Enhancement of irreversibility field and critical current density of rare earth containing V0.60Ti0.40 alloy superconductor by cold-working and annealing
Source abstract
Abstract
β-V 1−xTi x alloy superconductors are considered to be promising materials for high magnetic field applications. So far, attempts to improve the critical current density ( J C) of β-V 1−xTi x alloys have shown limited success. Improving J C requires a controlled generation of defects. Similar to the V 0.6Ti 0.4 -RE (RE = Gd, Y) alloys, RE = Ce, Dy and Nd are also immiscible in the V 0.6Ti 0.4 matrix. The superconducting transition temperature ( T C), upper critical field ( H C2), irreversibility field ( H Irr), and J C increase with the RE addition. However, the tensile strength of V 0.6Ti 0.4-Gd alloy is observed to be significantly lower than that of V 0.6Ti 0.4 alloy. Cold-working is found to further improve the T C, H C2, H Irr, and J C of all the V 0.6Ti 0.4-RE alloys. Successive cold-working (with 50% reduction of thickness each time) and annealing (SCA) at 450 ∘C for 5 hrs is found to significantly improve the H Irr, and J C of V 0.6Ti 0.4 -RE (RE = Gd, Ce) alloys. The tensile strength is also found to increase to about 60–70% of the V 0.6Ti 0.4 alloy after the third annealing. It is observed that α ′ and ω phases form at the defect sites at various stages of cold-working and annealing. J C(H = 0) and H Irr are about 840 Amm −2 and 7 T respectively for the as-cast V 0.6Ti 0.4-RE alloys. Cold-working on the V 0.6Ti 0.4-RE alloys further improves the J C(H = 0) and H Irr to about 1250 Amm −2 and 8.45 T respectively. SCA increases the J C(H = 0) and H Irr to about 4000 Amm −2 (or more) and 9 T respectively, and the J C(7 T) to about 500 Amm −2 in V 0.6Ti 0.4 -RE alloy at 4 K. We present a detailed description of the defect structure in these alloys and its role in pinning the magnetic flux lines, thereby improving the overall J C.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Rare-earth and actinide compounds · Iron-based superconductors research · Magnetic Properties of Alloys
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Low temperature superconductors: Nb3Sn, Nb3Al, and NbTi10.1016/j.supcon.2023.100047 ↗
2. Effect of the oxygen source configuration on the superconducting properties of internally-oxidized internal-Sn Nb3Sn wires10.1088/1361-6668/aced25 ↗
3. Improving critical current density of Nb3Sn by optimizing pinning potential of grain boundary and grain size10.1088/1361-6668/ac6b5f ↗
4. The 16 T dipole development program for FCC and HE-LHE
5. Analysis of local burnout in a sub-scale test coil for 32 T magnet after spontaneous quenches during fast ramping10.1088/1361-6668/ac49a4 ↗
6. Enhancement in high-field JC properties and flux pinning mechanism of ZnO-Buffered MgB2 films10.1021/acsomega.3c00809 ↗
7. Effect of cubic and hexagonal boron nitride additions on the microstructure and properties of bulk MgB2 superconductors10.1088/1361-6668/ac7616 ↗
8. Enhanced flux pinning by magnetic CrB2 nanoparticle in MgB2 superconductor10.1016/j.jmmm.2022.169174 ↗
9. Enhancing critical current density of bulk MgB2 via nanoscale boron and Dy2O3 doping10.1002/adem.202200487 ↗
10. High temperature superconductors for commercial magnets10.1088/1361-6668/acf901 ↗
11. Raising critical currents in TBaCuO-type high-temperature superconductors by Mo substitution10.1063/10.0017239 ↗
12. Enhancement of Bi-2223 intergrain connections by heat treatment parameters optimization10.1109/TASC.2022.3144126 ↗
