journal article·2024-01

Superior supercapacitive performance of molybdenum sulfide/reduced graphene oxide composite

Ahmed Samir, Abd Elhamid M. Abd Elhamid, Aref Eliwa, Essam El Din Aboul Zahab, Mohamed B. Zahran, Mahmoud M. Sayed

Publisher page

Abstract

Hydrothermal strategy was used to grow molybdenum sulfide (MoS 2 ) micro flower-like structures reinforced reduced graphene oxide (rGO) for supercapacitor (SC) application. Morphological and structural analyses confirmed the well-distribution of MoS 2 on rGO sheets. Despite using lithium sulfate (Li 2SO 4 ) as a relatively high-voltage window electrolyte, potassium iodide (KI) was incorporated for sturdy iodide/iodine redox interaction. Thus, the fabricated symmetric SCs result achieved superior power density (P d ) of ∼36 kW/kg and exceptionally high energy density (E d) of 132.9 Wh/kg at 10 and 0.1 A/g, respectively. The maximum estimated specific capacitance (C s) was 357 F/g for optimum KI ratio. Additionally, SC possesses more than 99 % of retention value after applying 8000 cycles at 10 A/g. These findings implies MoS 2/rGO composite and Li 2SO 4/KI mixed electrolyte configuration as a simple but efficient SC configuration for high energy, power and lifetime.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Nanomaterials for catalytic reactions · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (69)

