnetic materials and devices for the 21st century: Stronger, lighter, and more energy efficient. Adv Mater, 2011, 23: 821–84210.1002/adma.201002180 ↗
2. Wei L, Liu Y, Li Q, et al. Effect of roughness on general corrosion and pitting of (FeCoCrNi)0.89(WC)0.11 high-entropy alloy composite in 3.5 wt.% NaCl solution. Corrosion Sci, 2019, 146: 44–5710.1016/j.corsci.2018.10.025 ↗
3. Sundar RS, Deevi SC. Soft magnetic FeCo alloys: Alloy development, processing, and properties. Int Mater Rev, 2013, 50: 157–19210.1179/174328005X14339 ↗
4. Yeh JW, Chen SK, Lin SJ, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv Eng Mater, 2014, 6: 299–30310.1002/adem.200300567 ↗
5. Cantor B, Chang ITH, Knight P, et al. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng-A, 2004, 375–377: 213–21810.1016/j.msea.2003.10.257 ↗
6. Wu Z, Bei H, Pharr GM, et al. Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures. Acta Mater, 2014, 81: 428–44110.1016/j.actamat.2014.08.026 ↗
7. Fan L, Yang T, Zhao Y, et al. Ultrahigh strength and ductility in newly developed materials with coherent nanolamellar architectures. Nat Commun, 2020, 11: 624010.1038/s41467-020-20109-z ↗
8. Lu Y, Dong Y, Jiang H, et al. Promising properties and future trend of eutectic high entropy alloys. Scripta Mater, 2020, 187: 202–20910.1016/j.scriptamat.2020.06.022 ↗
9. Wang M, Lu Y, Wang T, et al. A novel bulk eutectic high-entropy alloy with outstanding as-cast specific yield strengths at elevated temperatures. Scripta Mater, 2021, 204: 11413210.1016/j.scriptamat.2021.114132 ↗
10. Yao MJ, Pradeep KG, Tasan CC, et al. A novel, single phase, non-equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility. Scripta Mater, 2014, 72–73: 5–810.1016/j.scriptamat.2013.09.030 ↗
11. Wang M, Lu Y, Zhang G, et al. A novel high-entropy alloy composite coating with core-shell structures prepared by plasma cladding. Vacuum, 2021, 184: 10990510.1016/j.vacuum.2020.109905 ↗
12. Zhang Y, Zuo TT, Cheng YQ, et al. High-entropy alloys with high saturation magnetization, electrical resistivity and malleability. Sci Rep, 2013, 3: 145510.1038/srep01455 ↗
13. Wang M, Zhang G, Cui H, et al. Effect of plasma remelting on microstructure and properties of a CoCrCuNiAl0.5 high-entropy alloy prepared by spark plasma sintering. J Mater Sci, 2021, 56: 5878–589810.1007/s10853-020-05570-x ↗
14. Ma Y, Wang Q, Zhou X, et al. A novel soft-magnetic B2-based multiprincipal-element alloy with a uniform distribution of coherent body-centered-cubic nanoprecipitates. Adv Mater, 2021, 33: 200672310.1002/adma.202006723 ↗
15. Han L, Rao Z, Souza Filho IR, et al. Ultrastrong and ductile soft magnetic high-entropy alloys via coherent ordered nanoprecipitates. Adv Mater, 2021, 33: 210213910.1002/adma.202102139 ↗
16. Li P, Wang A, Liu CT. Composition dependence of structure, physical and mechanical properties of FeCoNi(MnAl)x high entropy alloys. Intermetallics, 2017, 87: 21–2610.1016/j.intermet.2017.04.007 ↗
17. Li Z, Gu Y, Pan M, et al. Tailoring AC magnetic properties of FeCoNi-(MnSi)x (0 ≤ x ≤ 0.4) high-entropy alloys by the addition of Mn and Si elements. J Alloys Compd, 2019, 792: 215–22110.1016/j.jallcom.2019.03.411 ↗
18. Fu Z, MacDonald BE, Monson TC, et al. Influence of heat treatment on microstructure, mechanical behavior, and soft magnetic properties in an fcc-based Fe29Co28Ni29Cu7Ti7 high-entropy alloy. J Mater Res, 2018, 33: 2214–222210.1557/jmr.2018.161 ↗
19. Zuo T, Gao MC, Ouyang L, et al. Tailoring magnetic behavior of CoFeMnNiX (X = Al, Cr, Ga, and Sn) high entropy alloys by metal doping. Acta Mater, 2017, 130: 10–1810.1016/j.actamat.2017.03.013 ↗
20. Zhao C, Li J, Liu Y, et al. Tailoring mechanical and magnetic properties of AlCoCrFeNi high-entropy alloy via phase transformation. J Mater Sci Tech, 2021, 73: 83–9010.1016/j.jmst.2020.08.063 ↗