13. Enhanced critical current density and pinning properties in KNbO3 nanoparticles added YBCO superconductor10.1007/s00339-023-06572-7 ↗
14. Thermodynamic approach for enhancing superconducting critical current performance10.1038/s41427-022-00432-1 ↗
15. Neutron irradiation effects on alloy superconductors10.1016/0022-3115(82)90529-3 ↗
16. Comparing neutron and helium ion irradiation damage of REBa2Cu3O7−δ coated conductor using x-ray absorption spectroscopy10.1088/1361-6668/aced9e ↗
17. The effect of fast neutron irradiation on the superconducting properties of REBCO coated conductors with and without artificial pinning centres10.1088/1361-6668/aaadf2 ↗
18. Low activation high entropy alloys for next generation nuclear applications10.1016/j.mtla.2018.09.014 ↗
19. Refractory metals as core materials for generation IV nuclear reactors in Structural Materials for Generation IV Nuclear Reactors
20. Effect of Gd addition on the superconducting properties of Ti-based V, Nb, Ta alloys10.1016/j.supcon.2023.100048 ↗
21. Effect of adding Fe and Gd on the superconducting and normal state properties of V60Ti40 alloy
22. Enhancement of functional properties of V0.6Ti0.4 alloy superconductor by the addition of yttrium10.1063/5.0058170 ↗
23. Grain refinement and enhancement of critical current density in the V0.6Ti0.4 alloy superconductor wit hGd addition10.1109/TASC.2021.3052718 ↗
24. Induced activity of several candidate superconductor materials in a tokamak-type fusion reactor10.1016/j.jnucmat.2004.04.164 ↗
25. Towards V-based high-entropy alloys for fusion applications10.1016/j.scriptamat.2019.09.028 ↗
26. Vanadium for Nuclear systems in
27. Superconducting properties of V-Ti alloys10.1109/TASC.2007.899595 ↗
28. Critical current and flux pinning properties of the superconducting Ti-V alloys10.1016/j.physc.2015.02.049 ↗
29. Superconductivity and microstructure of V-Ti alloy multifilament prepared by diffusion reaction between constituent pure-metal subelements10.1063/1.3402311 ↗
30. Multifilamentary Nb-Zr and V-Ti superconducting alloys prepared by diffusion reaction between constituent pure-metal subelements10.1088/0953-2048/21/02/025004 ↗
31. Structural and magnetic properties of the as-cast V1−xZrx alloy superconductors10.1063/1.5121184 ↗
32. Multifilamentary coated conductors for ultra-high magnetic field applications
33. Improvement of critical current density of REBa2Cu3O7−δ by increase in configurational entropy of mixing10.1098/rsos.211874 ↗
34. Development of 50-meter RE-Ba-Cu-O tapes with critical current over 1750A/12mm at 65 K, 0.25 T by advanced-MOCVD
35. High-current double-sided REBCO tapes by advanced MOCVD10.1088/1361-6668/ace8c8 ↗
36. Enhancement of pinning and the peak effect in Y)1 − xFexBa2Cu3Oy high-temperature superconductors10.1016/j.cap.2022.06.019 ↗
37. Critical current density in granular REBa2Cu3O7−δ superconductors with different interlayer magnetic coupling10.1016/j.physleta.2022.128072 ↗
38. Roles of electron mean free path and flux pinning in optimizing the critical current in YBCO superconductors10.1088/1361-6668/ac68a5 ↗
39. Critical current density improvement in CSD-grown high-entropy REBa2Cu3O7−δ films10.1039/D2RA03807B ↗
40. Influence of defect morphology on Absolute JC value in heavy-ion irradiated REBCO films10.1109/TASC.2023.3238288 ↗
41. Defining optimal thickness for maximal self-field JC in TBCO/CeO2 multilayers grown on buffered metal
42. Investigation of Cr addition effect on structural, morphological, electrical and magnetic properties of Bi (Pb)-2212 superconductors
43. Effect of Er/Y addition on the growth and superconductivity of Bi2212 films
