journal article·2012-09Open access

The luminescence properties of rare-earth ions in natural fluorite

M. Czaja, S. Bodył-Gajowska, R. Lisiecki, A. Meijerink, Z. Mazurak

Physics and Chemistry of Minerals· Volume 39· Issue 8

Abstract

For the first time, the luminescence properties of Pr3+, Nd3+ and Tm3+ and Yb3+ ions in fluorite crystal have been obtained by steady-state measurements. In addition, the luminescence spectra of Ce3+, Sm2+, Sm3+, Dy3+, Er3+ and Yb3+ were measured. It was pointed out that λexc. = 415 nm is most suitable for measuring the Ho3+ emission beside the Er3+. The emission of trivalent holmium and erbium ions was measured independently using time-resolved measurements and tentative assignment of luminescence lines to C 3v and C 4v symmetry sites was proposed. Besides for natural fluorite crystal, the transitions between Stark energy levels of lanthanide ions were presented.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Aierken S, Lee KH, Kusachi I, Yamashita N (2000) Photoluminescence properties of natural fluorite. J Miner Petrolog Sci 95:228–23510.2465/jmps.95.228 ↗
2. Aierken S, Kusachi I, Yamashita N (2003) Natural fluorite emitting yellow fluorescence under UV light. Phys Chem Miner 30:478–48510.1007/s00269-003-0341-3 ↗
3. Baraldi A, Capelleni R, Mazzera M (2007) Hyperfine interaction in YAB:Ho3+: a high-resolution spectroscopy investigation. Phys Rev B 76:165130–16513910.1103/PhysRevB.76.165130 ↗
4. Bodył S (2006) Luminescencja jonów REE we fluorytach, (in Polish). Gospodarka Surowcami Mineralnymi 2(3):347–353
5. Bodył S (2009) Luminescence properties of Ce3+ and Eu2+ in fluorites and apatites. Mineralogia 40(1–4):5–18
6. Bodył S, Czaja M, Mazurak Z (2009) Optical properties of Pr3+, Sm3+ and Er3+ ions in apatite and phosphate glasses. Phys Proceedia 2(2):515–52510.1016/j.phpro.2009.07.037 ↗
7. Bodył-Gajowska S (2010) Spektroskopia lantanowców w wybranych minerałach. Dissertation, University of Silesia
8. Caldino U, de la Cruz C, Munoz H, Rubio O (1989) Ce3+ → Eu2+ energy transfer in CaF2. Solid State Commun 69:347–35110.1016/0038-1098(89)90685-6 ↗
9. Chrysochoos J, Stillman MJ, Jacobs PWM (1982) Laser induced luminescence of Pr3+ in CaF2 attributed to different local site symmetries. In: Silber, Rhyne (eds) The rare earths in modern science and technology, vol. 3 McCarthy. Plenum Publishing Corporation, pp 161–16410.1007/978-1-4613-3406-4_33 ↗
10. Chrysochoos J, Jacobs PWM, Stilman MJ (1983) Laser induced emission spectra of Pr3+ in CaF2 at low temperatures. J Lumin 28:177–19010.1016/0022-2313(83)90043-1 ↗
11. Czaja M, Bodył S, Głuchowski P, Mazurak Z, Stręk W (2008) Luminescence properties of rare earth ions in fluorite, apatite and scheelite mineral. J Alloys Compd 451:290–29210.1016/j.jallcom.2007.04.058 ↗
12. Dieke J (1968) Spectra and energy levels of rare-earth ions in crystals. Wiley, New York
13. Elcombe MM, Pryor AW (1970) Lattice dynamics of calcium fluorite. J Phys C3:492–500
14. Fenn JB, Wright JC, Fong FK (1973) Optical study of ion-defect clustering in CaF2:Er3+. J Chem Phys 59:5591–559910.1063/1.1679911 ↗
15. Gaft M, Reisfeld R, Panczer G, Blank Ph, Boulon G (1998) Laser-induced time-resolved luminescence of minerals. Spectrochim Acta A 54:2163–217510.1016/S1386-1425(98)00134-6 ↗
16. Gaft M, Panczer G, Reisfeld R, Uspensky E (2001a) Laser-induced time-resolved luminescence as a tool for rare-earth element identification in minerals. Phys Chem Miner 28:347–36310.1007/s002690100163 ↗
17. Gaft M, Reisfeld R, Panczer G, Ioffe O, Segal I (2001b) Laser- induced time-resolved luminescence as means for discrimination of oxidation state of Eu in minerals. J Alloys Compd 323–324:842–84610.1016/S0925-8388(01)01157-4 ↗
