Photochromic ferroelasticity observed in hybrid lead halide through effective structural regulation
Source abstract
Abstract
多功能材料是当前交叉研究的热点, 有机-无机杂化材料因其结构多样性为构筑多功能材料提供了极大的可能性. 多功能铁弹材料在机械开关、 形状记忆以及能量转换等领域具有广泛的应用前景, 特别是具备光学电学协同特征的铁弹材料是新器件应用研究的亮点. 尽管目前报道了大量具有光致发光、 热致变色等优异性质的铁弹材料, 但尚未破解将铁弹性和光致变色协同这一难题. 本文通过功能阳离子与卤化铅骨架构筑了具有光致变色效应的铁弹体, (3-hydroxypyrrolidinium)4Pb3Br10, 并通过分子间插入氢键的策略有效提高了材料的相变温度. 该材料还可同时实现两步介电响应, 具有可切换铁弹畴和光致变色的多通道物理特性, 这对显示传感器件的探索研究非常有帮助. 总之, 本研究为多功能物理响应材料的合成提供了多学科交叉研究策略和思路.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Polyoxometalates: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. Hermes IM, Best A, Winkelmann L, et al. Anisotropic carrier diffusion in single MAPbI3 grains correlates to their twin domains. Energy Environ Sci, 2020, 13: 4168–417710.1039/D0EE01016B ↗
2. Su CY, Yao YF, Zhang ZX, et al. The construction of a two-dimensional organic-inorganic hybrid double perovskite ferroelastic with a high Tc and narrow band gap. Chem Sci, 2022, 13: 4794–480010.1039/D1SC07045B ↗
3. Li J, Zhu Y, Huang PZ, et al. Ferroelasticity in organic-inorganic hybrid perovskites. Chem Eur J, 2022, 28: e20220100510.1002/chem.202201005 ↗
4. Wu Z, Li S, Yousry YM, et al. Intercalation-driven ferroelectric-to-ferroelastic conversion in a layered hybrid perovskite crystal. Nat Commun, 2022, 13: 310410.1038/s41467-022-30822-6 ↗
5. Xu X, Huang FT, Du K, et al. Multifunctionality of Li2SrNb2O7: Memristivity, tunable rectification, ferroelasticity, and ferroelectricity. Adv Mater, 2022, 34: 220602210.1002/adma.202206022 ↗
6. Han S, Ma Y, Hua L, et al. Soft multiaxial molecular ferroelectric thin films with self-powered broadband photodetection. J Am Chem Soc, 2022, 144: 20315–2032210.1021/jacs.2c07892 ↗
7. Wang Y, Yang D, Ma D, et al. Organic-inorganic hybrid Sn-based perovskite photodetectors with high external quantum efficiencies and wide spectral responses from 300 to 1000 nm. Sci China Mater, 2019, 62: 790–79610.1007/s40843-018-9377-3 ↗
8. Peng H, Qi JC, Song XJ, et al. An unprecedented azobenzene-based organic single-component ferroelectric. Chem Sci, 2022, 13: 4936–494310.1039/D2SC00689H ↗
9. Zhang ZX, Su CY, Li J, et al. Ferroelastic hybrid bismuth bromides with dual dielectric switches. Chem Mater, 2021, 33: 5790–579910.1021/acs.chemmater.1c01699 ↗
10. Mir SH, Takasaki Y, Engel ER, et al. Ferroelasticity in an organic crystal: A macroscopic and molecular level study. Angew Chem Int Ed, 2017, 56: 15882–1588510.1002/anie.201707749 ↗
11. Bari M, Bokov AA, Ye ZG. Ferroelasticity, domain structures and phase symmetries in organic-inorganic hybrid perovskite methylammonium lead chloride. J Mater Chem C, 2020, 8: 9625–963110.1039/D0TC02124E ↗
12. Zhou G, Guo S, Zhao J, et al. Unraveling the mechanochemical synthesis and luminescence in MnII-based two-dimensional hybrid perovskite (C4H9NH3)2PbCl4. Sci China Mater, 2019, 62: 1013–102210.1007/s40843-018-9404-4 ↗
