journal article·2009-06

Solution-Deposited Thin Silver Films on Plastic Surfaces for Low-Cost Applications in Plasmon-Coupled Emission Sensors

R. Sai Sathish, Y. Kostov, D. S. Smith, Govind Rao

Plasmonics· Volume 4· Issue 2
Publisher page

Abstract

We report the deposition of highly uniform thin silver films on plastic materials using a wet-chemistry method, suitable for surface plasmon-coupled emission (SPCE). This approach is reproducible for diverse low-cost applications and versatile to generate silver surfaces on various plastics substrates. An oxygen plasma pretreatment of the plastic provides for rapid silvering, leading to a 47-nm-thick continuous film for SPCE applications. The surface smoothness and thickness of the films have been estimated using atomic force microscope. The higher refractive index of polycarbonate, resulted in an SPCE angle of θF = 470 for Rhodamine B, compared to glass (θF = 500). The current study presents details on film deposition conditions, appropriate choice of index matching fluids, substrates, and light sources that play a vital role to augment SPCE emission intensity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced biosensing and bioanalysis techniques · Gold and Silver Nanoparticles Synthesis and Applications · Biosensors and Analytical Detection

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Ge X, Kostov Y, Rao G (2005) Low-cost noninvasive optical CO2 sensing system for fermentation and cell culture. Biotechnol Bioeng 89:329–334. doi: 10.1002/bit.2033710.1002/bit.20337 ↗
2. Ge X, Hanson M, Shen H, Kostov Y, Brorson KA, Frey DD, Moreira AR, Rao G (2006) Validation of an optical sensor-based high-throughput bioreactor system for mammalian cell culture. J Biotechnol 12:293–306. doi: 10.1016/j.jbiotec.2005.12.00910.1016/j.jbiotec.2005.12.009 ↗
3. Tanaka G, Funabashi H, Mie M, Kobatake E (2006) Fabrication of an antibody microwell array with self-adhering antibody binding protein. Anal Biochem 350:298–303. doi: 10.1016/j.ab.2005.12.03410.1016/j.ab.2005.12.034 ↗
4. Guo XQ, Castellano FN, Li L, Lakowicz JR (1998) Use of a long-lifetime Re(I) complex in fluorescence polarization immunoassays of high-molecular-weight analytes. Anal Chem 70:632–637. doi: 10.1021/ac970827k10.1021/ac970827k ↗
5. Kricka LJ (2002) Stains, labels and detection strategies for nucleic acids assays. Ann Clin Biochem 39:114–129. doi: 10.1258/000456302190186510.1258/0004563021901865 ↗
6. Van Orden A, Machara NP, Goodwin PM, Keller RA (1998) Single-molecule identification in flowing sample streams by fluorescence burst size and intraburst fluorescence decay rate. Anal Chem 70(7):14404–1451. doi: 10.1021/ac970545k10.1021/ac970545k ↗
7. Lakowicz JR (2004) Radiative decay engineering 3. Surface plasmon-coupled directional emission. Anal Biochem 324:153–169. doi: 10.1016/j.ab.2003.09.03910.1016/j.ab.2003.09.039 ↗
8. Gryczynski I, Malicka J, Gryczynski Z, Lakowicz JR (2004) Radiative decay engineering 4. Experimental studies of surface plasmon-coupled directional emission. Anal Biochem 324(2):170–182. doi: 10.1016/j.ab.2003.09.03610.1016/j.ab.2003.09.036 ↗
9. Hiep HM, Fujii M, Hayashi S (2007) Effects of molecular orientation on surface-plasmon-coupled emission patterns. Appl Phys Lett 91:183110–183113. doi: 10.1063/1.280456310.1063/1.2804563 ↗