18. Gaft M, Reisfeld R, Panczer G (2005) Luminescence spectroscopy of minerals and materials. Springer, Berlin
19. Gaft M, Reisfeld R, Panczer G, Dimova M (2008) Time-resolved laser-induced luminescence of UV-vis emission of Nd3+ in fluorite, scheelite and barite. J Alloys Compd 451:56–6110.1016/j.jallcom.2007.04.185 ↗
20. Gruber JB, Burdick GW, Valiev UV, Nash KL, Rakhimov SA, Sardar DK (2009) Energy levels and symmetry assignments for star components of Ho3+ (4f10) in yttrium gallium garnet (Y3Ga5O12). J Appl Phys 106:113110–11311210.1063/1.3259441 ↗
21. Illiev M, Liarokapis E, Sendova MBl (1988) Laser excited luminescence of rare earth impurities in natural and synthetic CaF2. Phys Chem of Miner 15:597–60010.1007/BF00311031 ↗
22. Kirilyuk LV (1973) The concentration dependence of the intensity of the luminescence line at λ = 551.2 nm in single crystals of CaF2 -Ho3+ and CaF2 -Ho3+ Eu2+. Z Prikl Spektr 19(5):843–845
23. Mazurak Z, Bodył S, Lisiecki R, Gabryś-Pisarska J, Czaja M (2010) Optical properties of Pr3+, Sm3+ and Er3+ doped P2O5-CaO-SrO-BaO phosphate glass. Opt Mater 32:547–55310.1016/j.optmat.2009.11.011 ↗
24. Mujaji M, Jones GD, Syme RW (1992) Polarization study and crystal-field analysis of the laser-selective excitation spectra of Ho3+ ions in CaF2 and SrF2crystals. Phys Rev B 46:14398–1441010.1103/PhysRevB.46.14398 ↗
25. Oskam KD, Houtepen AJ, Meijerink A (2002) Site selective 4f5d spectroscopy of CaF2:Pr3+. J Lumin 97:107–11410.1016/S0022-2313(01)00242-3 ↗
26. Petit V, Camy P, Doualan JL, Moncorge R (2007) Refined analysis of the luminescent centers in the Yb3+: CaF2 laser crystal. J Lumin 122–123:5–710.1016/j.jlumin.2006.01.064 ↗
27. Pugh VJ, Richardson FS, Gruber JB, Seltzer MD (1997) Characterization and analysis of the 4f–electronic states of trivalent holmium in yttrium scandium gallium garnet. J Phys Chem Solids 58:85–10110.1016/S0022-3697(96)00100-X ↗
28. Pujol MC, Cascales C, Rico M, Massons J, Diaz F, Porcher P, Zaldo C (2001) Measurements and crystal field analysis of energy levels of Ho3+ and Er3+ in KGd(WO4)2 single crystal. J Alloys Compd 323–324:321–32510.1016/S0925-8388(01)01081-7 ↗
29. Rector CW, Pandey BC, Moos HW (1966) Electron paramagnetic resonance and optical Zeeman spectra of type II CaF2: Er3+. J Chem Phys 45(1):171–17910.1063/1.1727303 ↗
30. Seelbinder MB, Wright JC (1979) Site-selective spectroscopy of CaF2: Ho3+. Phys Rev B 20:4308–432010.1103/PhysRevB.20.4308 ↗
31. Subramanian U, Mukherjee ML (1987) Thermoluminescence spectra and X-ray luminescence spectra of CaF2 -Ng single crystals. J Mat Sci 22:473–47710.1007/BF01160755 ↗
32. Tallant DR, Wright JC (1975) Selective laser excitation of charge compensated sites in CaF2: Er3+. J Chem Phys 63:2074–208510.1063/1.431545 ↗
33. Tofield BC, Weber HP (1974) Efficient phonon-assisted long-lifetime Nd3+ luminescence in Cs2NaNdCl6. Phys Rev B 10:4560–456710.1103/PhysRevB.10.4560 ↗
34. Walsh BM, Grew GW, Barnes NP (2005) Energy levels and intensity of Ho3+ ions in GdLiF4, YLiF4 and LuLiF4. J Phys Condens Matter 17:7643–766510.1088/0953-8984/17/48/016 ↗
35. Walsh BM, Grew GW, Barnes NP (2006) Energy levels and intensity parameters of Ho3+ ions in Y3Al5O12 and Lu3Al5O12. J Phys Chem Solids 67:1567–158210.1016/j.jpcs.2006.01.123 ↗
36. Weber MJ, Bierig RW (1964) Paramagnetic resonance and relaxation of trivalent rare-earth ions in calcium fluoride. I. Resonance spectra of crystal fields. Phys Rev 234:A1492–A150310.1103/PhysRev.134.A1492 ↗
37. Wood DL, Kaiser W (1962) Absorption and Fluorescence of Sm2+ in CaF2, SrF2 and BaF2. Phys Rev 126:2079–208810.1103/PhysRev.126.2079 ↗