journal article·2023-12

The oxidation mechanism of nanostructured Y-Zr-O complex oxide dispersion-strengthened Mo alloys

Liying Yao, Seiji Miura, Ken-ichi Ikeda, Yimin Gao, Yefei Li

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Abstract

The oxidation behavior of nanostructured Y-Zr-O complex oxide dispersion-strengthened Mo alloys was investigated using the thermogravimetric analysis in synthetic air at 300 °C, 600 °C, and 700 °C for 2 h, respectively. The Mo alloys have a higher weight gain than pure Mo, indicating a deterioration in oxidation resistance, which is derived from the ultrafine grain structure by providing more boundaries for the diffusion of oxygen and accelerating the oxidation rate. Whereas a low weight gain followed by a slow rate of weight loss is observed with increasing Zr addition, revealing the oxidation resistance is improved as the dissolved Zr concentration in the matrix increases. The dissolved Y and Zr promote the formation of the Y-Zr-Mo-O phase in the outer MoO 3 layer, which suppresses the formation and volatilization of MoO 3.
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OpenAlex topics: Nuclear Materials and Properties · High-Temperature Coating Behaviors · Advanced materials and composites

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