journal article·2005-01-01Open access

Development of femtosecond time-resolved scanning tunneling microscopy for nanoscale science and technology

Hidemi Shigekawa, Osamu Takeuchi, Masahiro Aoyama

Abstract

‘Smaller’ and ‘faster’ are the key words in the progress of current nanoscience and technology. Thus, a method of exploring the ultrafast transient dynamics of the local quantum functions in organized small structures is eagerly desired. Ultrashort optical pulse technology has allowed us to observe transient phenomena in the femtosecond range, which, however, has the drawback of a relatively low spatial resolution due to the electromagnetic wavelength used. In contrast, scanning tunneling microscopy and its related techniques, although having a time resolution limited by the circuit bandwidth (~100 kHz), enable us to observe spatial dynamics at the atomic level in real space. Our purpose is to combine these two techniques to achieve a new technology which will advance the pursuit of future nanoscale scientific research in terms of the ultimate temporal and spatial resolutions.We proposed a promising new design for achieving ultimate spatial and temporal resolution, by combining a short-pulse laser and STM.Using this method, time-resolved tunneling current measurement in the subpicosecond range was successfully demonstrated, this is shakenpulse-pair-excited STM (SPPX-STM) satisfies the requirements for exploring the ultrafast dynamics of the local quantum functions occurring in organized small structures. We hope this new technology will promote the development of future research on the nanoscale.
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Research context

OpenAlex topics: Force Microscopy Techniques and Applications · Laser-Matter Interactions and Applications · Spectroscopy and Quantum Chemical Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Applied Physics, CREST, 21st COE, University of Tsukuba, Tsukuba, 305-8573, Japan

References (22)

Show source-provided references
1. K. Shinohara, S. Yasuda, G. Kato, M. Fujita, H. Shigekawa, Direct measurement of the chiral quaternary structure in a p-conjugated polymer at room temperature, J. Am. Chem. Soc. 123 (2001) 3619–3620.10.1021/ja003023m ↗
2. O. Takeuchi, S. Yoshida, H. Shigekawa, Light-modulated scanning tunneling spectroscopy for nanoscale imaging of surface photovoltage, Appl. Phys. Lett. 84 (2004) 3645–3647.10.1063/1.1737063 ↗
3. S. Weiss, D. Botkin, D.F. Ogletree, M. Salmeron, D.S. Chemla, The ultrafast response of a scanning tunneling microscope, Phys. Status Solidi B 188 (1995) 343–359.10.1002/pssb.2221880132 ↗
4. M.R. Freeman, A.Y. Elezzabi, G.M. Steeves, G. Nunes Jr., Ultrafast time resolution in scanning tunneling microscopy, Surf. Sci. 386 (1997) 290–300.10.1016/S0039-6028(97)00306-3 ↗
5. R.H.M. Greoeneveld, H. van Kempman, The capacitive origin of the picosecond electrical transients detected by a photoconductively gated scanning tunneling microscope, Appl. Phys. Lett. 69 (1996) 2294–2296.10.1063/1.117538 ↗
6. N.N. Khusnatdinov, T.J. Nagle, G. Nunes Jr., Ultrafast scanning tunneling microscopy with 1 nm resolution, Appl. Phys. Lett. 77 (2000) 4434–4436.10.1063/1.1336817 ↗
7. R.J. Hamers, G. Cahill, Ultrafast time resolution in scanned probe microscopies: surface photovoltage on Si(111)-(7×7), J. Vac. Sci. Technol. B9 (1991) 514–518.10.1116/1.585559 ↗
8. O. Takeuchi, R. Morita, M. Yamashita, H. Shigekawa, Development of time-resolved scanning tunneling microscopy in femtosecond range, Jpn. J. Appl. Phys. 41 (7B) (2002) 4994–4997.10.1143/JJAP.41.4994 ↗
9. O. Takeuchi, M. Aoyama, R. Oshima, Y. Okada, H. Oigawa, N. Sano, R. Morita, M. Yamashita, H. Shigekawa, Probing subpicosecond dynamics using pulsed laser combined scanning tunneling microscopy, Appl. Phys. Lett. 85 (2004) 3268–3270.10.1063/1.1804238 ↗
10. O.Takeuchi, M. Aoyama, H.Shigekawa, Analysis of time-resolved tunnel current signal in sub-picosecond range observed by shaken-pulse-pair-excited scanning tunneling miscroscopy, Jpn. J. Appl. Phys. 44 (2005) 5354.
11. Mono-cycle photonics and optical scanning tunneling microscopy, in: M. Yamashita, H. Shigekawa, R. Morita (Eds.), Springer Series in Optical Sciences vol. 99 (2005).
12. S.R. Kurtz, J.F. Klem, A.A. Allerman, R.M. Sieg, C.H. Seager, E.D. Jones, Minority carrier diffusion and defects in InGaAsN grown by molecular beam epitaxy, Appl. Phys. Lett. 80 (2002) 1379–1381.10.1063/1.1453480 ↗
13. A. Mintairov, T. Kosel, J. Merz, P. Blagnov, A. Vlasov, V. Ustinov, R. Cook, Near-field magnetophotoluminescence spectroscopy of composition fluctuations in InGaAsN, Phys. Rev. Lett. 87 (2001) 277401.
14. J. Shah, Ultrafast spectroscopy of semiconductors and semiconductor nanostructures Springer, Solid State Science Series 1999.10.1007/978-3-662-03770-6 ↗
15. D. Zubarev, V. Morozov, G. Ropke, Statistical Mechanics of Nonequilibrium Processes, vol. 1, Akademie, Berlin, 1996.
16. S. Yasuda, T. Nakamura, M. Matsumoto, H. Shigekawa, Phase switching of a single isomeric molecule and associated characteristic rectification, J. Am. Chem. Soc. 125 (2003) 16430–16433.10.1021/ja038233o ↗
17. K. Hata, Y. Sainoo, H. Shigekawa, Atomically resolved local variation of the barrier height of the flip-flop motion of single buckled dimers of Si(100), Phys. Rev. Lett. 86 (2001) 3084–3087.10.1103/PhysRevLett.86.3084 ↗
18. S. Yoshida, T. Kimura, O. Takeuchi, K. Hata, H. Oigawa, T. nagamura, H. Sakama, H. Shigekawa, Probe effect in scanning tunneling microscopy on Si(001) low-temperature phases, Phys. Rev. B 70 (2004) 235411.
19. H. Shigekawa, K. Miyake, J. Sumaoka, A. Harada, M. Komiyama, The molecular abacus: STM manipulation of cyclodextrin necklace, J. Am. Chem. Soc. 122 (2000) 5411–5412.10.1021/ja000037j ↗
20. D.N. Futaba, R. Morita, M. Yamashita, S. Tomiyama, H. Shigekawa, Site-selective silicon adatom desorption using femtosecond laser pulse pairs and scanning tunneling microscopy, Appl. Phys. Lett. 83 (2003) 2333–2335.10.1063/1.1613361 ↗
21. M. Komiyama, N. Takeda, H. Shigekawa, Feature article: hydrolysis of DNA and RNA by lanthanide ions: mechanistic studies leading to new applications, Chem. Commun. 16 (1999) 1443–1451.
22. S. Yoshida, T. Kimura, O. Takeuchi, K. Hata, H. Oigawa, T. Nagamura, H. Sakama, H. Shigekawa, Probe effect in scanning tunneling microscopy on Si(001) low-temperature phases, Phys. Rev. B 70 (2004) 235411.