13. Miao LP, Ding N, Wang N, et al. Direct observation of geometric and sliding ferroelectricity in an amphidynamic crystal. Nat Mater, 2022, 21: 1158–116410.1038/s41563-022-01322-1 ↗
14. Zhang T, Xu K, Li J, et al. Ferroelectric hybrid organic-inorganic perovskites and their structural and functional diversity. Natl Sci Rev, 2023, 10, DOI: https://doi.org/10.1093/nsr/nwac24010.1093/nsr/nwac240 ↗
15. Sun H, Park SK, Diao Y, et al. Molecular mechanisms of superelasticity and ferroelasticity in organic semiconductor crystals. Chem Mater, 2021, 33: 1883–189210.1021/acs.chemmater.1c00080 ↗
16. Hermes IM, Bretschneider SA, Bergmann VW, et al. Ferroelastic fingerprints in methylammonium lead iodide perovskite. J Phys Chem C, 2016, 120: 5724–573110.1021/acs.jpcc.5b11469 ↗
17. Ai Y, Sun R, Zeng YL, et al. Coexistence of magnetic and electric orderings in a divalent Cr2+-based multiaxial molecular ferroelectric. Chem Sci, 2021, 12: 9742–974710.1039/D1SC01871J ↗
18. Zhang X, Zhao D, Liu X, et al. Ferroelastic domains enhanced the photoelectric response in a CsPbBr3 single-crystal film detector. J Phys Chem Lett, 2021, 12: 8685–869110.1021/acs.jpclett.1c02606 ↗
19. Zhao J, Ying Y, Zeng H, et al. Nanoscale thermal strain engineering-driven ferroelastic domain evolution in CH3NH3PbI3 perovskites. ACS Appl Mater Interfaces, 2023, 15: 12502–1251010.1021/acsami.2c19592 ↗
20. Seki T, Feng C, Kashiyama K, et al. Photoluminescent ferroelastic molecular crystals. Angew Chem Int Ed, 2020, 59: 8839–884310.1002/anie.201914610 ↗
21. Chen XX, Zhang XY, Liu DX, et al. Room-temperature ferroelectric and ferroelastic orders coexisting in a new tetrafluoroborate-based perovskite. Chem Sci, 2021, 12: 8713–872110.1039/D1SC01345A ↗
22. Zhang B, Sun S, Jia Y, et al. Simple visualization of universal ferroelastic domain walls in lead halide perovskites. Adv Mater, 2023, 35: 220833610.1002/adma.202208336 ↗
23. Liu DX, Chen XX, Ye ZM, et al. High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me3NCH2CH2OH)4[Ni(NCS)6]. Sci China Mater, 2022, 65: 263–26710.1007/s40843-021-1794-1 ↗
24. Wojciechowska M, Gagor A, Piecha-Bisiorek A, et al. Ferroelectricity and ferroelasticity in organic inorganic hybrid (pyrrolidinium)3[Sb2Cl9]. Chem Mater, 2018, 30: 4597–460810.1021/acs.chemmater.8b00962 ↗
25. Ignatans R, Damjanovic D, Tileli V. Individual Barkhausen pulses of ferroelastic nanodomains. Phys Rev Lett, 2021, 127: 16760110.1103/PhysRevLett.127.167601 ↗
26. Zhang ZX, Su CY, Gao JX, et al. Mechanochemistry enables optical-electrical multifunctional response and tunability in two-dimensional hybrid perovskites. Sci China Mater, 2021, 64: 706–71610.1007/s40843-020-1463-0 ↗
27. Lu X, Chen Z, Cao Y, et al. Mechanical-force-induced non-local collective ferroelastic switching in epitaxial lead-titanate thin films. Nat Commun, 2019, 10: 395110.1038/s41467-019-11825-2 ↗
