journal article·2013-06

Plasmonic Coupling Effect in Ag Nanocap–Nanohole Pairs for Surface-Enhanced Raman Scattering

Xiaolei Wen, Zheng Xi, Xiaojin Jiao, Wenhai Yu, Guosheng Xue, Douguo Zhang, Yonghua Lu, Pei Wang, Steve Blair, Hai Ming

Plasmonics· Volume 8· Issue 2
Publisher page

Abstract

A plasmonic coupling structure composed of Ag nanocap–nanohole pairs was fabricated through a novel and facile method. Both surface-enhanced Raman scattering (SERS) measurements and numerical simulations show that the cap-hole system produces much larger electric field enhancement and SERS signal than the isolated structures, which is due to the plasmonic coupling effect between the gap of the cap and the hole. Additionally, the plasmonic enhancement is sensitive to the gap size, which can be controlled by the Ag layer thickness during the evaporation process. A maximum enhancement factor of 1.1×108 can be obtained with optimized gap size.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Plasmonic and Surface Plasmon Research · Nanoparticle-Based Drug Delivery

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Nie S, Emory SR (1997) Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275(5303):1102–110610.1126/science.275.5303.1102 ↗
2. Winkler K, Kaminska A, Wojciechowski T, Holyst R, Fialkowski M (2011) Gold micro-flowers: one-step fabrication of efficient, highly reproducible surface-enhanced Raman spectroscopy platform. Plasmonics 6(4):697–70410.1007/s11468-011-9253-0 ↗
3. Yi M, Zhang D, Wang P, Jiao X, Blair S, Wen X, Fu Q, Lu Y, Ming H (2011) Plasmonic interaction between silver nano-cubes and a silver ground plane studied by surface-enhanced Raman scattering. Plasmonics 6(3):515–51910.1007/s11468-011-9230-7 ↗
4. Michaels AM, Nirmal M, Brus LE (1999) Surface enhanced Raman spectroscopy of individual rhodamine 6g molecules on large ag nanocrystals. J Am Chem Soc 121(43):9932–993910.1021/ja992128q ↗
5. Otto A, Mrozek I, Grabhorn H, Akemann W (1992) Surface-enhanced Raman scattering. J Phys Condens Matter 4:1143–121210.1088/0953-8984/4/5/001 ↗
6. Moskovits M (1985) Surface-enhanced spectroscopy. Rev Mod Phys 57(3):783–82610.1103/RevModPhys.57.783 ↗
7. Metiu H, Das P (1984) The electromagnetic theory of surface enhanced spectroscopy. Annu Rev Phys Chem 35(1):507–53610.1146/annurev.pc.35.100184.002451 ↗
8. Ye J, Shioi M, Lodewijks K, Lagae L, Kawamura T, Van Dorpe P (2010) Tuning plasmonic interaction between gold nanorings and a gold film for surface enhanced Raman scattering. Appl Phys Lett 97(16):1–3
9. Im H, Bantz KC, Lindquist NC, Haynes CL, Oh SH (2010) Vertically oriented sub-10-nm plasmonic nanogap arrays. Nano Lett 10(6):2231–223610.1021/nl1012085 ↗
10. Wei H, Håkanson U, Yang Z, Höök F, Xu H (2008) Individual nanometer hole-particle pairs for surface-enhanced Raman scattering. Small 4(9):1296–130010.1002/smll.200701135 ↗
11. Wen X, Yi M, Zhang D, Wang P, Lu Y, Ming H (2011) Tunable plasmonic coupling between silver nano-cubes and silver nano-hole arrays. Nanotechnology 22:85203–8520910.1088/0957-4484/22/8/085203 ↗
12. Lu Y, Liu GL, Kim J, Mejia YX, Lee LP (2005) Nanophotonic crescent moon structures with sharp edge for ultrasensitive biomolecular detection by local electromagnetic field enhancement effect. Nano Lett 5(1):119–12410.1021/nl048232+ ↗
13. Kneipp K, Kneipp H, Kartha VB, Manoharan R, Deinum G, Itzkan I, Dasari RR, Feld MS (1998) Detection and identification of a single DNA base molecule using surface-enhanced Raman scattering (SERS). Phys Rev E 57(6):6281–628410.1103/PhysRevE.57.R6281 ↗
14. Love JC, Gates BD, Wolfe DB, Paul KE, Whitesides GM (2002) Fabrication and wetting properties of metallic half-shells with submicron diameters. Nano Lett 2(8):891–89410.1021/nl025633l ↗
15. Zhang Y, Barhoumi A, Lassiter JB, Halas NJ (2011) Orientation-preserving transfer and directional light scattering from individual light-bending nanoparticles. Nano Lett 11(4):1838–184410.1021/nl2008357 ↗
16. Wei H, Hao F, Huang Y, Wang W, Nordlander P, Xu H (2008) Polarization dependence of surface-enhanced Raman scattering in gold nanoparticle-nanowire systems. Nano Lett 8(8):2497–250210.1021/nl8015297 ↗
17. Mirin NA, Halas NJ (2009) Light-bending nanoparticles. Nano Lett 9(3):1255–125910.1021/nl900208z ↗
18. Palik ED (1998) Handbook of optical constants of solids III. Academic, New York
19. Moskovits M (2006) Surface-enhanced Raman spectroscopy: a brief perspective. In: Kneipp K, Moskovits M, Kneipp H (eds) Surface-enhanced Raman scattering: physics and applications. Topics in applied physics, vol 103. Springer, New York, pp 1–1710.1007/3-540-33567-6_1 ↗
20. Wu H-Y, Cunningham BT (2011) Plasmonic coupling of sio[sub 2]-ag“post-cap” nanostructures and silver film for surface enhanced Raman scattering. Appl Phys Lett 98(15):153103–15310510.1063/1.3555342 ↗
21. Yamaguchi K, Inoue T, Fujii M, Haraguchi M, Okamoto T, Fukui M, Seki SHU, Tagawa S (2007) Electric field enhancement of nano gap of silver prisms. Chin Phys Lett 24(10):2934–293710.1088/0256-307X/24/10/061 ↗
22. Lévêque G, Martin OJF (2006) Optical interactions in a plasmonic particle coupled to a metallic film. Opt Express 14(21):9971–998110.1364/OE.14.009971 ↗
23. Zhu W, Banaee MG, Wang D, Chu Y, Crozier KB (2011) Lithographically fabricated optical antennas with gaps well below 10 nm. Small 7(13):1761–176610.1002/smll.201100371 ↗
24. Van Duyne RP, Hulteen JC, Treichel DA (1993) Atomic force microscopy and surface-enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass. J Chem Phys 99(3):2101–211510.1063/1.465276 ↗
25. lIN WC, Huang SH, Chen CL, Chen CC, Tsai DP, Chiang HP (2010) Controlling sers intensity by tuning the size and height of a silver nanoparticle array. Appl Phys A Mater Sci Process 101:185–18910.1007/s00339-010-5777-y ↗