Show source-provided references
1. Renewable energy resources: current status, future prospects and their enabling technology10.1016/j.rser.2014.07.113 ↗
2. Energy, economics and environmental impacts of renewable energy systems10.1016/j.rser.2009.05.007 ↗
3. Role of renewable energy sources in environmental protection: A review10.1016/j.rser.2010.11.037 ↗
4. What are batteries, fuel cells, and supercapacitors?10.1021/cr020730k ↗
5. Flexible electrodes and supercapacitors for wearable energy storage: a review by category10.1039/C5TA10582J ↗
6. Layer-by-layer self-assembly of ternary MoS2-rGO@PPyNTs nanocomposites for high performance supercapacitor electrode10.1016/j.synthmet.2018.06.001 ↗
7. Facile synthesis of MoS2/reduced graphene Oxide@polyaniline for high-performance supercapacitors10.1021/acsami.6b06762 ↗
8. Collaborated nanosecond lasers processing of crude graphene oxide for superior supercapacitive performance10.1016/j.est.2023.106669 ↗
9. Fabrication of symmetric supercapacitor based on relatively long lifetime polyaniline grown on reduced graphene oxide via Fe2+ oxidation sites10.1016/j.diamond.2019.05.013 ↗
10. Review on supercapacitors: technologies and materials10.1016/j.rser.2015.12.249 ↗
11. Carbon-based composite materials for supercapacitor electrodes: a review10.1039/C7TA00863E ↗
12. 0D to 3D carbon-based networks combined with pseudocapacitive electrode material for high energy density supercapacitor: a review10.1016/j.cej.2020.126352 ↗
13. Enhanced activity of a hydrothermally synthesized mesoporous MoS 2 nanostructure for high performance supercapacitor applications10.1039/c3nj01558k ↗
14. Ultrathin MoS2 nanosheets hybridizing with reduced graphene oxide for high-performance pseudocapacitors10.1016/j.flatc.2020.100212 ↗
15. MoS2 based nanomaterials: advanced antibacterial agents for future10.1016/j.jconrel.2022.05.047 ↗
16. Uniform MoS 2 nanolayer with sulfur vacancy on carbon nanotube networks as binder-free electrodes for asymmetrical supercapacitor10.1016/j.apsusc.2019.01.007 ↗
17. Core-shell structured MoS 2 @Mesoporous hollow carbon spheres nanocomposite for supercapacitors applications with enhanced capacitance and energy density10.1016/j.electacta.2018.12.126 ↗
18. Few layered MoS2 grown on pencil graphite: a unique single-step approach to fabricate economical, binder-free electrode for supercapacitor applications10.1088/1361-6528/aaed78 ↗
19. Ultra-small amorphous MoS2 decorated reduced graphene oxide for supercapacitor application10.1016/j.jmst.2019.08.032 ↗
20. A review of electrolyte materials and compositions for electrochemical supercapacitors10.1039/C5CS00303B ↗
21. Aqueous supercapacitor with ultrahigh voltage window beyond 2.0 volt10.1002/sstr.202000020 ↗
22. Next-generation activated carbon supercapacitors: a simple step in electrode processing leads to remarkable gains in energy density10.1002/adfm.201605745 ↗
23. Revisited insights into charge storage mechanisms in electrochemical capacitors with Li2SO4-based electrolyte10.1016/j.ensm.2019.08.005 ↗
24. Carbon materials for supercapacitors
25. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage10.1126/science.aab3798 ↗
26. Hydrangea-like N/O codoped porous carbons for high-energy supercapacitors10.1016/j.cej.2020.124208 ↗
27. Neutralization reaction in synthesis of carbon materials for supercapacitors10.1016/j.cej.2019.122547 ↗
28. A high energy density aqueous hybrid supercapacitor with widened potential window through multi approaches10.1016/j.nanoen.2019.02.001 ↗
29. A review of redox electrolytes for supercapacitors
30. Carbons and electrolytes for advanced supercapacitors10.1002/adma.201304137 ↗
31. Ultrathin hierarchical porous carbon nanosheets for high-performance supercapacitors and redox electrolyte energy storage10.1002/adma.201705789 ↗
32. Mini-review on the redox additives in aqueous electrolyte for high performance supercapacitors10.1021/acsomega.9b04063 ↗
33. Study of reduced graphene oxide preparation by Hummers’ method and related characterization10.1155/2015/168125 ↗
34. Improved synthesis of graphene oxide10.1021/nn1006368 ↗
35. High power capability of mos2 based aqueous electrolyte supercapacitor
36. Defect-rich MoS2 ultrathin nanosheets with additional active edge sites for enhanced electrocatalytic hydrogen evolution10.1002/adma.201302685 ↗
37. Investigation on the structure and physical properties of Fe 3 O 4 /RGO nanocomposites and their photocatalytic application10.1016/j.mssp.2019.04.005 ↗
38. MoS2 nanorods anchored reduced graphene oxide nanohybrids for electrochemical energy conversion applications10.1016/j.physe.2020.114589 ↗
39. Raman study of D* band in graphene oxide and its correlation with reduction10.1016/j.apsusc.2020.147990 ↗
40. Raman spectroscopy as a versatile tool for studying the properties of graphene10.1038/nnano.2013.46 ↗
41. CoS 2 nanoparticles‐decorated MoS 2 /rGO nanosheets as an efficient electrocatalyst for ultrafast hydrogen evolution10.1002/admi.202101294 ↗
42. Edge-terminated MoS2 nanosheets with an expanded interlayer spacing on graphene to boost supercapacitive performance10.1016/j.cej.2020.124204 ↗
43. Effect of doping temperatures and nitrogen precursors on the physicochemical, optical, and electrical conductivity properties of nitrogen-doped reduced graphene oxide10.3390/ma12203376 ↗
44. MoS2-reduced graphene oxide composites via microwave assisted synthesis for sodium ion battery anode with improved capacity and cycling performance10.1016/j.electacta.2014.11.034 ↗
45. MoS2/RGO hybrids prepared by a hydrothermal route as a highly efficient catalytic for sonocatalytic degradation of methylene blue10.1016/j.rinp.2019.102458 ↗
46. Catalytic synergy effect of MoS2/reduced graphene oxide hybrids for a highly efficient hydrogen evolution reaction10.1039/C6RA26149C ↗
47. A highly conductive porous graphene electrode prepared via in situ reduction of graphene oxide using Cu nanoparticles for the fabrication of high performance supercapacitors10.1039/C5RA07857A ↗
48. Free-standing and flexible MoS2/rGO paper electrode for amperometric detection of folic acid10.1002/elan.201700778 ↗
49. Two-dimensional hybrid materials: MoS 2 -RGO nanocomposites enhanced the barrier properties of epoxy coating10.1016/j.apsusc.2018.03.013 ↗
50. Energy storage: the future enabled by nanomaterials10.1126/science.aan8285 ↗
51. Towards establishing standard performance metrics for batteries, supercapacitors and beyond10.1039/C8CS00581H ↗
52. Improved energy density of reduced graphene oxide based aqueous symmetric supercapacitors in redox-active and “water-in-salt” electrolytes10.1016/j.est.2022.105006 ↗
53. Silver-substituted cobalt zeolite imidazole framework on reduced graphene oxide nanosheets as a novel electrode for supercapacitors10.1016/j.est.2022.105443 ↗
54. Hydrothermal carbonization of abundant renewable natural organic chemicals for high-performance supercapacitor electrodes10.1002/aenm.201100019 ↗
55. Enhancing specific energy and power in asymmetric supercapacitors - a synergetic strategy based on the use of redox additive electrolytes
56. Novel insight into neutral medium as electrolyte for high-voltage supercapacitors10.1039/C1EE02262H ↗
57. Li2SO4-polyacrylamide polymer electrolytes for 2.0 V solid symmetric supercapacitors10.1016/j.elecom.2017.06.003 ↗
58. Exploring the large voltage range of carbon/carbon supercapacitors in aqueous lithium sulfate electrolyte10.1039/c2ee22284a ↗
59. Laser writing of graphene‑tin hybrid composite-based supercapacitor for battery-like performance10.1016/j.est.2023.109106 ↗
60. Lignin-based composites for high-performance supercapacitor electrode materials10.1039/D2RA02200A ↗
61. Integrated paper electrodes derived from cotton stalks for high-performance flexible supercapacitors10.1016/j.nanoen.2018.08.056 ↗
62. Charge storage kinetics of MoS2 flower decorated reduced graphene oxide for quasi solid-state symmetric supercapacitor10.1016/j.jpcs.2022.111117 ↗
63. Emerging robust heterostructure of MoS 2 –rGO for high-performance supercapacitors10.1021/acsami.8b04540 ↗
64. Nickel cobaltite functionalized silver doped carbon xerogels as efficient electrode materials for high performance symmetric supercapacitor10.3390/ma13214906 ↗
65. The effects of electrolyte on the supercapacitive performance of activated calcium carbide-derived carbon10.1016/j.jpowsour.2012.11.014 ↗
66. The integration of SnO2 dots and porous carbon nanofibers for flexible supercapacitors10.1016/j.electacta.2019.03.204 ↗
67. Best practice methods for determining an electrode material’s performance for ultracapacitors10.1039/c0ee00074d ↗
68. Secondary batteries - nickel systems | Nickel-metal hydride: overview
69. Rechargeable metal-metal alkaline batteries: Recent advances, current issues and future research strategies10.1016/j.jpowsour.2023.232777 ↗