journal article·2023-10

Effect of Ni alloying on the microstructure and magnetocaloric properties of Gd-based metallic microfibers

Yanyang Yao, Ze Li, Jingshun Liu, Mingwei Zhang, Yun Zhang, Feng Wang, Rui Liu, HongXian Shen

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Abstract

Gd-based metallic microfibers have been the research highlights due to the significant magnetocaloric effect. Herein, the atomic cluster micro-regions are constructed in Gd-based microfibers to further improve the magnetocaloric effect. The results show that the continuous and amorphous microfibers with excellent softly magnetic and thermal stability properties are obtained. The maximum magnetic entropy change -Δ S m max of Gd-based microfibers increases first and then decreases with Ni alloying degree increase. Among which, the better magnetocaloric properties is obtained in (Gd 60A 20lCo 20) 95Ni 5 microfibers. The maximum magnetic entropy change, refrigeration capacity ( RC), and relative cooling power ( RCP) at 5 T reach 11.57 J/kg K, 834.14 J/kg, and 1138.16 J/kg, respectively. The outstanding magnetocaloric properties of microfibers are attributed to the indirect interaction coupling caused by Ni elements and the atomic cluster micro-regions, which lead to a fundamental shift in magnetic entropy. The findings of this study promote the application of Gd-based microfibers in the field of magnetic refrigeration.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Shape Memory Alloy Transformations

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