10. Ray K, Chowdhury MH, Lakowicz JR (2008) Observation of surface plasmon-coupled emission using thin platinum films. Chem Phys Lett 465(1–3):92–95. doi: 10.1016/j.cplett.2008.09.05710.1016/j.cplett.2008.09.057 ↗
11. Aslan K, McDonald K, Previte MJR, Zhang Y, Geddes CD (2008) Silver island nanodeposits to enhance surface plasmon coupled fluorescence from copper thin films. Chem Phys Lett 464(4–6):216–219. doi: 10.1016/j.cplett.2008.09.04110.1016/j.cplett.2008.09.041 ↗
12. Smith DS, Kostov Y, Rao G (2008) Signal enhancement of surface plasmon-coupled directional emission by a conical mirror. Appl Opt 47(8):5229–5234. doi: 10.1364/AO.47.00522910.1364/AO.47.005229 ↗
13. Kostov Y, Smith DS, Tolosa L, Rao G, Gryczynski I, Gryczynski Z, Malicka J, Lakowicz JR (2005) Directional surface plasmon-coupled emission from a 3 nm green fluorescent protein monolayer. Biotechnol Prog 21:1731–1735. doi: 10.1021/bp050114k10.1021/bp050114k ↗
14. Smith DS, Kostov Y, Rao G (2007) SPCE-based sensors: ultrafast oxygen sensing using surface plasmon-coupled emission from ruthenium probes. Sens Actuator B 127:432–440. doi: 10.1016/j.snb.2007.04.04410.1016/j.snb.2007.04.044 ↗
15. Stefani D, Vasilev K, Bocchio N, Stoyanova N, Kreiter M (2005) Surface-plasmon-mediated single-molecule fluorescence through a thin metallic film. Phys Rev Lett 94(2):023005. doi: 10.1103/PhysRevLett.94.02300510.1103/PhysRevLett.94.023005 ↗
16. Matveeva EG, Gryczynski I, Malicka J, Gryczynski Z, Goldys E, Howe J, Berndt KW, Lakowicz JR (2005) Plastic versus glass support for an immunoassay on metal-coated surfaces in optically dense samples utilizing directional surface plasmon-coupled emission. J Fluoresc 15(6):865–871. doi: 10.1007/s10895-005-0015-210.1007/s10895-005-0015-2 ↗
17. Xia Y, Venkateswaran N, Qin D, Tien J, Whitesides GM (1998) Use of electroless silver as the substrate in microcontact printing of alkanethiols and its application in microfabrication. Langmuir 14:363–371. doi: 10.1021/la970708010.1021/la9707080 ↗
18. Moran CE, Radloff C, Halas NJ (2003) Benchtop fabrication of submicrometer metal line and island arrays using passivative microcontact printing and electroless plating. Adv Mater 15(10):804–807. doi: 10.1002/adma.20030450710.1002/adma.200304507 ↗
19. Smith DS, Thesis Ph.D (2008) UMBC, Baltimore
20. Kreschmann E, Raether H (1968) Radiative decay of nonradiative surface plasmons excited. by light. Z Naturforsch Teil A 23:2135–213610.1515/zna-1968-1247 ↗
21. Smith DS, Kostov Y, Rao G, Gryczynski I, Malicka J, Gryczynski Z, Lakowicz JR (2005) First observation of surface plasmon-coupled emission due to led excitation. J Fluoresc 15(6):895–900. doi: 10.1007/s10895-005-0021-410.1007/s10895-005-0021-4 ↗
22. Raether H (1997) Physics of Thin Films, Advances in Research and Development. Academic, New York
23. Rastomjee CS, Keil M, Sotobayashi H, Bradshaw AM, Lamont CLA, Gador D, Umbach E (1998) Aluminium metallisation of argon and oxygen plasma-modified polycarbonate thin film surfaces. Appl Surf Sci 136(4):280–297. doi: 10.1016/S0169-4332(98)00348-110.1016/S0169-4332(98)00348-1 ↗
24. Guruvenket S, Mohan Rao G, Manoj Komath, Raichur AM (2004) Plasma surface modification of polyethylene and polystyrene. Appl Surf Sci 236(1–4):278–284. doi: 10.1016/j.apsusc.2004.04.03310.1016/j.apsusc.2004.04.033 ↗
25. Liebermann T, Knoll W (2000) Surface-plasmon field-enhanced fluorescence spectroscopy. Colloids Surf. A Physicochem Eng Asp 171:115–130. doi: 10.1016/S0927-7757(99)00550-610.1016/S0927-7757(99)00550-6 ↗