44. Microstructure and substrate dependent enhanced critical current density in Pb-substituted Bi-based high temperature superconducting thin films
45. Drastic enhancement of magnetic critical current density in Zn doped Bi-2212
46. High critical current density of nanostructured MgB2 bulk superconductor densified by spark plasma sintering10.3390/nano12152583 ↗
47. Review on high performance bulk MgB2 superconductors10.1088/1361-6463/ad039a ↗
48. Mechanism of enhanced critical fields and critical current densities of MgB2 wires with C/Dy2O3 co-additions10.1063/5.0130589 ↗
49. Effect of polysilane addition on spark plasma sintering and superconducting properties of MgB2 bulks10.1016/j.ceramint.2022.07.127 ↗
50. D. Kalyan, S. K. Makineni, and S. Santra, Effect of Zr on growth kinetics, microstructure and microtexture of Nb3Sn by bronze technique10.1016/j.jallcom.2022.168140 ↗
51. Matsushita · 2014
52. APC Nb3Sn superconductors based on internal oxidation of Nb-Ta-Hf alloys10.1088/1361-6668/acb17a ↗
53. Effect of independent alloying of zirconium with bronze and niobium on superconducting properties of Nb3Sn in a Cu(Sn)/Nb system10.1016/j.scriptamat.2023.115466 ↗
54. Critical current density enhancement of Nb3Sn superconducting wires by incorporating oxygen through rapid heating method10.1016/j.matlet.2023.134157 ↗
55. Novel high-tin bronze and Nb3Sn multifilamentary wires10.1109/TASC.2022.3163680 ↗
56. The effect of joint titanium and tatalum doping on the structure and properties of Nb3Sn-based superconducting strands10.1134/S0031918X22080142 ↗
57. Improvement of critical current density JC in powder-in-tube rapid heating, quenching and transformation Nb3Al wires by doping with nano-SnO210.1088/1361-6668/acc6f9 ↗
58. Experimental study on the critical current properties of flexible Nb3Al superconducting wires in cryocooler system10.1109/TASC.2023.3258911 ↗
59. Reproducible stable critical current density in powder-in-tube (PIT) Nb3Al superconductors by multi-time rapid heating and quenching process
60. Fabrication and microstructure of 30-filament jelly-roll Nb3Al superconducting wires with very high critical current density10.1007/s10948-022-06275-9 ↗
61. Comparison of the pinning behaviour of Nb3Al superconductors prepared by MAT and RHQT methods10.1007/s10948-022-06235-3 ↗
62. Microstructure and composition comparison of Ti- and Ta-doped Nb3Al superconducting wires fabricated by RHQT process10.1002/pssa.202200170 ↗
63. New nanoscale artificial pinning centres for NbTi superconductors10.1016/j.matdes.2020.109285 ↗
64. Investigation of the correlation between initial microstructure and critical current density of Nb-46.5 wt%Ti superconducting material10.3390/met11050777 ↗
65. Spin-fluctuations in Ti0.6V0.4 alloy and its influence on the superconductivity10.1016/j.physb.2013.11.043 ↗
66. Coexisting superconductivity and ferromagnetism in the (V0.60Ti0.40)-Gd alloys10.1016/j.mseb.2021.115462 ↗
67. Strong paramagnetic response in the superconducting state of Y-containing V0.60Ti0.40 alloys10.1088/1361-6668/ac8290 ↗
68. Gschneidner · 1964 · 222
69. A.S. Komjathy, R.H. Read and W. Rostoker, Phase relationships in selected binary and ternary vanadium-base alloys systems, WADD Technical report no. 59–483, Wright-Patterson Airforce base, Ohio, 1960. [Permanent Online link: 〈https://catalog.hathitrust.org/Record/009230761〉].
70. B. Love, The metallurgy of yttrium and the rare earth metals, WADD Technical report no. 60–74, part I, Wright-Patterson Airforce base, Ohio, 1960. [Permanent Online link: 〈https://catalog.hathitrust.org/Record/009206837〉].
