Abnormal L12-LPSO phase transformation and its influence on mechanical properties and deformation mechanisms in a Ti-alloyed medium-entropy alloy
Source abstract
Abstract
A comprehensive understanding of precipitation behaviors, including phase transformation, morphology and distribution of precipitates, and their impacts on mechanical properties and deformation mechanisms is very important for the development of precipitation-hardened high/medium-entropy alloys (HEAs/MEAs). In this work, a Ti-alloyed MEA was successfully fabricated and systematically investigated. Experimental results reveal that two types of precipitates, i.e. intragranular spherical L1 2 and intergranular lamellar long-period stacking ordered (LPSO) precipitates with same stoichiometry, are coexist at early aging state in this Ti-alloyed MEA, which result in superior mechanical properties. With aging process continuous, the L1 2 phase could abnormally transforms to the LPSO phase, and this abnormal transformation originates from geometrical modification of the compact planes stacking sequences. Furthermore, the effects of abnormal phase transformation on mechanical properties and deformation mechanisms are systematically investigated. This work not only provides a comprehensive understanding of precipitation behaviors and their impacts on mechanical properties in a Ti-alloyed MEA, but also an interesting phase transformation path for the design of precipitation-hardened HEA/MEAs.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. Towards stacking fault energy engineering in FCC high entropy alloys10.1016/j.actamat.2021.117472 ↗
2. Functional properties and promising applications of high entropy alloys10.1016/j.scriptamat.2020.06.017 ↗
3. Enhancing the radiation tolerance of high-entropy alloys via solute-promoted chemical heterogeneities10.1016/j.actamat.2022.118662 ↗
4. Remarkable cryogenic strengthening and toughening in nano-coherent CoCrFeNiTi0.2 high-entropy alloys via energetically-tuning polymorphous precipitates10.1016/j.msea.2022.143111 ↗
5. A strong and ductile medium-entropy alloy resists hydrogen embrittlement and corrosion10.1038/s41467-020-16791-8 ↗
6. Microstructure-dependent phase stability and precipitation kinetics in equiatomic CrMnFeCoNi high-entropy alloy: Role of grain boundaries10.1016/j.actamat.2021.117470 ↗
7. Hall-petch relationship and heterogeneous strength of CrCoNi medium-entropy alloy10.1016/j.matchemphys.2020.123073 ↗
8. Decelerated grain growth kinetic and effectiveness of Hall-Petch relationship in a cold-rolled non-equiatomic high entropy alloy10.1016/j.jallcom.2021.159849 ↗
9. Effect of annealing temperatures on microstructure and deformation behavior of Al0.1CrFeCoNi high-entropy alloy10.1016/j.msea.2020.140523 ↗
10. Achieving excellent strength-ductility synergy in twinned NiCoCr medium-entropy alloy via Al/Ta co-doping10.1016/j.jmst.2021.01.060 ↗
11. Solid solution hardening in CrMnFeCoNi-based high entropy alloy systems studied by a combinatorial approach10.1557/s43578-021-00205-6 ↗
12. Metalloid substitution elevates simultaneously the strength and ductility of face-centered-cubic high-entropy alloys10.1016/j.actamat.2021.117571 ↗
13. Strength and ductility enhancement of high-entropy FeCoNi2Al0.9 alloy by ultrasonically refining eutectic structures10.1016/j.scriptamat.2022.115154 ↗
14. Designing structures with combined gradients of grain size and precipitation in high entropy alloys for simultaneous improvement of strength and ductility10.1016/j.actamat.2022.117847 ↗
15. Nano-precipitates strengthened non-equiatomic medium-entropy alloy with outstanding tensile properties10.1016/j.msea.2020.139218 ↗
16. Microstructure and mechanical properties of (CrCoNi)97Al1.5Ti1.5 medium entropy alloy twisted by free-end-torsion at room and cryogenic temperatures10.1016/j.msea.2020.140101 ↗
17. γ′′ phase transformation, precipitation hardening, hetero-deformation induced hardening and deformation mechanisms in a Nb-alloyed medium-entropy alloy
18. Advancing strength and counteracting embrittlement by displacive transformation in heterogeneous high-entropy alloys containing sigma phase10.1016/j.actamat.2023.118717 ↗
19. Temperature-dependent microstructural evolutions and deformation mechanisms of (Ni2Co2FeCr)92Al4Nb4 high-entropy alloys10.1016/j.jallcom.2022.165597 ↗
20. Tailoring microstructures and tensile properties of a precipitation-strengthened (FeCoNi)94Ti6 medium-entropy alloy10.1016/j.jallcom.2020.154457 ↗
21. Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy10.1038/s41467-020-16085-z ↗
22. Superb strength and ductility balance of a Co-free medium-entropy alloy with dual heterogeneous structures10.1016/j.jmst.2021.05.023 ↗
23. Concurrent recrystallization and precipitation for combination of superior precipitation and grain boundary hardening in Co37Cr20Ni37Ti3Al3 high-entropy alloy10.1007/s12540-022-01178-9 ↗
24. Manipulation of precipitation and mechanical properties of precipitation-strengthened medium-entropy alloy10.1016/j.scriptamat.2022.115057 ↗
25. A novel high-entropy alloy with desirable strength and ductility designed by multi-component substitution for traditional austenitic alloys10.1016/j.jallcom.2022.168266 ↗
26. Novel high-entropy alloys with high-density ε-D019 and abnormal phase transformation10.1016/j.scriptamat.2021.113893 ↗
27. Secondary phases in AlxCoCrFeNi high-entropy alloys: An in-situ TEM heating study and thermodynamic appraisal10.1016/j.actamat.2017.03.066 ↗
28. Precipitation behavior and its effects on tensile properties of FeCoNiCr high-entropy alloys10.1016/j.intermet.2016.09.005 ↗
29. Huang effects of Al addition on structural evolution and mechanical properties of the CrCoNi medium-entropy alloy
30. Heterogeneous precipitates facilitate excellent mechanical properties in non-equiatomic medium-entropy alloy10.1016/j.intermet.2020.107036 ↗
31. Outstanding tensile properties of a precipitation-strengthened FeCoNiCrTi0.2 high-entropy alloy at room and cryogenic temperatures10.1016/j.actamat.2018.11.049 ↗
32. An in situ ambient and cryogenic transmission electron microscopy study of the effects of temperature on dislocation behavior in CrCoNi-based high-entropy alloys with low stacking-fault energy10.1063/5.0069086 ↗
33. Generalized stacking faults energies of face-centered cubic high-entropy alloys: a first-principles study10.1016/j.intermet.2022.107556 ↗
34. Alloying behaviour of Ni3Al, Ni3Ca, Ni3Si and Ni3Ge10.1016/0001-6160(84)90057-9 ↗
35. Effect of iron addition on the precipitation behavior of CoNiCr alloys containing Nb10.1007/BF02811688 ↗
36. Exceptional nanostructure stability and its origins in the CoCrNi-based precipitation-strengthened medium-entropy alloy10.1080/21663831.2019.1568315 ↗
37. Excellent thermal stability and their origins in γ′ precipitation-strengthened medium-entropy alloys10.1016/j.scriptamat.2022.114576 ↗
38. Effect of alloying elements on the coarsening rate of γ′ precipitates in multi-component CoNi-based superalloys with high Cr content10.1016/j.scriptamat.2021.114004 ↗
39. Improving the intermediate- and high-temperature strength of L1 2 -Co 3 (Al,W) by Ni and Ta additions10.1016/j.actamat.2022.118224 ↗
40. Development of low-density γ/γ′ Co–Al–Ta-based superalloys with high solvus temperature10.1016/j.actamat.2020.02.049 ↗
41. Characterizing precipitation defects in nickel based 718 alloy10.4028/www.scientific.net/MSF.636-637.517 ↗
42. Cluster on interface of LPSO phase and matrix in Mg-Gd-Y-Ni alloy: Atomic scale insight from HAADF-STEM10.1016/j.matlet.2018.09.162 ↗
43. Local lattice distortion mediated formation of stacking faults in Mg alloys10.1016/j.actamat.2019.03.030 ↗
44. Formation of long-period stacking-ordered (LPSO) structures and microhardness of as-cast Mg-4.5Zn–6Y alloy10.1016/j.msea.2020.139019 ↗
45. Domain structures and the transitional state of ordering in long-period stacking ordered (LPSO) structures in Mg–Al–Gd alloy10.1016/j.scriptamat.2020.05.055 ↗
46. Precipitation of the Ni3Nb Phase in two Nickel base superalloys10.1007/BF02649259 ↗
47. Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi10.1016/j.actamat.2017.02.036 ↗
48. Contribution of coherent precipitates on mechanical properties of CoCrFeNiTi0.2 high-entropy alloy at room and cryogenic temperatures10.1016/j.intermet.2022.107820 ↗
49. Heterogeneous precipitation behavior and stacking-fault-mediated deformation in a CoCrNi-based medium-entropy alloy10.1016/j.actamat.2017.07.029 ↗
50. On dislocation pole models for twinning10.1080/14786437408207269 ↗
51. Perfect dislocation pole models for twinning in the f.c.c. and b.c.c lattices10.1080/14786437408213281 ↗
52. A dislocation model for twinning in fcc metals10.1016/0001-6160(63)90074-9 ↗
53. Nucleation and growth of deformation twins: a perspective based on the double-cross-slip mechanism of deformation twinning10.1080/01418610208240069 ↗
54. Strengthening mechanisms in polycrystalline multimodal nickel-base superalloys10.1007/s11661-009-9858-5 ↗