21. Shang C, Axinte E, Ge W, et al. High-entropy alloy coatings with excellent mechanical, corrosion resistance and magnetic properties prepared by mechanical alloying and hot pressing sintering. Surfs Interfaces, 2017, 9: 36–4310.1016/j.surfin.2017.06.012 ↗
22. Borkar T, Gwalani B, Choudhuri D, et al. A combinatorial assessment of AlxCrCuFeNi2 (0 < x < 1.5) complex concentrated alloys: Microstructure, microhardness, and magnetic properties. Acta Mater, 2016, 116: 63–7610.1016/j.actamat.2016.06.025 ↗
23. Huang S, Li W, Li X, et al. Mechanism of magnetic transition in FeCrCoNi-based high entropy alloys. Mater Des, 2016, 103: 71–7410.1016/j.matdes.2016.04.053 ↗
24. Jung C, Kang K, Marshal A, et al. Effects of phase composition and elemental partitioning on soft magnetic properties of AlFeCoCrMn high entropy alloys. Acta Mater, 2019, 171: 31–3910.1016/j.actamat.2019.04.007 ↗
25. Liu C, Peng W, Jiang CS, et al. Composition and phase structure dependence of mechanical and magnetic properties for AlCoCuFeNi high entropy alloys. J Mater Sci Tech, 2019, 35: 1175–118310.1016/j.jmst.2018.12.014 ↗
26. Zhao C, Li J, Liu Y, et al. Optimizing mechanical and magnetic properties of AlCoCrFeNi high-entropy alloy via FCC to BCC phase transformation. J Mater Sci Tech, 2021, 86: 117–12610.1016/j.jmst.2020.12.080 ↗
27. Zuo TT, Li RB, Ren XJ, et al. Effects of Al and Si addition on the structure and properties of CoFeNi equal atomic ratio alloy. J Magn Magn Mater, 2014, 371: 60–6810.1016/j.jmmm.2014.07.023 ↗
28. Feng J, Gao S, Han K, et al. Effects of minor B addition on microstructure and properties of Al19Co20Fe20Ni41 eutectic high-entropy alloy. Trans Nonferrous Met Soc China, 2021, 31: 1049–105810.1016/S1003-6326(21)65560-7 ↗
29. Zhu M, Zhang C, Li K, et al. A novel CoFe2NiMn0.3AlCux high-entropy alloy with excellent magnetic properties and good mechanical properties. Acta Metall Sin (Engl Lett), 2014, 34: 1557–156410.1007/s40195-021-01256-8 ↗
30. Kang T, Wu S, Wang M, et al. Novel Fe2CoNi(AlSi)x high-entropy alloys with attractive soft magnetic and mechanical properties. Appl Phys A, 2021, 127: 82910.1007/s00339-021-04988-7 ↗
31. Dong Y, Zhou K, Lu Y, et al. Effect of vanadium addition on the microstructure and properties of AlCoCrFeNi high entropy alloy. Mater Des, 2014, 57: 67–7210.1016/j.matdes.2013.12.048 ↗
32. Li Z, Bai G, Liu X, et al. Tuning phase constitution and magnetic properties by composition in FeCoNiAlMn high-entropy alloys. J Alloys Compd, 2020, 845: 15620410.1016/j.jallcom.2020.156204 ↗
33. Dasari S, Chaudhary V, Gwalani B, et al. Highly tunable magnetic and mechanical properties in an Al0.3CoFeNi complex concentrated alloy. Materialia, 2020, 12: 10075510.1016/j.mtla.2020.100755 ↗
34. Zhou KX, Sun BR, Liu GY, et al. FeCoNiAlSi high entropy alloys with exceptional fundamental and application-oriented magnetism. Inter-metallics, 2020, 122: 106801
35. Yao HW, Qiao JW, Gao MC, et al. NbTaV-(Ti,W) refractory high-entropy alloys: Experiments and modeling. Mater Sci Eng-A, 2016, 674: 203–21110.1016/j.msea.2016.07.102 ↗
36. Wang M, Cui H, Zhao Y, et al. A simple strategy for fabrication of an FCC-based complex concentrated alloy coating with hierarchical nanoprecipitates and enhanced mechanical properties. Mater Des, 2019, 180: 10789310.1016/j.matdes.2019.107893 ↗
37. Wang W, Li H, Wei P, et al. A corrosion-resistant soft-magnetic high entropy alloy. Mater Lett, 2021, 304: 13057110.1016/j.matlet.2021.130571 ↗
38. Zhang K, Fu Z. Effects of annealing treatment on properties of CoCrFeNiTiAlx multi-component alloys. Intermetallics, 2012, 28: 34–3910.1016/j.intermet.2012.03.059 ↗
39. Mishra SS, Bajpai A, Biswas K. TiVCrNiZrFex high entropy alloy: Phase evolution, magnetic and mechanical properties. J Alloys Compd, 2021, 871: 15957210.1016/j.jallcom.2021.159572 ↗
40. Kumari P, Gupta AK, Mishra RK, et al. A comprehensive review: Recent progress on magnetic high entropy alloys and oxides. J Magn Magn Mater, 2022, 554: 16914210.1016/j.jmmm.2022.169142 ↗
