journal article·2021-12Open access

Compositional dependence of the magnetic state of Co3−xZnxTeO6 solid solutions

T. Sarkar, S.A. Ivanov, M. Weil, R. Clulow, E. Lewin, R. Mathieu

Abstract

The magnetic properties of phase-pure solid solutions of Co3−xZnxTeO6 are investigated using magnetometry (single crystals) and neutron diffraction (polycrystalline powders), and compared to results of detailed crystallographic studies. There are five unique Co sites in Co3TeO6, including a tetrahedrally coordinated Co2 site which Zn preferentially occupies. The magnetic interaction is found to monotonically decrease as the Co2-O bond length decreases with increasing Zn content. The results suggest a modification of the magnetic structure in the samples containing Zn.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Complex magnetism and magnetic-field-driven electrical polarization of Co3TeO610.1103/PhysRevB.84.180404 ↗
2. Spin and dipole ordering in Ni2InSbO6 and Ni2ScSbO6 with corundum-related structure10.1021/cm304095s ↗
3. Non-hysteretic collosal magnetoelectricity in a collinear antiferromagnet10.1038/ncomms4201 ↗
4. Mn3TeO6- a new multiferroic material with two magnetic substructures10.1002/pssr.201510347 ↗
5. Spin-driven pyroelectricity in Ni3TeO6 without ferroelectric signatures of the transition at Néel temperature: spin-driven pyroelectricity in Ni3TeO610.1002/pssr.201700073 ↗
6. Magnetoelectric inversion of domain patterns10.1038/s41586-018-0432-4 ↗
7. Complex magnetism in Ni3TeO6-type Co3TeO6 and high-pressure polymorphs of Mn3-xCoxTeO6 solid solutions10.1039/D0CC07487J ↗
8. Structural, magnetic, and spin dynamical properties of the polar antiferromagnets Ni3−xCoxTeO6 (x=1,210.1103/PhysRevB.101.014429 ↗
9. Data-driven computational prediction and experimental realization of exotic perovskite-related polar magnets10.1038/s41535-020-00294-2 ↗
10. Multianvil high-pressure/high-temperature synthesis and characterization of magnetoelectric HP-Co3TeO610.1039/D0TC05210H ↗
11. New type of incommensurate magnetic ordering in Mn3TeO610.1016/j.materresbull.2011.07.041 ↗
12. New insights into the multiferroic properties of Mn3TeO610.1088/1361-6463/aa5621 ↗
13. Novel spin lattice in Cu3TeO6: an antiferromagnetic order and domain dynamics
14. Ni3TeO6--a collinear antiferromagnet with ferromagnetic honeycomb planes10.1088/0953-8984/22/5/056002 ↗
15. A new synthetic cobalt tellurate: Co3TeO610.1107/S010827010602347X ↗
16. Temperature-dependent multi-k magnetic structure in multiferroic Co3TeO610.1016/j.materresbull.2011.10.003 ↗
17. Crystal chemistry, optical spectroscopy and crystal field calculations of Co3TeO6 and solid solutions Co3-xZnxTeO610.1002/ejic.201800701 ↗
18. Remarks on magnetically dilute systems10.1016/0022-3697(59)90121-0 ↗
19. The magnetic dilution problem10.1002/pssb.19680270152 ↗
20. Spectacular switching from ferrimagnetism to antiferromagnetism by zinc doping in “114″ orthorhombic CaBaCo4O710.1063/1.4725517 ↗
21. Magnetic structure of the frustrated S=1/2 chain magnet LiCu2O2 doped with nonmagnetic Zn10.1103/PhysRevB.88.104411 ↗
22. Experimental characterization of the Ising model in disordered antiferromagnets10.1590/S0103-97332000000400009 ↗
23. Cationic distribution, exchange interactions, and relaxation dynamics in Zn-diluted MnCo2O4 nanostructures10.1063/1.5079800 ↗
24. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
26. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data10.1107/S0021889811038970 ↗
27. Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination10.1107/S1600576714022985 ↗
28. Crystal structure refinement with SHELXL10.1107/S2053229614024218 ↗
29. Surface charge neutralization of insulating samples in x-ray photoemission spectroscopy10.1116/1.581507 ↗
30. Enhancement of antiferromagnetic interaction and transition temperature in M3TeO6 systems (M = Mn, Co, Ni, Cu10.1140/epjb/e2013-40152-x ↗