Ultra-stable 2D cuprofullerene imidazolate polymer as a high-performance visible-light photodetector
Source abstract
Abstract
本工作通过溶剂热法制备了一种超稳定二维层状铜(I)富勒 烯配位聚合物材料. Cu-(η2-C60)配位作用和层间凹凸π⋅⋅⋅π相互作用 支撑C60分子排列形成倾斜六方面堆积((i-hfp))特点, 显著地改善了 材料的化学稳定性. 该材料表现出高性能可见光探测功能. 密度泛 函计算表明, 与六方紧密堆积和立方堆积的C60纳米材料类似, 其优 异的光探测功能主要来源于C60分子本身, 但是铜(I)的配位显著增 强了其对可见光的吸收效率, 改善了材料的可见光探测功能. 该工 作对于拓展富勒烯光电功能材料的种类具有重要意义.
The source flagged this abstract for review. Check formulas and completeness against the original publication.
Source: openaire · Quality: needs review · Source record ↗
Source flags: short_text
Source flags: short_text
Research context
OpenAlex topics: Organic Electronics and Photovoltaics · Fullerene Chemistry and Applications · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Kroto HW, Heath JR, O’Brien SC, et al. C60: Buckminsterfullerene. Nature, 1985, 318: 162–16310.1038/318162a0 ↗
2. Gong X, Tong M, Xia Y, et al. High-detectivity polymer photo-detectors with spectral response from 300 nm to 1450 nm. Science, 2009, 325: 1665–166710.1126/science.1176706 ↗
3. Saran R, Curry RJ. Solution processable 1D fullerene C60 crystals for visible spectrum photodetectors. Small, 2018, 14: 170362410.1002/smll.201703624 ↗
4. Zheng S, Xiong X, Zheng Z, et al. Solution-grown large-area C60 single-crystal arrays as organic photodetectors. Carbon, 2018, 126: 299–30410.1016/j.carbon.2017.10.012 ↗
5. Liu K, Gao S, Zheng Z, et al. Spatially confined growth of fullerene to super-long crystalline fibers in supramolecular gels for highperformance photodetector. Adv Mater, 2019, 31: 180825410.1002/adma.201808254 ↗
6. Yang D, Zhou X, Ma D. Fast response organic photodetectors with high detectivity based on rubrene and C60. Org Electron, 2013, 14: 3019–302310.1016/j.orgel.2013.08.027 ↗
7. Kang H, Lee W, Oh J, et al. From fullerene-polymer to all-polymer solar cells: the importance of molecular packing, orientation, and morphology control. Acc Chem Res, 2016, 49: 2424–243410.1021/acs.accounts.6b00347 ↗
8. Wu KY, Wu TY, Chang ST, et al. A facile PDMS-assisted crystallization for the crystal-engineering of C60 single-crystal organic field-effect transistors. Adv Mater, 2015, 27: 4371–437610.1002/adma.201501140 ↗
9. Wang J, Xu L, Zhang B, et al. n-Type doping induced by electron transport layer in organic photovoltaic devices. Adv Electron Mater, 2017, 3: 160045810.1002/aelm.201600458 ↗
10. Balch AL, Winkler K. Two-component polymeric materials of fullerenes and the transition metal complexes: a bridge between metal-organic frameworks and conducting polymers. Chem Rev, 2016, 116: 3812–388210.1021/acs.chemrev.5b00553 ↗
11. Liu X, Kozlowska M, Okkali T, et al. Photoconductivity in metal-organic framework (MOF) thin films. Angew Chem Int Ed, 2019, 58: 9590–959510.1002/anie.201904475 ↗
12. Goswami S, Ray D, Otake KI, et al. A porous, electrically conductive hexa-zirconium(iv) metal-organic framework. Chem Sci, 2018, 9: 4477–448210.1039/C8SC00961A ↗
13. Yang F, Cheng S, Zhang X, et al. 2D organic materials for optoelectronic applications. Adv Mater, 2018, 30: 170241510.1002/adma.201702415 ↗
14. Huang Q, Zhuang G, Jia H, et al. Photoconductive curved-nano-graphene/fullerene supramolecular heterojunctions. Angew Chem Int Ed, 2019, 58: 6244–624910.1002/anie.201900084 ↗
15. Liu YM, Xia D, Li BW, et al. Functional sulfur-doped buckybowls and their concave-convex supramolecular assembly with fullerenes. Angew Chem Int Ed, 2016, 55: 13047–1305110.1002/anie.201606383 ↗
16. Li B, Zhen J, Wan Y, et al. Anchoring fullerene onto perovskite film via grafting pyridine toward enhanced electron transport in high-efficiency solar cells. ACS Appl Mater Interfaces, 2018, 10: 32471–3248210.1021/acsami.8b11459 ↗
17. Hwang IW, Xu QH, Soci C, et al. Ultrafast spectroscopic study of photoinduced electron transfer in an oligo(thienylenevinylene): fullerene composite. Adv Funct Mater, 2007, 17: 563–56810.1002/adfm.200600267 ↗
18. Sariciftci NS, Smilowitz L, Heeger AJ, et al. Photoinduced electron transfer from a conducting polymer to buckminsterfullerene. Science, 1992, 258: 1474–147610.1126/science.258.5087.1474 ↗
19. Wang C, Wang H, Liu C, et al. Molecular assembly-induced charge transfer between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene. Inorg Chem Front, 2019, 6: 654–658