28. Yang Y, Zhang L, Li S, et al. Mild fluctuations in ferroelastic domain switching. Phys Rev B, 2021, 104: 21410310.1103/PhysRevB.104.214103 ↗
29. Liu X, Xu Z, Long P, et al. A multiaxial layered halide double perovskite ferroelectric with multiple ferroic orders. Chem Mater, 2020, 32: 8965–897010.1021/acs.chemmater.0c02966 ↗
30. Fu DW, Gao JX, Huang PZ, et al. Observation of transition from ferroelasticity to ferroelectricity by solvent selective effect in anilinium bromide. Angew Chem Int Ed, 2021, 60: 8198–820210.1002/anie.202015219 ↗
31. Zhang HY, Chen XG, Tang YY, et al. PFM (piezoresponse force microscopy)-aided design for molecular ferroelectrics. Chem Soc Rev, 2021, 50: 8248–827810.1039/C9CS00504H ↗
32. Liu HY, Zhang HY, Chen XG, et al. Molecular design principles for ferroelectrics: Ferroelectrochemistry. J Am Chem Soc, 2020, 142: 15205–1521810.1021/jacs.0c07055 ↗
33. Tang YY, Xie Y, Zeng YL, et al. Record enhancement of phase transition temperature realized by H/F substitution. Adv Mater, 2020, 32: 200353010.1002/adma.202003530 ↗
34. Zeng YL, Ai Y, Tang SY, et al. Axial-chiral BINOL multiferroic crystals with coexistence of ferroelectricity and ferroelasticity. J Am Chem Soc, 2022, 144: 19559–1956610.1021/jacs.2c08667 ↗
35. Gong YP, Chen XX, Huang GZ, et al. Ferroelasticity, thermochromism, semi-conductivity, and ferromagnetism in a new layered perovskite: (4-Fluorophenethylaminium)2[CuCl4]. J Mater Chem C, 2022, 10: 5482–548810.1039/D2TC00335J ↗
36. Su C, Lun M, Chen Y, et al. Hybrid optical-electrical perovskite can be a ferroelastic semiconductor. CCS Chem, 2022, 4: 2009–201910.31635/ccschem.021.202101073 ↗
37. Kennard RM, Dahlman CJ, DeCrescent RA, et al. Ferroelastic hysteresis in thin films of methylammonium lead iodide. Chem Mater, 2021, 33: 298–30910.1021/acs.chemmater.0c03776 ↗
38. Liu H, Chen J, Huang H, et al. Role of reversible phase transformation for strong piezoelectric performance at the morphotropic phase boundary. Phys Rev Lett, 2018, 120: 05550110.1103/PhysRevLett.120.055501 ↗
39. Pisat AS, Rohrer GS, Salvador PA. Spatial selectivity ofphotodeposition reactions on polar surfaces of centrosymmetric ferroelastic γ-WO3. J Mater Chem A, 2017, 5: 8261–826610.1039/C7TA00842B ↗
40. Qin W, Ali W, Wang J, et al. Suppressing non-radiative recombination in metal halide perovskite solar cells by synergistic effect of ferroelasticity. Nat Commun, 2023, 14: 25610.1038/s41467-023-35837-1 ↗
41. Du ZY, Xu TT, Huang B, et al. Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitive thermo-responsive dielectric materials. Angew Chem Int Ed, 2015, 54: 914–91810.1002/anie.201408491 ↗
42. Moskwa M, Ganczar E, Sobieszczyk P, et al. Temperature-stimulus responsive ferroelastic molecular-ionic crystal: (C8H20N)[BF4]. J Phys Chem C, 2020, 124: 18209–1821810.1021/acs.jpcc.0c05322 ↗
43. Huang PZ, Ni HF, Su CY, et al. Thermal-induced ferroelastics in two lead-free organic-inorganic hybrid perovskites. CCS Chem, 2022, 1–10