41. Li P, Wang A, Liu CT. A ductile high entropy alloy with attractive magnetic properties. J Alloys Compd, 2017, 694: 55–6010.1016/j.jallcom.2016.09.186 ↗
42. Koželj P, Vrtnik S, Jelen A, et al. Discovery of a FeCoNiPdCu high-entropy alloy with excellent magnetic softness. Adv Eng Mater, 2019, 21: 180105510.1002/adem.201801055 ↗
43. Zhao C, Li J, He Y, et al. Effect of strong magnetic field on the microstructure and mechanical-magnetic properties of AlCoCrFeNi high-entropy alloy. J Alloys Compd, 2021, 820: 15340710.1016/j.jallcom.2019.153407 ↗
44. Sun LL. Features and applications of semi-hard magnetic materials. Elect Eng Mater, 1975, 2: 78–83
45. Sahu P, Samal S, Kumar V. Microstructural, magnetic, and geometrical thermodynamic investigation of FeCoNi(MnSi)x (0.0, 0.1, 0.25, 0.5, 0.75, 1.0) high entropy alloys. Materialia, 2021, 18: 10113310.1016/j.mtla.2021.101133 ↗
46. Mishra RK, Kumari P, Gupta AK, et al. Design and development of Co35Cr5Fe20−xNi20+xTi20 high entropy alloy with excellent magnetic softness. J Alloys Compd, 2021, 889: 16177310.1016/j.jallcom.2021.161773 ↗
47. Shi Y, Yang B, Xie X, et al. Corrosion of AlxCoCrFeNi high-entropy alloys: Al-content and potential scan-rate dependent pitting behavior. Corrosion Sci, 2017, 119: 33–4510.1016/j.corsci.2017.02.019 ↗
48. Zhou Z, Wang L, Zhao X, et al. Effects of W addition on the corrosion behaviors of FeCoNiCrMn high entropy alloy composites in the 3.5 wt. % NaCl solution. Surfs Interfaces, 2021, 23: 10095610.1016/j.surfin.2021.100956 ↗
49. Shuang S, Ding ZY, Chung D, et al. Corrosion resistant nanostructured eutectic high entropy alloy. Corrosion Sci, 2020, 164: 10831510.1016/j.corsci.2019.108315 ↗
50. Biesinger MC, Payne BP, Grosvenor AP, et al. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci, 2011, 257: 2717–273010.1016/j.apsusc.2010.10.051 ↗
51. Babilas R, Łoński W, Boryło P, et al. The influence of cooling rate, chromium and silicon addition on the structure and properties of Al-CoCrFeNiSi high entropy alloys. J Magn Magn Mater, 2020, 502: 16649210.1016/j.jmmm.2020.166492 ↗
52. Jiang S, Lin Z, Xu H, et al. Studies on the microstructure and properties of AlxCoCrFeNiTi1−x high entropy alloys. J Alloys Compd, 2018, 741: 826–83310.1016/j.jallcom.2018.01.247 ↗
53. Xiao DH, Zhou PF, Wu WQ, et al. Microstructure, mechanical and corrosion behaviors of AlCoCuFeNi-(Cr,Ti) high entropy alloys. Mater Des, 2017, 116: 438–44710.1016/j.matdes.2016.12.036 ↗
54. Wang W, Li B, Zhai S, et al. Alloying behavior and properties of FeSiBAlNiCox high entropy alloys fabricated by mechanical alloying and spark plasma sintering. Met Mater Int, 2018, 24: 1112–111910.1007/s12540-018-0047-1 ↗
55. Mishra RK, Sahay PP, Shahi RR. Alloying, magnetic and corrosion behavior of AlCrFeMnNiTi high entropy alloy. J Mater Sci, 2019, 54: 4433–444310.1007/s10853-018-3153-z ↗
56. Chen C, Zhang H, Fan Y, et al. Improvement of corrosion resistance and magnetic properties of FeCoNiAl0.2Si0.2 high entropy alloy via rapid-solidification. Intermetallics, 2020, 122: 10677810.1016/j.intermet.2020.106778 ↗
57. Raphel A, Kumaran S, Kumar KV, et al. Oxidation and corrosion resistance of AlCoCrFeTi high entropy alloy. Mater Today-Proc, 2017, 4: 195–20210.1016/j.matpr.2017.01.013 ↗
58. Wu CL, Zhang S, Zhang CH, et al. Phase evolution and cavitation erosion-corrosion behavior of FeCoCrAlNiTix high entropy alloy coatings on 304 stainless steel by laser surface alloying. J Alloys Compd, 2017, 698: 761–77010.1016/j.jallcom.2016.12.196 ↗
59. Liu J, Liu H, Chen P, et al. Microstructural characterization and corrosion behaviour of AlCoCrFeNiTix high-entropy alloy coatings fabricated by laser cladding. Surf Coatings Tech, 2019, 361: 63–7410.1016/j.surfcoat.2019.01.044 ↗
60. Qiu Y, Thomas S, Gibson MA, et al. Microstructure and corrosion properties of the low-density single-phase compositionally complex alloy AlTiVCr. Corrosion Sci, 2018, 133: 386–39610.1016/j.corsci.2018.01.035 ↗