20. Jiang X, Yuan M, Liu H, et al. Optoelectronic properties of one-dimensional fullerene nanorods. Mater Lett, 2016, 176: 52–5510.1016/j.matlet.2016.03.087 ↗
21. Saran R, Stolojan V, Curry RJ. Ultrahigh performance C60 nanorod large area flexible photoconductor devices via ultralow organic and inorganic photodoping. Sci Rep, 2014, 4: 504110.1038/srep05041 ↗
22. Geng J, Zhou W, Skelton P, et al. Crystal structure and growth mechanism of unusually long fullerene (C60) nanowires. J Am Chem Soc, 2008, 130: 2527–253410.1021/ja076392s ↗
23. Zhan SZ, Zhang GH, Li JH, et al. Exohedral cuprofullerene: sequentially expanding metal olefin up to a C60@Cu24 rhombicuboctahedron. J Am Chem Soc, 2020, 142: 5943–594710.1021/jacs.0c00090 ↗
24. Chu D, Liu Y, Li Y, et al. Journey to the holy grail of a coordination saturated buckyball. Inorg Chem Front, 2020, 7: 2556–255910.1039/D0QI00511H ↗
25. Lebedeva MA, Chamberlain TW, Khlobystov AN. Harnessing the synergistic and complementary properties of fullerene and transition-metal compounds for nanomaterial applications. Chem Rev, 2015, 115: 11301–1135110.1021/acs.chemrev.5b00005 ↗
26. Konarev DV, Khasanov SS, Nakano Y, et al. Linear coordination fullerene C60 polymer [{Ni(Me3P)2}(μ-η2, η2-C60)]∞, bridged by zerovalent nickel atoms. Inorg Chem, 2014, 53: 11960–1196510.1021/ic501551y ↗
27. Aghabali A, Jun S, Olmstead MM, et al. Silver(I)-mediated modification, dimerization, and polymerization of an open-cage full-erene. J Am Chem Soc, 2016, 138: 16459–1646510.1021/jacs.6b10394 ↗
28. Peng P, Li FF, Bowles FL, et al. High yield synthesis of a new fullerene linker and its use in the formation of a linear coordination polymer by silver complexation. Chem Commun, 2013, 49: 3209–321110.1039/c3cc40697k ↗
29. Chancellor CJ, Olmstead MM, Balch AL. Formation of crystalline polymers from the reaction of amine-functionalized C60 with silver salts. Inorg Chem, 2009, 48: 1339–134510.1021/ic8012427 ↗
30. Lee K, Song H, Park JT. [60]Fullerene-metal cluster complexes: Novel bonding modes and electronic communication. Acc Chem Res, 2003, 36: 78–8610.1021/ar020149a ↗
31. Gradzka E, Wysocka-Żołopa M, Winkler K. In situ conductance studies of two-component C60-Pd polymer. J Phys Chem C, 2014, 118: 14061–1407210.1021/jp5008544 ↗
32. Nagashima H, Nakaoka A, Saito Y, et al. C60Pdn: the first organometallic polymer of buckminsterfullerene. J Chem Soc Chem Commun, 1992, 37710.1039/c39920000377 ↗
33. Tanaka M, Yamanaka S. Vapor-phase growth and structural characterization of single crystals of magnesium doped two-dimensional fullerene polymer Mg2C60. Cryst Growth Des, 2018, 18: 3877–388210.1021/acs.cgd.8b00186 ↗
34. Zhan SZ, Li JH, Zhang GH, et al. Coordination disk-type nano-Saturn complexes. Chem Commun, 2020, 56: 3325–332810.1039/D0CC00532K ↗
35. Huang XC, Zhang JP, Chen XM. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates. J Am Chem Soc, 2004, 126: 13218–1321910.1021/ja045249l ↗
36. Santiso-Quinones G, Reisinger A, Slattery J, et al. Homoleptic Cu-phosphorus and Cu-ethene complexes. Chem Commun, 2007, 53: 504610.1039/b710899k ↗
37. Jayaratna NB, Cowan MG, Parasar D, et al. Low heat of adsorption of ethylene achieved by major solid-state structural rearrangement of a discrete copper(I) complex. Angew Chem Int Ed, 2018, 57: 16442–1644610.1002/anie.201810460 ↗
38. Seo DK, Hoffmann R. Direct and indirect band gap types in one-dimensional conjugated or stacked organic materials. Theor Chem Acc, 1999, 102: 23–3210.1007/s002140050469 ↗
39. Liu J, Zhou W, Liu J, et al. Photoinduced charge-carrier generation in epitaxial mof thin films: High efficiency as a result of an indirect electronic band gap? Angew Chem Int Ed, 2015, 54: 7441–744510.1002/anie.201501862 ↗
40. Alers GB, Golding B, Kortan AR, et al. Existence of an orientational electric dipolar response in C60 single crystals. Science, 1991, 257: 511–51410.1126/science.257.5069.511 ↗
41. Wen C, Li J, Kitazawa K, et al. Electrical conductivity of a pure C60 single crystal. Appl Phys Lett, 1992, 61: 2162–216310.1063/1.108281 ↗
42. Mort J, Ziolo R, Machonkin M, et al. Electrical conductivity studies of undoped solid films of C60/70. Chem Phys Lett, 1991, 186: 284–28610.1016/S0009-2614(91)85142-J ↗