journal article·2018-02

Durability tests of BCY-BZY electrolyte fuel cells under severe operating conditions

Mi Young Park, Kwon Deok Seo, Jun-Young Park, Hyung-Tae Lim

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Abstract

Abstract Anode supported BCY (anode side) - BZY (cathode side) cells were fabricated and their durability was investigated under constant current tests. The cells remained stable under the severe operating conditions of negative cell voltage and high air utilization. This is because the BZY layer at the cathode side provided local electronic conduction, which prevented electrolyte/electrode delamination under negative voltage, as well as chemical stability against water vapor attack under high air utilization conditions. No significant changes in composition or phase were observed in the cells following the tests. These results are contrary to those reported for a single layer BCY cell. The present work suggests that a protonic ceramic fuel cell fabricated with BZY+LSCF cathode, BZY/BCY electrolyte, and Ni + BCY anode provides superior durability under severe operating conditions.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fuel Cells and Related Materials · Advancements in Solid Oxide Fuel Cells · Nuclear Materials and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. Electrical conductivity of the high-temperature proton conductor BaZr0.9Y0.1O2.9510.1111/j.1151-2916.2000.tb01272.x ↗
2. Protonic conduction in Zr-substituted BaCeO3, solid state ionics10.1016/S0167-2738(00)00777-3 ↗
3. Proton conducting alkaline earth zirconates and titanates for high drain electrochemical applications10.1016/S0167-2738(01)00953-5 ↗
4. Technological challenges in the application of proton conducting ceramics10.1016/0167-2738(95)00051-7 ↗
5. Concentration and transport of protons in oxides
6. Solid-state protonic conductors: principles, properties, progress and prospects10.1016/S0167-2738(99)00152-6 ↗
7. BCY-based proton conducting ceramic cell: 1000 h of long term testing in fuel cell application10.1016/j.jpowsour.2013.04.028 ↗
8. A solid oxide fuel cell using Y-doped BaCeO3 with Pd-loaded FeO anode and Ba0. 5Pr0. 5CoO3 cathode at low temperatures10.1149/1.1513983 ↗
9. A stable BaCeO3-based proton conductor for intermediate-temperature solid oxide fuel cells10.1016/j.jpowsour.2009.12.047 ↗
10. Y-doped BaCeO3-d nanopowders as proton-conducting electrolyte materials for ethane fuel cells to co-generate ethylene and electricity10.1016/j.jpowsour.2009.10.069 ↗
11. Measurement of proton and oxide ion fluxes in a working Y-doped BaCeO3 SOFC10.1016/j.ssi.2007.02.003 ↗
12. Influence of the transition-metal doping on conductivity of a BaCeO3-based protonic conductor10.1016/j.ssi.2005.09.027 ↗
13. A stable and easily sintering BaCeO3-based proton-conductive electrolyte10.1016/j.jallcom.2008.05.071 ↗
14. Protonic conduction in Zr-substituted BaCeO310.1016/S0167-2738(00)00777-3 ↗
15. Study on the chemical stability of Y-doped BaCeO3-d and BaZrO3-d films deposited by aerosol deposition10.1016/j.tsf.2011.08.013 ↗
16. Elaboration of CO2 tolerance limits of BaCe 0.9Y 0.1O3–δ electrolytes for fuel cells and other applications10.1016/j.ssi.2005.09.040 ↗
17. Instability of BaCeO3 in H2O-Containing atmospheres10.1149/1.1836647 ↗
18. Stability of BaCe0.8Gd0.2O3 in a H2O-Containing atmosphere at intermediate temperatures10.1149/1.1837759 ↗
19. Stability of BaCeO3-based proton conductors in water-containing atmospheres10.1149/1.1391888 ↗
20. Endurance against moisture for protonic conductors of perovskite-type ceramics and preparation of practical conductors10.1016/S0167-2738(01)00930-4 ↗
21. Chemical stability of doped BaCeO3-BaZrO3 solid solutions in different atmospheres10.1016/S1002-0721(08)60127-1 ↗
22. Resistance of composite materials based on BaCeO3 against the corrosive effects of carbon dioxide and water vapour at intermediate fuel cell operating temperatures10.1007/s10973-013-3562-9 ↗
23. Synthesis, stability and conductivity of BaCe0.8−xZrxY0.2O3−δ as electrolyte for proton conducting SOFC
24. Combined bulk and surface analysis of the BaCe0.5Zr0.3Y0.16Zn0.04O3−δ (BCZYZ) ceramic proton-conducting electrolyte10.1016/j.ssi.2013.12.044 ↗
25. Protonation and structural/chemical stability of Ln2NiO4+ δ ceramics vs. H2O/CO2: high temperature/water pressure ageing tests10.1016/j.jallcom.2014.11.017 ↗
26. Intermediate temperature anode-supported fuel cell based on BaCe0.9Y0. 1O3 electrolyte with novel Pr2NiO4 cathode10.1002/fuce.200900033 ↗
27. Cobalt-free oxide Ba0.5 Sr0.5 Fe0.8Cu0.2O3− δ for proton-conducting solid oxide fuel cell cathode10.1016/j.ijhydene.2010.01.039 ↗