44. Jia QQ, Ni HF, Lun MM, et al. Tunable phase transition temperature and nonlinear optical properties of organic-inorganic hybrid perovskites enabled by dimensional engineering. J Mater Chem C, 2022, 10: 16330–1633610.1039/D2TC03497B ↗
45. Zeng YL, Huang XQ, Huang CR, et al. Unprecedented 2D homochiral hybrid lead-iodide perovskite thermochromic ferroelectrics with ferroelastic switching. Angew Chem Int Ed, 2021, 60: 10730–1073510.1002/anie.202102195 ↗
46. Chen Y, Gao C, Yang T, et al. Research advances of ferroelectric semiconductors of 2D hybrid perovskites toward photoelectronic applications. Chin J Struct Chem, 2022, 41: 2204001
47. Ye H, Chen XX, Liu DX, et al. Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic. Chem Sci, 2022, 13: 14124–1413110.1039/D2SC04112J ↗
48. Yue CY, Sun HX, Liu QX, et al. Organic cation directed hybrid lead halides of zero-dimensional to two-dimensional structures with tunable photoluminescence properties. Inorg Chem Front, 2019, 6: 2709–271710.1039/C9QI00684B ↗
49. Zhou J, Li M, Ning L, et al. Broad-band emission in a zero-dimensional hybrid organic [PbBr6] trimer with intrinsic vacancies. J Phys Chem Lett, 2019, 10: 1337–134110.1021/acs.jpclett.9b00238 ↗
50. Liu Y, Han S, Wang J, et al. Spacer cation alloying of a homo-conformational carboxylate trans isomer to boost in-plane ferroelectricity in a 2D hybrid perovskite. J Am Chem Soc, 2021, 143: 2130–213710.1021/jacs.0c12513 ↗
51. Kanwat A, Ghosh B, Ng SE, et al. Reversible photochromism in 〈110〉 oriented layered halide perovskite. ACS Nano, 2022, 16: 2942–295210.1021/acsnano.1c10098 ↗
52. Lee S, Zhou C, Neu J, et al. Bulk assemblies of lead bromide trimer clusters with geometry-dependent photophysical properties. Chem Mater, 2019, 32: 374–38010.1021/acs.chemmater.9b03893 ↗
53. Zheng HW, Yang DD, Shi YS, et al. Conformation- and coordination mode-dependent stimuli-responsive salicylaldehyde hydrazone Zn(II) complexes. Inorg Chem, 2023, 62: 6323–633110.1021/acs.inorgchem.3c00035 ↗
54. Martin CR, Park KC, Leith GA, et al. Stimuli-modulated metal oxidation states in photochromic MOFs. J Am Chem Soc, 2022, 144: 4457–446810.1021/jacs.1c11984 ↗
55. Smith MD, Watson BL, Dauskardt RH, et al. Broadband emission with a massive Stokes shift from sulfonium Pb–Br hybrids. Chem Mater, 2017, 29: 7083–708710.1021/acs.chemmater.7b02594 ↗
56. Jing CQ, Li JZ, Xu T, et al. Organic cations directed 1D [Pb3Br10]4− chains: Syntheses, crystal structures, and photoluminescence properties. CrystEngComm, 2021, 23: 292–29810.1039/D0CE01457E ↗
57. Aizu K. Possible species of “ferroelastic” crystals and of simultaneously ferroelectric and ferroelastic crystals. J Phys Soc Jpn, 1969, 27: 387–39610.1143/JPSJ.27.387 ↗
58. Meng QR, Xu WJ, Hu WH, et al. An unprecedented hexagonal double perovskite organic-inorganic hybrid ferroelastic material: (Piperidinium)2[KBiCl6]. Chem Commun, 2021, 57: 6292–629510.1039/D1CC02085D ↗