journal article·2023-07

Preparation and electrochemical behaviour of Ti/Mn 2 O 3 coating anode

Fa‐Ming Xie, Lin Tian, Chuan‐Bin Li, Xue‐Tao Yuan, Yan‐Xi Yin

Rare Metals· Volume 42· Issue 7
Publisher page

Abstract

Owing to the excellent electrocatalytic activity, corrosion resistance and high cell potential of the dimensionally stable anodes (DSA), DSAs have great application potential in metallurgical electrolysis industry. In this research, the Ti/Mn 2 O 3 DSA anode was prepared by the thermal decomposition method. The results showed that the composition of the coating is Mn 2 O 3 , and the surface of the Ti/Mn 2 O 3 coating anode is uniform and compact. But there are tiny cracks in the local area of the dense Mn 2 O 3 coating surface, which significantly improves the electrocatalytic activity. The catalytic activity of the Ti/Mn 2 O 3 anode is greater than that of the Pb‐Ag (0.8 wt%) anode in the sulfuric acid solution. The rate‐determining step of both anodes is the rearrangement of intermediates. The accelerated life of Ti/Mn 2 O 3 anode can reach 34 h, which has great application potential in metallurgical electrochemistry.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing Engineering Research Center of Strategic Nonferrous Metals Green Manufacturing Technology 101047 Beijing China

National Engineering Research Center for Environment‐Friendly Metallurgy in Producing Premium Non‐Ferrous Metals 101047 Beijing China

China General Research Institute for Nonferrous Metals 100088 Beijing China

GRINM Resources and Environment Tech. Co. Ltd 101047 Beijing China

Funding

Research and Development Program of China

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