28. Indium as an ideal functional dopant for a proton-conducting solid oxide fuel cell10.1016/j.ijhydene.2008.12.087 ↗
29. Performance of solid oxide fuel cells based on proton-conducting BaCe0.7In0.3-xYxO3-δ electrolyte10.1016/j.ijhydene.2010.06.073 ↗
30. Degradation study of yttria-doped barium cerate (BCY) electrolyte in protonic ceramic fuel cells under various operating conditions10.2109/jcersj2.123.257 ↗
31. Dependence of polarization in anode-supported solid oxide fuel cells on various cell parameters10.1016/j.jpowsour.2004.08.057 ↗
32. Fuel composition and diluent effect on gas transport and performance of anode-supported SOFCs10.1149/1.1579480 ↗
33. Gas conversion impedance: a test geometry effect in characterization of solid oxide fuel cell anodes10.1149/1.1838654 ↗
34. Correlation between internal chemical potential and durability of yttria-doped barium cerate (bcy)-based protonic ceramic fuel cells10.1016/j.electacta.2016.04.031 ↗
35. Tailoring the chemical stability of Ba(Ce0.8−xZrx)Y0.2O3−δ protonic conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)10.1016/j.ssi.2008.04.002 ↗
36. Performance and stability of proton conducting solid oxide fuel cells based on yttrium-doped barium cerate-zirconate thin-film electrolyte10.1016/j.jpowsour.2012.11.094 ↗
37. Long term testing of BCZY-based protonic ceramic fuel cell PCFC: micro-generation profile and reversible production of hydrogen and electricity10.1016/j.ssi.2017.03.002 ↗
38. Elaboration of intermediate size planar proton conducting solid oxide cell by wet chemical routes: a way to industrialization10.1016/j.ssi.2015.02.002 ↗
39. High-performance protonic ceramic fuel cells with thin-film yttrium-doped barium cerate–zirconate electrolytes on compositionally gradient anodes10.1021/acsami.6b00512 ↗
40. Design and fabrication of a chemically-stable proton conductor bilayer electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFCs)10.1039/b806655h ↗
41. Fabrication and performance of a carbon dioxide-tolerant proton-conducting solid oxide fuel cells with a dual-layer electrolyte10.1016/j.ijhydene.2010.07.179 ↗
42. Fabrication and performance of BaCe0.8Y 0.2O3− δ–BaZr0.8Y0.2O3− δ bilayer electrolyte for anode-supported solid oxide fuel cells10.1016/j.jpowsour.2013.10.120 ↗
43. Micro ceramic fuel cells with multilayered yttrium-doped barium cerate and zirconate thin film electrolytes10.1016/j.jpowsour.2013.10.057 ↗
44. Fabrication of anode-supported protonic ceramic fuel cell with Ba(Zr0.85Y0.15)O3−δ–Ba(Ce0.9Y0.1)O3−δ dual-layer electrolyte10.1016/j.ijhydene.2014.06.018 ↗
45. A review on proton conducting electrolytes for clean energy and intermediate temperature-solid oxide fuel cells10.1016/j.rser.2017.05.147 ↗
46. Advanced materials for SOFC application: strategies for the development of highly conductive and stable solid oxide proton electrolytes10.1016/j.pmatsci.2015.08.001 ↗
47. Electrochemical study on Ce0.85Sm0.15O1.925–BaCe0.83Y0.17O3−δ composite electrolyte10.1016/j.jallcom.2015.01.135 ↗
48. Electrical and physical properties of composite BaZr0.85Y0.15O3−d-Nd0.1Ce0.9O2−δ electrolytes for intermediate temperature-solid oxide fuel cells10.1016/j.jpowsour.2016.11.005 ↗
49. A model for solid oxide fuel cell (SOFC) stack degradation10.1016/j.jpowsour.2007.05.076 ↗
50. A study of solid oxide fuel cell stack failure by inducing abnormal behavior in a single cell test10.1016/j.jpowsour.2008.07.051 ↗
51. Measurement of hydrogen and oxygen chemical potential in yttria doped barium cerate (BCY) electrolyte of anode-supported protonic ceramic fuel cells10.1016/j.ijhydene.2014.04.146 ↗
52. Bi-layer electrolyte for preventing solid oxide fuel cell stack degradation10.4191/kcers.2014.51.4.289 ↗
53. Electrochemical degradation of fuel cells: effect of electrolyte composition10.1149/1.3205554 ↗
54. Delamination-resistant bi-layer electrolyte for anode-supported solid oxide fuel cells10.1016/j.ssi.2014.02.013 ↗
55. Bae · Electrochim. Acta · 2017 · 236 · 39910.1016/j.electacta.2017.03.151 ↗
56. Electrode materials: a challenge for the exploitation of protonic solid oxide fuel cells10.1088/1468-6996/11/4/044301 ↗
57. Influence of water vapor on long-term performance and accelerated degradation of solid oxide fuel cell cathodes10.1016/j.jpowsour.2010.08.014 ↗
58. Proton-conducting solid oxide fuel cell (SOFC) with Y-doped BaZrO3 electrolyte10.1016/j.elecom.2017.05.006 ↗
59. Structural and conductivity study of the proton conductor BaCe(0.9-x)ZrxY0.1O(3-d) at intermediate temperatures10.1016/j.jpowsour.2008.11.080 ↗
60. BaCeO3-BaCeO3 solid solution (BCZY) as a high-performance electrolyte of protonic ceramic fuel cells (PCFCs)10.4191/kcers.2014.51.4.271 ↗