71. Binary rare earth-vanadium systems10.1016/0364-5916(88)90033-8 ↗
72. Intermetallic compounds of rare-earth and 3d transition metals10.1088/0034-4885/40/10/002 ↗
73. Thermodynamic assessment of V-rare earth systems10.1007/s11669-010-9779-4 ↗
74. J.F. Collins, V.P. Calkins, and J.A. McGurty, Applications of rare earths to ferrous and non-ferrous alloys.in Am. Soc. Met.-Atomic Ener. commission symp. on the rare earth and related metals, Chicago, Illinois, 1959. [Permanent online link: 10.2172/4215576].10.2172/4215576 ↗
75. The formation of precipitates and its effect on grain structure in V-4Cr-4Ti alloys with yttrium addition10.1016/j.jallcom.2016.10.112 ↗
76. The influence of electron-phonon coupling and spin fluctuations on the superconducting of the Ti-V alloys10.1140/epjb/e2014-50036-2 ↗
77. Magnetic properties of high purity yttrium, lanthanum, and lutetium and the effects of impurities on these properties10.1063/1.1680357 ↗
78. Titanium: Physical Metallurgy
79. dePruneda, J.H., Gallegos, G.F., and Stratman, M.P. The effects of furnace environment on the mechanical properties of vanadium. Technical Report No. UCID-20726, OSTI identifier: 7161856, 1988.Web. 10.2172/7161856.10.2172/7161856 ↗
80. Microstructure and mechanical properties of titanium alloys
81. Overview: Microstructure and properties of beta titanium alloys
82. Deformation behaviour in quenched and aged beta Ti-V alloys10.1007/BF02644467 ↗
83. Omega phase embrittlement in aged Ti-V10.1007/BF02900269 ↗
84. Phase transformation in beta isomorphous, titanium alloys10.1016/0001-6160(70)90087-8 ↗
85. Martensitic transformation from β to α′ and α″ phases in Ti-V alloys: A first Principles study10.1557/jmr.2017.276 ↗
86. The role of stress induced martensite in ductile metastable beta Ti-alloys showing combined TRIP/TWIP effects
87. Effect of deformation-induced ω phase on the mechanical properties of metastable β-type Ti-V alloys10.2320/matertrans.M2012116 ↗
88. Phase transformations in Ti-V alloys10.1007/BF00560624 ↗
89. The stress-induced omega phase transformations in Ti-V alloys10.1007/BF02642306 ↗
90. Metastable phases in the Ti-V system: Part I. Neutron diffraction study and assessment of structural properties10.1007/s11661-002-0057-x ↗
91. Low temperature -calorimetric studies of superconductivity and microstructure in titanium-vanadium alloys
92. Composition dependence of Young’s modulus in Ti-V, Ti-Nb, and Ti-V-Sn alloys10.1007/BF02586159 ↗
93. Resistometric estimation of temperature range of athermal ω phase formation in quenched Ti-V alloys10.2320/jinstmet1952.54.7_743 ↗
94. Hgh field paramagnetic effect in the superconducting state of Ti0.8V0.2 alloy10.1088/0953-2048/26/11/115005 ↗
95. Phase transformations in Ti-V alloys: Part I Martensitic transformations10.1007/BF00560624 ↗
96. Flux pinning in type II superconductors10.1080/14786439808206556 ↗
97. Anomalous electrical resistivity, bcc phase stability, and superconductivity in titanium-vanadium alloys10.1103/PhysRevB.9.3989 ↗
98. Crystallography Open Database -an open-acess collection of crystal structure10.1107/S0021889809016690 ↗
99. Mechanical properties correlated with transformation characteristics of titanium-vanadium alloys
100. The indirect influence of the ω phase on the degree of refinement of distributions of the α phase in metastable β-titanium alloys10.1016/j.actamat.2015.09.053 ↗